Regio- and Stereoselective Synthesis of Functionalized Vinyl Sulfides Based on Pyridine-2-thiol and Propynoic Acid and Its Derivatives View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-12

AUTHORS

V. A. Potapov, R. S. Ishigeev, M. V. Musalov, S. V. Zinchenko, Yu. A. Chuvashev, T. N. Borodina, S. V. Amosova

ABSTRACT

Regio- and stereoselective methods of synthesis of 3-(pyridin-2-ylsulfanyl)prop-2-enoic acid and alkyl (Z)-3-(pyridin-2-ylsulfanyl)prop-2-enoates have been developed on the basis of nucleophilic addition of pyridine-2-thiol to propynoic acid and alkyl propynoates. Reactions of alkyl (Z)-3-(pyridin-2-ylsulfanyl)prop-2- enoates with methyl iodide afforded 2-[(3-alkoxy-3-oxoprop-1-enyl)sulfanyl]-1-methylpyridinium iodides.

PAGES

1798-1802

References to SciGraph publications

  • 1978-03. Reaction of pyridine-2-thione with acetylenes in CHEMISTRY OF HETEROCYCLIC COMPOUNDS
  • 1995-06. Pyridine derivatives in the drug arsenal (150 years of pyridine chemistry) in CHEMISTRY OF HETEROCYCLIC COMPOUNDS
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1134/s1070428018120102

    DOI

    http://dx.doi.org/10.1134/s1070428018120102

    DIMENSIONS

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