4-Aryl-3-(methanesulfonyl)pyrazolo[5,1-c][1,2,4]triazines and their transformations View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2016-09

AUTHORS

I. V. Ledenyova, P. A. Kartavtsev, Kh. S. Shikhaliev, A. Yu. Egorova

ABSTRACT

Coupling of 3-alkyl-4-aryl-1H-pyrazole-5-diazonium chlorides with methylene-active methyl phenacyl sulfones afforded new pyrazolo[5,1-c][1,2,4]triazine derivatives via cyclization of the corresponding intermediate 1-aryl-2-(hetarylhydrazinylidene)-2-(methanesulfonyl)ethanones. The reactivity of the methanesulfonyl group on C3 of pyrazolo[5,1-c][1,2,4]triazines toward some nucleophiles was studied.

PAGES

1316-1321

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070428016090116

DOI

http://dx.doi.org/10.1134/s1070428016090116

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1011282762


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0399", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Other Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Saratov State University, ul. Astrakhanskaya 83, 410012, Saratov, Russia", 
          "id": "http://www.grid.ac/institutes/grid.446088.6", 
          "name": [
            "Saratov State University, ul. Astrakhanskaya 83, 410012, Saratov, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ledenyova", 
        "givenName": "I. V.", 
        "id": "sg:person.010766270753.75", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010766270753.75"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Voronezh State University, Universitetskaya pl. 1, 394018, Voronezh, Russia", 
          "id": "http://www.grid.ac/institutes/grid.20567.36", 
          "name": [
            "Voronezh State University, Universitetskaya pl. 1, 394018, Voronezh, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kartavtsev", 
        "givenName": "P. A.", 
        "id": "sg:person.010042074525.48", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010042074525.48"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Voronezh State University, Universitetskaya pl. 1, 394018, Voronezh, Russia", 
          "id": "http://www.grid.ac/institutes/grid.20567.36", 
          "name": [
            "Voronezh State University, Universitetskaya pl. 1, 394018, Voronezh, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shikhaliev", 
        "givenName": "Kh. S.", 
        "id": "sg:person.012501266731.37", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012501266731.37"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Saratov State University, ul. Astrakhanskaya 83, 410012, Saratov, Russia", 
          "id": "http://www.grid.ac/institutes/grid.446088.6", 
          "name": [
            "Saratov State University, ul. Astrakhanskaya 83, 410012, Saratov, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Egorova", 
        "givenName": "A. Yu.", 
        "id": "sg:person.01076435630.34", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01076435630.34"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1023/a:1013287918408", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053600391", 
          "https://doi.org/10.1023/a:1013287918408"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10593-014-1585-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011992359", 
          "https://doi.org/10.1007/s10593-014-1585-1"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1023/a:1019631610505", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1026068019", 
          "https://doi.org/10.1023/a:1019631610505"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10593-015-1766-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1008969722", 
          "https://doi.org/10.1007/s10593-015-1766-6"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s11172-008-0130-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1022064675", 
          "https://doi.org/10.1007/s11172-008-0130-8"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2016-09", 
    "datePublishedReg": "2016-09-01", 
    "description": "Coupling of 3-alkyl-4-aryl-1H-pyrazole-5-diazonium chlorides with methylene-active methyl phenacyl sulfones afforded new pyrazolo[5,1-c][1,2,4]triazine derivatives via cyclization of the corresponding intermediate 1-aryl-2-(hetarylhydrazinylidene)-2-(methanesulfonyl)ethanones. The reactivity of the methanesulfonyl group on C3 of pyrazolo[5,1-c][1,2,4]triazines toward some nucleophiles was studied.", 
    "genre": "article", 
    "id": "sg:pub.10.1134/s1070428016090116", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1136317", 
        "issn": [
          "0514-7492", 
          "1070-4280"
        ], 
        "name": "Russian Journal of Organic Chemistry", 
        "publisher": "Pleiades Publishing", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "9", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "52"
      }
    ], 
    "keywords": [
      "group", 
      "C3", 
      "methanesulfonyl group", 
      "reactivity", 
      "derivatives", 
      "chloride", 
      "sulfone", 
      "transformation", 
      "nucleophiles", 
      "cyclization", 
      "methylene-active methyl phenacyl sulfones", 
      "methyl phenacyl sulfones", 
      "phenacyl sulfones"
    ], 
    "name": "4-Aryl-3-(methanesulfonyl)pyrazolo[5,1-c][1,2,4]triazines and their transformations", 
    "pagination": "1316-1321", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1011282762"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s1070428016090116"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s1070428016090116", 
      "https://app.dimensions.ai/details/publication/pub.1011282762"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2021-11-01T18:26", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20211101/entities/gbq_results/article/article_699.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1134/s1070428016090116"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1070428016090116'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1070428016090116'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1070428016090116'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1070428016090116'


 

This table displays all metadata directly associated to this object as RDF triples.

115 TRIPLES      22 PREDICATES      44 URIs      31 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s1070428016090116 schema:about anzsrc-for:03
2 anzsrc-for:0399
3 schema:author N1e1d8f91b11e437da06e0116cdbbac8a
4 schema:citation sg:pub.10.1007/s10593-014-1585-1
5 sg:pub.10.1007/s10593-015-1766-6
6 sg:pub.10.1007/s11172-008-0130-8
7 sg:pub.10.1023/a:1013287918408
8 sg:pub.10.1023/a:1019631610505
9 schema:datePublished 2016-09
10 schema:datePublishedReg 2016-09-01
11 schema:description Coupling of 3-alkyl-4-aryl-1H-pyrazole-5-diazonium chlorides with methylene-active methyl phenacyl sulfones afforded new pyrazolo[5,1-c][1,2,4]triazine derivatives via cyclization of the corresponding intermediate 1-aryl-2-(hetarylhydrazinylidene)-2-(methanesulfonyl)ethanones. The reactivity of the methanesulfonyl group on C3 of pyrazolo[5,1-c][1,2,4]triazines toward some nucleophiles was studied.
12 schema:genre article
13 schema:inLanguage en
14 schema:isAccessibleForFree false
15 schema:isPartOf N3fe60bed8d024406b45cff843348df72
16 Nc2b24b05535c4cab9848c7bba60df629
17 sg:journal.1136317
18 schema:keywords C3
19 chloride
20 cyclization
21 derivatives
22 group
23 methanesulfonyl group
24 methyl phenacyl sulfones
25 methylene-active methyl phenacyl sulfones
26 nucleophiles
27 phenacyl sulfones
28 reactivity
29 sulfone
30 transformation
31 schema:name 4-Aryl-3-(methanesulfonyl)pyrazolo[5,1-c][1,2,4]triazines and their transformations
32 schema:pagination 1316-1321
33 schema:productId N6d9402e44e7a4ba5af59a3df26f87c81
34 Nc226c73bd4be43cfa0ce61957fc01c86
35 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011282762
36 https://doi.org/10.1134/s1070428016090116
37 schema:sdDatePublished 2021-11-01T18:26
38 schema:sdLicense https://scigraph.springernature.com/explorer/license/
39 schema:sdPublisher N90cc9b6938034d2ab40badf054b6b082
40 schema:url https://doi.org/10.1134/s1070428016090116
41 sgo:license sg:explorer/license/
42 sgo:sdDataset articles
43 rdf:type schema:ScholarlyArticle
44 N07414e2f30ed46c0903bd037077c7c15 rdf:first sg:person.01076435630.34
45 rdf:rest rdf:nil
46 N1e1d8f91b11e437da06e0116cdbbac8a rdf:first sg:person.010766270753.75
47 rdf:rest N1f5b984254004ce5b244f929a750490b
48 N1f5b984254004ce5b244f929a750490b rdf:first sg:person.010042074525.48
49 rdf:rest N9d8637bebf2c41638f776b4e81d27525
50 N3fe60bed8d024406b45cff843348df72 schema:volumeNumber 52
51 rdf:type schema:PublicationVolume
52 N6d9402e44e7a4ba5af59a3df26f87c81 schema:name dimensions_id
53 schema:value pub.1011282762
54 rdf:type schema:PropertyValue
55 N90cc9b6938034d2ab40badf054b6b082 schema:name Springer Nature - SN SciGraph project
56 rdf:type schema:Organization
57 N9d8637bebf2c41638f776b4e81d27525 rdf:first sg:person.012501266731.37
58 rdf:rest N07414e2f30ed46c0903bd037077c7c15
59 Nc226c73bd4be43cfa0ce61957fc01c86 schema:name doi
60 schema:value 10.1134/s1070428016090116
61 rdf:type schema:PropertyValue
62 Nc2b24b05535c4cab9848c7bba60df629 schema:issueNumber 9
63 rdf:type schema:PublicationIssue
64 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
65 schema:name Chemical Sciences
66 rdf:type schema:DefinedTerm
67 anzsrc-for:0399 schema:inDefinedTermSet anzsrc-for:
68 schema:name Other Chemical Sciences
69 rdf:type schema:DefinedTerm
70 sg:journal.1136317 schema:issn 0514-7492
71 1070-4280
72 schema:name Russian Journal of Organic Chemistry
73 schema:publisher Pleiades Publishing
74 rdf:type schema:Periodical
75 sg:person.010042074525.48 schema:affiliation grid-institutes:grid.20567.36
76 schema:familyName Kartavtsev
77 schema:givenName P. A.
78 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010042074525.48
79 rdf:type schema:Person
80 sg:person.01076435630.34 schema:affiliation grid-institutes:grid.446088.6
81 schema:familyName Egorova
82 schema:givenName A. Yu.
83 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01076435630.34
84 rdf:type schema:Person
85 sg:person.010766270753.75 schema:affiliation grid-institutes:grid.446088.6
86 schema:familyName Ledenyova
87 schema:givenName I. V.
88 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010766270753.75
89 rdf:type schema:Person
90 sg:person.012501266731.37 schema:affiliation grid-institutes:grid.20567.36
91 schema:familyName Shikhaliev
92 schema:givenName Kh. S.
93 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012501266731.37
94 rdf:type schema:Person
95 sg:pub.10.1007/s10593-014-1585-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011992359
96 https://doi.org/10.1007/s10593-014-1585-1
97 rdf:type schema:CreativeWork
98 sg:pub.10.1007/s10593-015-1766-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1008969722
99 https://doi.org/10.1007/s10593-015-1766-6
100 rdf:type schema:CreativeWork
101 sg:pub.10.1007/s11172-008-0130-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1022064675
102 https://doi.org/10.1007/s11172-008-0130-8
103 rdf:type schema:CreativeWork
104 sg:pub.10.1023/a:1013287918408 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053600391
105 https://doi.org/10.1023/a:1013287918408
106 rdf:type schema:CreativeWork
107 sg:pub.10.1023/a:1019631610505 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026068019
108 https://doi.org/10.1023/a:1019631610505
109 rdf:type schema:CreativeWork
110 grid-institutes:grid.20567.36 schema:alternateName Voronezh State University, Universitetskaya pl. 1, 394018, Voronezh, Russia
111 schema:name Voronezh State University, Universitetskaya pl. 1, 394018, Voronezh, Russia
112 rdf:type schema:Organization
113 grid-institutes:grid.446088.6 schema:alternateName Saratov State University, ul. Astrakhanskaya 83, 410012, Saratov, Russia
114 schema:name Saratov State University, ul. Astrakhanskaya 83, 410012, Saratov, Russia
115 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...