Reaction of 2-(2-Oxo-1,2-dihydro-3H-pyrrol-3-ylidene)- malononitriles with C-Nucleophiles. Synthesis of New Spiro-Fused Pyrrole Derivatives View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-12

AUTHORS

A. G. Milovidova, M. Yu. Belikov, M. Yu. Ievlev, O. V. Ershov, O. E. Nasakin

ABSTRACT

Base-catalyzed nucleophilic addition of carbon nucleophiles to the exocyclic double bond of 2-(5-aryl-4-methyl-2-oxo-1,2-dihydro-3H-pyrrol-3-ylidene)malononitriles afforded spiro-fused pyrrole derivatives, 7-amino-3-aryl-4-methyl-1-oxo-8-oxa-2-azaspiro[4.5]deca-3,6,9-triene-6-carbonitriles. The products can be regarded as rare structural analogs of biologically active spirans based on isatin.

PAGES

1790-1793

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070428018120084

DOI

http://dx.doi.org/10.1134/s1070428018120084

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1112546767


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