Fused pyrimidine systems: XVII. Arylsulfenylation of 5-allylpyrimidine-4(3H)-one derivatives. Synthesis of arylsulfanyl-substituted 5,6-dihydrofuro[2,3-d]- and 6,7-dihydro-5H-pyrano[2,3-d]pyrimidines View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2017-02

AUTHORS

A. I. Vas’kevich, M. V. Vovk

ABSTRACT

5-Allylpyrimidine-4-ones react with arylsulfenyl chlorides in dichloromethane with the formation of 5-[(2-arylsulfanyl)-3-chloropropyl]-pyrimidine-4-ones that under the action of sodium acetate undergo cyclization into 6-arylsulfanyl-6,7-dihydro-5H-pyrano[2,3-d]pyrimidines. At performing similar reactions in nitromethane an intramolecular electrophilic cyclization occurs affording 6-[(arylsulfanyl)methyl]-5,6-dihydrofuro[2,3-d]pyrimidines.

PAGES

270-276

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070428017020221

DOI

http://dx.doi.org/10.1134/s1070428017020221

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1084861399


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0305", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Organic Chemistry", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "National Technical University of Ukraine, Kiev Polytechnical University, Kiev, Ukraine", 
          "id": "http://www.grid.ac/institutes/grid.440544.5", 
          "name": [
            "Institute of Organic Chemistry of National Academy of Sciences of Ukraine, Murmanskaya ul. 5, 02094, Kiev, Ukraine", 
            "National Technical University of Ukraine, Kiev Polytechnical University, Kiev, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Vas\u2019kevich", 
        "givenName": "A. I.", 
        "id": "sg:person.016422071357.41", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016422071357.41"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry of National Academy of Sciences of Ukraine, Murmanskaya ul. 5, 02094, Kiev, Ukraine", 
          "id": "http://www.grid.ac/institutes/grid.464621.3", 
          "name": [
            "Institute of Organic Chemistry of National Academy of Sciences of Ukraine, Murmanskaya ul. 5, 02094, Kiev, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Vovk", 
        "givenName": "M. V.", 
        "id": "sg:person.013407403301.91", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013407403301.91"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1007/s00044-014-0959-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009328687", 
          "https://doi.org/10.1007/s00044-014-0959-3"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s1070428014100029", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1049692926", 
          "https://doi.org/10.1134/s1070428014100029"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s1070428016050225", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038156417", 
          "https://doi.org/10.1134/s1070428016050225"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2017-02", 
    "datePublishedReg": "2017-02-01", 
    "description": "Abstract5-Allylpyrimidine-4-ones react with arylsulfenyl chlorides in dichloromethane with the formation of 5-[(2-arylsulfanyl)-3-chloropropyl]-pyrimidine-4-ones that under the action of sodium acetate undergo cyclization into 6-arylsulfanyl-6,7-dihydro-5H-pyrano[2,3-d]pyrimidines. At performing similar reactions in nitromethane an intramolecular electrophilic cyclization occurs affording 6-[(arylsulfanyl)methyl]-5,6-dihydrofuro[2,3-d]pyrimidines.", 
    "genre": "article", 
    "id": "sg:pub.10.1134/s1070428017020221", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1136317", 
        "issn": [
          "1070-4280", 
          "1608-3393"
        ], 
        "name": "Russian Journal of Organic Chemistry", 
        "publisher": "Pleiades Publishing", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "2", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "53"
      }
    ], 
    "keywords": [
      "dihydro-5H", 
      "action", 
      "intramolecular electrophilic cyclization", 
      "electrophilic cyclization", 
      "undergo cyclization", 
      "similar reaction", 
      "arylsulfenyl chlorides", 
      "cyclization", 
      "chloride", 
      "reaction", 
      "derivatives", 
      "dichloromethane", 
      "formation", 
      "synthesis", 
      "Abstract5", 
      "XVII", 
      "Arylsulfenylation"
    ], 
    "name": "Fused pyrimidine systems: XVII. Arylsulfenylation of 5-allylpyrimidine-4(3H)-one derivatives. Synthesis of arylsulfanyl-substituted 5,6-dihydrofuro[2,3-d]- and 6,7-dihydro-5H-pyrano[2,3-d]pyrimidines", 
    "pagination": "270-276", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1084861399"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s1070428017020221"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s1070428017020221", 
      "https://app.dimensions.ai/details/publication/pub.1084861399"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-12-01T06:35", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20221201/entities/gbq_results/article/article_727.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1134/s1070428017020221"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1070428017020221'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1070428017020221'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1070428017020221'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1070428017020221'


 

This table displays all metadata directly associated to this object as RDF triples.

97 TRIPLES      21 PREDICATES      45 URIs      34 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s1070428017020221 schema:about anzsrc-for:03
2 anzsrc-for:0305
3 schema:author Ne4e0cfa51652478a8d090cf16078270f
4 schema:citation sg:pub.10.1007/s00044-014-0959-3
5 sg:pub.10.1134/s1070428014100029
6 sg:pub.10.1134/s1070428016050225
7 schema:datePublished 2017-02
8 schema:datePublishedReg 2017-02-01
9 schema:description Abstract5-Allylpyrimidine-4-ones react with arylsulfenyl chlorides in dichloromethane with the formation of 5-[(2-arylsulfanyl)-3-chloropropyl]-pyrimidine-4-ones that under the action of sodium acetate undergo cyclization into 6-arylsulfanyl-6,7-dihydro-5H-pyrano[2,3-d]pyrimidines. At performing similar reactions in nitromethane an intramolecular electrophilic cyclization occurs affording 6-[(arylsulfanyl)methyl]-5,6-dihydrofuro[2,3-d]pyrimidines.
10 schema:genre article
11 schema:isAccessibleForFree false
12 schema:isPartOf N1f7c6b481dc4422a9d5fec9e36e33f37
13 Nf5fb4e87a0af4048874da080df774fbf
14 sg:journal.1136317
15 schema:keywords Abstract5
16 Arylsulfenylation
17 XVII
18 action
19 arylsulfenyl chlorides
20 chloride
21 cyclization
22 derivatives
23 dichloromethane
24 dihydro-5H
25 electrophilic cyclization
26 formation
27 intramolecular electrophilic cyclization
28 reaction
29 similar reaction
30 synthesis
31 undergo cyclization
32 schema:name Fused pyrimidine systems: XVII. Arylsulfenylation of 5-allylpyrimidine-4(3H)-one derivatives. Synthesis of arylsulfanyl-substituted 5,6-dihydrofuro[2,3-d]- and 6,7-dihydro-5H-pyrano[2,3-d]pyrimidines
33 schema:pagination 270-276
34 schema:productId N9e021e9be0f642c7b01cd4041fed271a
35 Ncfc5e7cf63d84a8d900e1a00112d07e1
36 schema:sameAs https://app.dimensions.ai/details/publication/pub.1084861399
37 https://doi.org/10.1134/s1070428017020221
38 schema:sdDatePublished 2022-12-01T06:35
39 schema:sdLicense https://scigraph.springernature.com/explorer/license/
40 schema:sdPublisher N6a270336e2ff404486becc56d98cbd24
41 schema:url https://doi.org/10.1134/s1070428017020221
42 sgo:license sg:explorer/license/
43 sgo:sdDataset articles
44 rdf:type schema:ScholarlyArticle
45 N1f7c6b481dc4422a9d5fec9e36e33f37 schema:issueNumber 2
46 rdf:type schema:PublicationIssue
47 N6a270336e2ff404486becc56d98cbd24 schema:name Springer Nature - SN SciGraph project
48 rdf:type schema:Organization
49 N9e021e9be0f642c7b01cd4041fed271a schema:name dimensions_id
50 schema:value pub.1084861399
51 rdf:type schema:PropertyValue
52 Ncfc5e7cf63d84a8d900e1a00112d07e1 schema:name doi
53 schema:value 10.1134/s1070428017020221
54 rdf:type schema:PropertyValue
55 Ne4e0cfa51652478a8d090cf16078270f rdf:first sg:person.016422071357.41
56 rdf:rest Nf1e6d114ca1b484d907d42324ae5db6d
57 Nf1e6d114ca1b484d907d42324ae5db6d rdf:first sg:person.013407403301.91
58 rdf:rest rdf:nil
59 Nf5fb4e87a0af4048874da080df774fbf schema:volumeNumber 53
60 rdf:type schema:PublicationVolume
61 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
62 schema:name Chemical Sciences
63 rdf:type schema:DefinedTerm
64 anzsrc-for:0305 schema:inDefinedTermSet anzsrc-for:
65 schema:name Organic Chemistry
66 rdf:type schema:DefinedTerm
67 sg:journal.1136317 schema:issn 1070-4280
68 1608-3393
69 schema:name Russian Journal of Organic Chemistry
70 schema:publisher Pleiades Publishing
71 rdf:type schema:Periodical
72 sg:person.013407403301.91 schema:affiliation grid-institutes:grid.464621.3
73 schema:familyName Vovk
74 schema:givenName M. V.
75 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013407403301.91
76 rdf:type schema:Person
77 sg:person.016422071357.41 schema:affiliation grid-institutes:grid.440544.5
78 schema:familyName Vas’kevich
79 schema:givenName A. I.
80 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016422071357.41
81 rdf:type schema:Person
82 sg:pub.10.1007/s00044-014-0959-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1009328687
83 https://doi.org/10.1007/s00044-014-0959-3
84 rdf:type schema:CreativeWork
85 sg:pub.10.1134/s1070428014100029 schema:sameAs https://app.dimensions.ai/details/publication/pub.1049692926
86 https://doi.org/10.1134/s1070428014100029
87 rdf:type schema:CreativeWork
88 sg:pub.10.1134/s1070428016050225 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038156417
89 https://doi.org/10.1134/s1070428016050225
90 rdf:type schema:CreativeWork
91 grid-institutes:grid.440544.5 schema:alternateName National Technical University of Ukraine, Kiev Polytechnical University, Kiev, Ukraine
92 schema:name Institute of Organic Chemistry of National Academy of Sciences of Ukraine, Murmanskaya ul. 5, 02094, Kiev, Ukraine
93 National Technical University of Ukraine, Kiev Polytechnical University, Kiev, Ukraine
94 rdf:type schema:Organization
95 grid-institutes:grid.464621.3 schema:alternateName Institute of Organic Chemistry of National Academy of Sciences of Ukraine, Murmanskaya ul. 5, 02094, Kiev, Ukraine
96 schema:name Institute of Organic Chemistry of National Academy of Sciences of Ukraine, Murmanskaya ul. 5, 02094, Kiev, Ukraine
97 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...