Synthesis of 3,5-Bis(hydroxymethyl)adamantan-1-ols and 3,5-Bis(nitrooxymethyl)adamantan-1-yl Nitrates View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2020-09

AUTHORS

E. A. Ivleva, A. I. Kazakova, Yu. N. Klimochkin

ABSTRACT

A convenient method has been developed for the synthesis of 3,5-bis(hydroxymethyl)adamantan-1-ols via successive nitroxylation of 1,3-bis(acetoxymethyl)adamantanes with fuming nitric acid, alkaline hydrolysis of intermediate 3,5-bis(acetoxymethyl)adamantane-1-yl nitrates, and reaction of the resulting 3,5-bis(hydroxymethyl)adamantan-1-yl nitrates with hydrazine hydrate. 3,5-Bis(hydroxymethyl)adamantan-1-ols have been converted to the corresponding trinitrates by treatment with fuming nitric acids in acetic anhydride. More... »

PAGES

1562-1569

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070428020090109

DOI

http://dx.doi.org/10.1134/s1070428020090109

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1131896681


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