Reaction of 2-(2-Oxo-1,2-dihydro-3H-pyrrol-3-ylidene)- malononitriles with C-Nucleophiles. Synthesis of New Spiro-Fused Pyrrole Derivatives View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-12

AUTHORS

A. G. Milovidova, M. Yu. Belikov, M. Yu. Ievlev, O. V. Ershov, O. E. Nasakin

ABSTRACT

Base-catalyzed nucleophilic addition of carbon nucleophiles to the exocyclic double bond of 2-(5-aryl-4-methyl-2-oxo-1,2-dihydro-3H-pyrrol-3-ylidene)malononitriles afforded spiro-fused pyrrole derivatives, 7-amino-3-aryl-4-methyl-1-oxo-8-oxa-2-azaspiro[4.5]deca-3,6,9-triene-6-carbonitriles. The products can be regarded as rare structural analogs of biologically active spirans based on isatin.

PAGES

1790-1793

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070428018120084

DOI

http://dx.doi.org/10.1134/s1070428018120084

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1112546767


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Chuvash State University", 
          "id": "https://www.grid.ac/institutes/grid.411669.d", 
          "name": [
            "I.N. Ul\u2019yanov Chuvash State University, Moskovskii pr. 15, 428015, Cheboksary, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Milovidova", 
        "givenName": "A. G.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Chuvash State University", 
          "id": "https://www.grid.ac/institutes/grid.411669.d", 
          "name": [
            "I.N. Ul\u2019yanov Chuvash State University, Moskovskii pr. 15, 428015, Cheboksary, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Belikov", 
        "givenName": "M. Yu.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Chuvash State University", 
          "id": "https://www.grid.ac/institutes/grid.411669.d", 
          "name": [
            "I.N. Ul\u2019yanov Chuvash State University, Moskovskii pr. 15, 428015, Cheboksary, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ievlev", 
        "givenName": "M. Yu.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Chuvash State University", 
          "id": "https://www.grid.ac/institutes/grid.411669.d", 
          "name": [
            "I.N. Ul\u2019yanov Chuvash State University, Moskovskii pr. 15, 428015, Cheboksary, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ershov", 
        "givenName": "O. V.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Chuvash State University", 
          "id": "https://www.grid.ac/institutes/grid.411669.d", 
          "name": [
            "I.N. Ul\u2019yanov Chuvash State University, Moskovskii pr. 15, 428015, Cheboksary, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Nasakin", 
        "givenName": "O. E.", 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1039/c4ra16605a", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018044157"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0040-4020(01)01029-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1023676857"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s00044-012-0249-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1025040215", 
          "https://doi.org/10.1007/s00044-012-0249-x"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/adsc.201100792", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027810079"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.bmcl.2013.02.086", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1033120732"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s1070428015010121", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035346549", 
          "https://doi.org/10.1134/s1070428015010121"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.bmcl.2012.06.055", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035457237"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s1070428016040254", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1037782472", 
          "https://doi.org/10.1134/s1070428016040254"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/cber.19370700917", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1039592941"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.ejmech.2014.03.016", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047483032"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.bmcl.2010.05.025", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1052809558"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1055/s-0033-1341028", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1057286371"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s1070428017010249", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1084223887", 
          "https://doi.org/10.1134/s1070428017010249"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s1070428017100207", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1092909928", 
          "https://doi.org/10.1134/s1070428017100207"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2018-12", 
    "datePublishedReg": "2018-12-01", 
    "description": "Base-catalyzed nucleophilic addition of carbon nucleophiles to the exocyclic double bond of 2-(5-aryl-4-methyl-2-oxo-1,2-dihydro-3H-pyrrol-3-ylidene)malononitriles afforded spiro-fused pyrrole derivatives, 7-amino-3-aryl-4-methyl-1-oxo-8-oxa-2-azaspiro[4.5]deca-3,6,9-triene-6-carbonitriles. The products can be regarded as rare structural analogs of biologically active spirans based on isatin.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/s1070428018120084", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1136317", 
        "issn": [
          "1070-4280", 
          "1608-3393"
        ], 
        "name": "Russian Journal of Organic Chemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "12", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "54"
      }
    ], 
    "name": "Reaction of 2-(2-Oxo-1,2-dihydro-3H-pyrrol-3-ylidene)- malononitriles with C-Nucleophiles. Synthesis of New Spiro-Fused Pyrrole Derivatives", 
    "pagination": "1790-1793", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "4519b6dab30ae462e9b29adbe87361a1842b3a0730b6fca1cc31d328879e98cd"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s1070428018120084"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1112546767"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s1070428018120084", 
      "https://app.dimensions.ai/details/publication/pub.1112546767"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T11:05", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000352_0000000352/records_60369_00000004.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://link.springer.com/10.1134%2FS1070428018120084"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1070428018120084'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1070428018120084'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1070428018120084'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1070428018120084'


 

This table displays all metadata directly associated to this object as RDF triples.

131 TRIPLES      21 PREDICATES      41 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s1070428018120084 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N0bd6339f32d245d0997ae67a1fda1234
4 schema:citation sg:pub.10.1007/s00044-012-0249-x
5 sg:pub.10.1134/s1070428015010121
6 sg:pub.10.1134/s1070428016040254
7 sg:pub.10.1134/s1070428017010249
8 sg:pub.10.1134/s1070428017100207
9 https://doi.org/10.1002/adsc.201100792
10 https://doi.org/10.1002/cber.19370700917
11 https://doi.org/10.1016/j.bmcl.2010.05.025
12 https://doi.org/10.1016/j.bmcl.2012.06.055
13 https://doi.org/10.1016/j.bmcl.2013.02.086
14 https://doi.org/10.1016/j.ejmech.2014.03.016
15 https://doi.org/10.1016/s0040-4020(01)01029-8
16 https://doi.org/10.1039/c4ra16605a
17 https://doi.org/10.1055/s-0033-1341028
18 schema:datePublished 2018-12
19 schema:datePublishedReg 2018-12-01
20 schema:description Base-catalyzed nucleophilic addition of carbon nucleophiles to the exocyclic double bond of 2-(5-aryl-4-methyl-2-oxo-1,2-dihydro-3H-pyrrol-3-ylidene)malononitriles afforded spiro-fused pyrrole derivatives, 7-amino-3-aryl-4-methyl-1-oxo-8-oxa-2-azaspiro[4.5]deca-3,6,9-triene-6-carbonitriles. The products can be regarded as rare structural analogs of biologically active spirans based on isatin.
21 schema:genre research_article
22 schema:inLanguage en
23 schema:isAccessibleForFree false
24 schema:isPartOf N299a282eb9a74bccb0f85fd31918d817
25 Ncaa47366b7a84ede93be3f0713f649ab
26 sg:journal.1136317
27 schema:name Reaction of 2-(2-Oxo-1,2-dihydro-3H-pyrrol-3-ylidene)- malononitriles with C-Nucleophiles. Synthesis of New Spiro-Fused Pyrrole Derivatives
28 schema:pagination 1790-1793
29 schema:productId N394065c8c65841cdb5f556dd4bd5839b
30 Nb8d025e2e50f45f388a8702423b635e7
31 Neeb8d41cb2fb42818a32ff30672e1519
32 schema:sameAs https://app.dimensions.ai/details/publication/pub.1112546767
33 https://doi.org/10.1134/s1070428018120084
34 schema:sdDatePublished 2019-04-11T11:05
35 schema:sdLicense https://scigraph.springernature.com/explorer/license/
36 schema:sdPublisher N25abaa2169934a04b2687e98d2704ee8
37 schema:url https://link.springer.com/10.1134%2FS1070428018120084
38 sgo:license sg:explorer/license/
39 sgo:sdDataset articles
40 rdf:type schema:ScholarlyArticle
41 N0bd6339f32d245d0997ae67a1fda1234 rdf:first Nb2b76b298a9a4edfb351508666d57f17
42 rdf:rest Ncefa14ae3ff94ed4852c8739afb336cf
43 N0e59bed00754407bb7eacee7076e2733 rdf:first Nd05fe970e97545d7a41ffd5edebe91c4
44 rdf:rest Ne8e2c3759579402cba69da3e7ea205df
45 N25abaa2169934a04b2687e98d2704ee8 schema:name Springer Nature - SN SciGraph project
46 rdf:type schema:Organization
47 N299a282eb9a74bccb0f85fd31918d817 schema:issueNumber 12
48 rdf:type schema:PublicationIssue
49 N394065c8c65841cdb5f556dd4bd5839b schema:name dimensions_id
50 schema:value pub.1112546767
51 rdf:type schema:PropertyValue
52 N55ca266c768b4da79d2be76a3163b67c schema:affiliation https://www.grid.ac/institutes/grid.411669.d
53 schema:familyName Nasakin
54 schema:givenName O. E.
55 rdf:type schema:Person
56 N5df63f2ccf5a49b598dfa5db5be12e9a schema:affiliation https://www.grid.ac/institutes/grid.411669.d
57 schema:familyName Ershov
58 schema:givenName O. V.
59 rdf:type schema:Person
60 N817f112642c1443abd5fa5fb0326933d schema:affiliation https://www.grid.ac/institutes/grid.411669.d
61 schema:familyName Belikov
62 schema:givenName M. Yu.
63 rdf:type schema:Person
64 Na192d4dab5fc4a74b5f15cd73ae0ce9b rdf:first N55ca266c768b4da79d2be76a3163b67c
65 rdf:rest rdf:nil
66 Nb2b76b298a9a4edfb351508666d57f17 schema:affiliation https://www.grid.ac/institutes/grid.411669.d
67 schema:familyName Milovidova
68 schema:givenName A. G.
69 rdf:type schema:Person
70 Nb8d025e2e50f45f388a8702423b635e7 schema:name doi
71 schema:value 10.1134/s1070428018120084
72 rdf:type schema:PropertyValue
73 Ncaa47366b7a84ede93be3f0713f649ab schema:volumeNumber 54
74 rdf:type schema:PublicationVolume
75 Ncefa14ae3ff94ed4852c8739afb336cf rdf:first N817f112642c1443abd5fa5fb0326933d
76 rdf:rest N0e59bed00754407bb7eacee7076e2733
77 Nd05fe970e97545d7a41ffd5edebe91c4 schema:affiliation https://www.grid.ac/institutes/grid.411669.d
78 schema:familyName Ievlev
79 schema:givenName M. Yu.
80 rdf:type schema:Person
81 Ne8e2c3759579402cba69da3e7ea205df rdf:first N5df63f2ccf5a49b598dfa5db5be12e9a
82 rdf:rest Na192d4dab5fc4a74b5f15cd73ae0ce9b
83 Neeb8d41cb2fb42818a32ff30672e1519 schema:name readcube_id
84 schema:value 4519b6dab30ae462e9b29adbe87361a1842b3a0730b6fca1cc31d328879e98cd
85 rdf:type schema:PropertyValue
86 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
87 schema:name Chemical Sciences
88 rdf:type schema:DefinedTerm
89 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
90 schema:name Physical Chemistry (incl. Structural)
91 rdf:type schema:DefinedTerm
92 sg:journal.1136317 schema:issn 1070-4280
93 1608-3393
94 schema:name Russian Journal of Organic Chemistry
95 rdf:type schema:Periodical
96 sg:pub.10.1007/s00044-012-0249-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1025040215
97 https://doi.org/10.1007/s00044-012-0249-x
98 rdf:type schema:CreativeWork
99 sg:pub.10.1134/s1070428015010121 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035346549
100 https://doi.org/10.1134/s1070428015010121
101 rdf:type schema:CreativeWork
102 sg:pub.10.1134/s1070428016040254 schema:sameAs https://app.dimensions.ai/details/publication/pub.1037782472
103 https://doi.org/10.1134/s1070428016040254
104 rdf:type schema:CreativeWork
105 sg:pub.10.1134/s1070428017010249 schema:sameAs https://app.dimensions.ai/details/publication/pub.1084223887
106 https://doi.org/10.1134/s1070428017010249
107 rdf:type schema:CreativeWork
108 sg:pub.10.1134/s1070428017100207 schema:sameAs https://app.dimensions.ai/details/publication/pub.1092909928
109 https://doi.org/10.1134/s1070428017100207
110 rdf:type schema:CreativeWork
111 https://doi.org/10.1002/adsc.201100792 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027810079
112 rdf:type schema:CreativeWork
113 https://doi.org/10.1002/cber.19370700917 schema:sameAs https://app.dimensions.ai/details/publication/pub.1039592941
114 rdf:type schema:CreativeWork
115 https://doi.org/10.1016/j.bmcl.2010.05.025 schema:sameAs https://app.dimensions.ai/details/publication/pub.1052809558
116 rdf:type schema:CreativeWork
117 https://doi.org/10.1016/j.bmcl.2012.06.055 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035457237
118 rdf:type schema:CreativeWork
119 https://doi.org/10.1016/j.bmcl.2013.02.086 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033120732
120 rdf:type schema:CreativeWork
121 https://doi.org/10.1016/j.ejmech.2014.03.016 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047483032
122 rdf:type schema:CreativeWork
123 https://doi.org/10.1016/s0040-4020(01)01029-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1023676857
124 rdf:type schema:CreativeWork
125 https://doi.org/10.1039/c4ra16605a schema:sameAs https://app.dimensions.ai/details/publication/pub.1018044157
126 rdf:type schema:CreativeWork
127 https://doi.org/10.1055/s-0033-1341028 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057286371
128 rdf:type schema:CreativeWork
129 https://www.grid.ac/institutes/grid.411669.d schema:alternateName Chuvash State University
130 schema:name I.N. Ul’yanov Chuvash State University, Moskovskii pr. 15, 428015, Cheboksary, Russia
131 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...