Kinetic Study of the Nitrolysis of Haloadamantanes View Full Text


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Article Info

DATE

2020-09

AUTHORS

Yu. N. Klimochkin, E. A. Ivleva, M. Yu. Skomorokhov

ABSTRACT

The kinetics of nitrolysis of haloadamantanes containing halogen atoms in the bridging and bridgehead positions with fuming nitric acid have been studied. The effective nitrolysis constants of eight haloadamantane derivatives have been determined. The reaction is described by pseudo-first-order kinetic equation, and the reactivity decreases as the number of halogen atoms in the substrate molecule increases. Haloadamantanes with less electronegative halogens show higher reactivity. More... »

PAGES

1525-1531

References to SciGraph publications

  • 2020-03. Oxidation of Deactivated Cage Substrates in the System H2SO4–HNO3 in RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
  • 2001-07. New Fragmentation of 1,3-Dibromoadamantane in RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
  • 1989-11. Kinetics and mechanism of nitration of cellulose with the HNO3-CH2Cl2 mixture in RUSSIAN CHEMICAL BULLETIN
  • 2011-12. Reaction of dibromoadamantanes with glycols in the presence of sodium glycolate in RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
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    http://scigraph.springernature.com/pub.10.1134/s1070428020090043

    DOI

    http://dx.doi.org/10.1134/s1070428020090043

    DIMENSIONS

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