Anthracene-Containing Podands, Ion-Active Molecular Switches of Fluorescence Characteristics View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-08

AUTHORS

V. A. Bren’, I. E. Tolpygin, Yu. V. Revinskii, K. S. Tikhomirova, A. D. Dubonosov

ABSTRACT

2,2′-[Ethane-1,2-diylbis(oxy)]bis[N-(anthracen-9-ylmethyl)ethanamine] and its bisphenylthiourea and bisthiourea derivatives have been synthesized. The diamine, being a certain analog of an aza-crown ether with an open chain, exhibits a 50 times increase in the relative fluorescence intensity (off-on process) in the presence of cadmium(II) cations. Bis(phenylthiourea) is a bifunctional fluorophore sensitive to mercury(II) cations (emission flaring) and fluoride anions (emission quenching). Anions F–, CN–, H2PO4–, and AcO– lead to a practically complete quenching of the fluorescent properties of the bis(thiourea) (off-on process). More... »

PAGES

1117-1121

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070428018080018

DOI

http://dx.doi.org/10.1134/s1070428018080018

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1107598800


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