Spectral luminescent properties of 2-aryl-5-(2,4,6-trimethylphenyl)-1Н-1,3,4-oxadiazoles View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2017-05

AUTHORS

Yu. M. Artyushkina, I. E. Mikhailov, G. A. Dushenko, O. I. Mikhailova, Yu. V. Revinskii, O. N. Burov, S. V. Kurbatov

ABSTRACT

Reaction of aroylhydrazides with 2,4,6-trimethylbenzoyl chloride in the presence of Et3N afforded N-(mesityl)aroylhydrazides, which through subsequent cyclization at treatment with SOCl2 resulted in 2-aryl-5-(2,4,6-trimethylphenyl)-1Н-1,3,4-oxadiazoles. For 2-hydroxyphenyl derivative containing a stable O–H N intramolecular bond a low quantum luminescence yield is observed (φ 0.006–0.038) due to the nonradiative deactivation of the agitated state by ESPIT mechanism. More... »

PAGES

808-811

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070428017050281

DOI

http://dx.doi.org/10.1134/s1070428017050281

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1090313721


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