Reaction of 2-(2-Oxo-1,2-dihydro-3H-pyrrol-3-ylidene)- malononitriles with C-Nucleophiles. Synthesis of New Spiro-Fused Pyrrole Derivatives View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-12

AUTHORS

A. G. Milovidova, M. Yu. Belikov, M. Yu. Ievlev, O. V. Ershov, O. E. Nasakin

ABSTRACT

Base-catalyzed nucleophilic addition of carbon nucleophiles to the exocyclic double bond of 2-(5-aryl-4-methyl-2-oxo-1,2-dihydro-3H-pyrrol-3-ylidene)malononitriles afforded spiro-fused pyrrole derivatives, 7-amino-3-aryl-4-methyl-1-oxo-8-oxa-2-azaspiro[4.5]deca-3,6,9-triene-6-carbonitriles. The products can be regarded as rare structural analogs of biologically active spirans based on isatin.

PAGES

1790-1793

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070428018120084

DOI

http://dx.doi.org/10.1134/s1070428018120084

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1112546767


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Chuvash State University", 
          "id": "https://www.grid.ac/institutes/grid.411669.d", 
          "name": [
            "I.N. Ul\u2019yanov Chuvash State University, Moskovskii pr. 15, 428015, Cheboksary, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Milovidova", 
        "givenName": "A. G.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Chuvash State University", 
          "id": "https://www.grid.ac/institutes/grid.411669.d", 
          "name": [
            "I.N. Ul\u2019yanov Chuvash State University, Moskovskii pr. 15, 428015, Cheboksary, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Belikov", 
        "givenName": "M. Yu.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Chuvash State University", 
          "id": "https://www.grid.ac/institutes/grid.411669.d", 
          "name": [
            "I.N. Ul\u2019yanov Chuvash State University, Moskovskii pr. 15, 428015, Cheboksary, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ievlev", 
        "givenName": "M. Yu.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Chuvash State University", 
          "id": "https://www.grid.ac/institutes/grid.411669.d", 
          "name": [
            "I.N. Ul\u2019yanov Chuvash State University, Moskovskii pr. 15, 428015, Cheboksary, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ershov", 
        "givenName": "O. V.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Chuvash State University", 
          "id": "https://www.grid.ac/institutes/grid.411669.d", 
          "name": [
            "I.N. Ul\u2019yanov Chuvash State University, Moskovskii pr. 15, 428015, Cheboksary, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Nasakin", 
        "givenName": "O. E.", 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1039/c4ra16605a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018044157"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0040-4020(01)01029-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1023676857"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s00044-012-0249-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1025040215", 
          "https://doi.org/10.1007/s00044-012-0249-x"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adsc.201100792", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027810079"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.bmcl.2013.02.086", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033120732"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s1070428015010121", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035346549", 
          "https://doi.org/10.1134/s1070428015010121"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.bmcl.2012.06.055", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035457237"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s1070428016040254", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1037782472", 
          "https://doi.org/10.1134/s1070428016040254"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/cber.19370700917", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039592941"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.ejmech.2014.03.016", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047483032"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.bmcl.2010.05.025", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1052809558"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1055/s-0033-1341028", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1057286371"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s1070428017010249", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1084223887", 
          "https://doi.org/10.1134/s1070428017010249"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s1070428017100207", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1092909928", 
          "https://doi.org/10.1134/s1070428017100207"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2018-12", 
    "datePublishedReg": "2018-12-01", 
    "description": "Base-catalyzed nucleophilic addition of carbon nucleophiles to the exocyclic double bond of 2-(5-aryl-4-methyl-2-oxo-1,2-dihydro-3H-pyrrol-3-ylidene)malononitriles afforded spiro-fused pyrrole derivatives, 7-amino-3-aryl-4-methyl-1-oxo-8-oxa-2-azaspiro[4.5]deca-3,6,9-triene-6-carbonitriles. The products can be regarded as rare structural analogs of biologically active spirans based on isatin.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/s1070428018120084", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1136317", 
        "issn": [
          "1070-4280", 
          "1608-3393"
        ], 
        "name": "Russian Journal of Organic Chemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "12", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "54"
      }
    ], 
    "name": "Reaction of 2-(2-Oxo-1,2-dihydro-3H-pyrrol-3-ylidene)- malononitriles with C-Nucleophiles. Synthesis of New Spiro-Fused Pyrrole Derivatives", 
    "pagination": "1790-1793", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "4519b6dab30ae462e9b29adbe87361a1842b3a0730b6fca1cc31d328879e98cd"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s1070428018120084"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1112546767"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s1070428018120084", 
      "https://app.dimensions.ai/details/publication/pub.1112546767"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T11:05", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000352_0000000352/records_60369_00000004.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://link.springer.com/10.1134%2FS1070428018120084"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1070428018120084'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1070428018120084'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1070428018120084'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1070428018120084'


 

This table displays all metadata directly associated to this object as RDF triples.

131 TRIPLES      21 PREDICATES      41 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s1070428018120084 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author Nb29104ae9b8a4d66b076c9bbb669a0df
4 schema:citation sg:pub.10.1007/s00044-012-0249-x
5 sg:pub.10.1134/s1070428015010121
6 sg:pub.10.1134/s1070428016040254
7 sg:pub.10.1134/s1070428017010249
8 sg:pub.10.1134/s1070428017100207
9 https://doi.org/10.1002/adsc.201100792
10 https://doi.org/10.1002/cber.19370700917
11 https://doi.org/10.1016/j.bmcl.2010.05.025
12 https://doi.org/10.1016/j.bmcl.2012.06.055
13 https://doi.org/10.1016/j.bmcl.2013.02.086
14 https://doi.org/10.1016/j.ejmech.2014.03.016
15 https://doi.org/10.1016/s0040-4020(01)01029-8
16 https://doi.org/10.1039/c4ra16605a
17 https://doi.org/10.1055/s-0033-1341028
18 schema:datePublished 2018-12
19 schema:datePublishedReg 2018-12-01
20 schema:description Base-catalyzed nucleophilic addition of carbon nucleophiles to the exocyclic double bond of 2-(5-aryl-4-methyl-2-oxo-1,2-dihydro-3H-pyrrol-3-ylidene)malononitriles afforded spiro-fused pyrrole derivatives, 7-amino-3-aryl-4-methyl-1-oxo-8-oxa-2-azaspiro[4.5]deca-3,6,9-triene-6-carbonitriles. The products can be regarded as rare structural analogs of biologically active spirans based on isatin.
21 schema:genre research_article
22 schema:inLanguage en
23 schema:isAccessibleForFree false
24 schema:isPartOf N4fab47b3b5914d05a7e0b151deb0f906
25 N5bf4307dbac84256a29532995504925e
26 sg:journal.1136317
27 schema:name Reaction of 2-(2-Oxo-1,2-dihydro-3H-pyrrol-3-ylidene)- malononitriles with C-Nucleophiles. Synthesis of New Spiro-Fused Pyrrole Derivatives
28 schema:pagination 1790-1793
29 schema:productId N2191d3daa6cd484cb5c329ddb92db6a9
30 N6a4dbee8a84242c98ad8f327439fbb70
31 Ndd9cf2fd2d9449c7b157d1ff37eed286
32 schema:sameAs https://app.dimensions.ai/details/publication/pub.1112546767
33 https://doi.org/10.1134/s1070428018120084
34 schema:sdDatePublished 2019-04-11T11:05
35 schema:sdLicense https://scigraph.springernature.com/explorer/license/
36 schema:sdPublisher Nc671ca0dfebc458f9267e719ff7c32dc
37 schema:url https://link.springer.com/10.1134%2FS1070428018120084
38 sgo:license sg:explorer/license/
39 sgo:sdDataset articles
40 rdf:type schema:ScholarlyArticle
41 N0707dc0d89704a41b614faef737cb1de schema:affiliation https://www.grid.ac/institutes/grid.411669.d
42 schema:familyName Nasakin
43 schema:givenName O. E.
44 rdf:type schema:Person
45 N109ff278304049df8ada2fcc1e65aabb schema:affiliation https://www.grid.ac/institutes/grid.411669.d
46 schema:familyName Ershov
47 schema:givenName O. V.
48 rdf:type schema:Person
49 N2191d3daa6cd484cb5c329ddb92db6a9 schema:name dimensions_id
50 schema:value pub.1112546767
51 rdf:type schema:PropertyValue
52 N4fab47b3b5914d05a7e0b151deb0f906 schema:issueNumber 12
53 rdf:type schema:PublicationIssue
54 N538936f811d04866bc626e81516d2d58 schema:affiliation https://www.grid.ac/institutes/grid.411669.d
55 schema:familyName Ievlev
56 schema:givenName M. Yu.
57 rdf:type schema:Person
58 N5bf4307dbac84256a29532995504925e schema:volumeNumber 54
59 rdf:type schema:PublicationVolume
60 N6a4dbee8a84242c98ad8f327439fbb70 schema:name readcube_id
61 schema:value 4519b6dab30ae462e9b29adbe87361a1842b3a0730b6fca1cc31d328879e98cd
62 rdf:type schema:PropertyValue
63 N7b316b4edde24d818039171bcc85ae8e rdf:first N0707dc0d89704a41b614faef737cb1de
64 rdf:rest rdf:nil
65 N9cda00821a1447b5966ca4e775d99b88 rdf:first N109ff278304049df8ada2fcc1e65aabb
66 rdf:rest N7b316b4edde24d818039171bcc85ae8e
67 Nb29104ae9b8a4d66b076c9bbb669a0df rdf:first Nf5791ec679e64f75a571d443c4636269
68 rdf:rest Nfb338b90251545d9b670ee672db6e79c
69 Nc671ca0dfebc458f9267e719ff7c32dc schema:name Springer Nature - SN SciGraph project
70 rdf:type schema:Organization
71 Ndd9cf2fd2d9449c7b157d1ff37eed286 schema:name doi
72 schema:value 10.1134/s1070428018120084
73 rdf:type schema:PropertyValue
74 Nedd625d4313c48bbb5103f8d602d68bb rdf:first N538936f811d04866bc626e81516d2d58
75 rdf:rest N9cda00821a1447b5966ca4e775d99b88
76 Nf5791ec679e64f75a571d443c4636269 schema:affiliation https://www.grid.ac/institutes/grid.411669.d
77 schema:familyName Milovidova
78 schema:givenName A. G.
79 rdf:type schema:Person
80 Nfb338b90251545d9b670ee672db6e79c rdf:first Nfc558133ea5143a3828d5bf2c154f651
81 rdf:rest Nedd625d4313c48bbb5103f8d602d68bb
82 Nfc558133ea5143a3828d5bf2c154f651 schema:affiliation https://www.grid.ac/institutes/grid.411669.d
83 schema:familyName Belikov
84 schema:givenName M. Yu.
85 rdf:type schema:Person
86 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
87 schema:name Chemical Sciences
88 rdf:type schema:DefinedTerm
89 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
90 schema:name Physical Chemistry (incl. Structural)
91 rdf:type schema:DefinedTerm
92 sg:journal.1136317 schema:issn 1070-4280
93 1608-3393
94 schema:name Russian Journal of Organic Chemistry
95 rdf:type schema:Periodical
96 sg:pub.10.1007/s00044-012-0249-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1025040215
97 https://doi.org/10.1007/s00044-012-0249-x
98 rdf:type schema:CreativeWork
99 sg:pub.10.1134/s1070428015010121 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035346549
100 https://doi.org/10.1134/s1070428015010121
101 rdf:type schema:CreativeWork
102 sg:pub.10.1134/s1070428016040254 schema:sameAs https://app.dimensions.ai/details/publication/pub.1037782472
103 https://doi.org/10.1134/s1070428016040254
104 rdf:type schema:CreativeWork
105 sg:pub.10.1134/s1070428017010249 schema:sameAs https://app.dimensions.ai/details/publication/pub.1084223887
106 https://doi.org/10.1134/s1070428017010249
107 rdf:type schema:CreativeWork
108 sg:pub.10.1134/s1070428017100207 schema:sameAs https://app.dimensions.ai/details/publication/pub.1092909928
109 https://doi.org/10.1134/s1070428017100207
110 rdf:type schema:CreativeWork
111 https://doi.org/10.1002/adsc.201100792 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027810079
112 rdf:type schema:CreativeWork
113 https://doi.org/10.1002/cber.19370700917 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039592941
114 rdf:type schema:CreativeWork
115 https://doi.org/10.1016/j.bmcl.2010.05.025 schema:sameAs https://app.dimensions.ai/details/publication/pub.1052809558
116 rdf:type schema:CreativeWork
117 https://doi.org/10.1016/j.bmcl.2012.06.055 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035457237
118 rdf:type schema:CreativeWork
119 https://doi.org/10.1016/j.bmcl.2013.02.086 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033120732
120 rdf:type schema:CreativeWork
121 https://doi.org/10.1016/j.ejmech.2014.03.016 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047483032
122 rdf:type schema:CreativeWork
123 https://doi.org/10.1016/s0040-4020(01)01029-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023676857
124 rdf:type schema:CreativeWork
125 https://doi.org/10.1039/c4ra16605a schema:sameAs https://app.dimensions.ai/details/publication/pub.1018044157
126 rdf:type schema:CreativeWork
127 https://doi.org/10.1055/s-0033-1341028 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057286371
128 rdf:type schema:CreativeWork
129 https://www.grid.ac/institutes/grid.411669.d schema:alternateName Chuvash State University
130 schema:name I.N. Ul’yanov Chuvash State University, Moskovskii pr. 15, 428015, Cheboksary, Russia
131 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...