Kinetics and thermochemistry of [2π + 2σ + 2σ]-cycloaddition of quadricyclane to tetracyanoethylene View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2016-06

AUTHORS

V. D. Kiselev, D. A. Kornilov, O. V. Anikin, L. I. Latypova, M. V. Bermeshev, P. P. Chapala, A. I. Konovalov

ABSTRACT

Kinetic data for the unusual [2π + 2σ + 2σ]-cycloaddition of quadricyclane to tetracyanoethylene in toluene have been obtained for the first time. The same reaction in 1,4-dioxane appears to be the most exothermic among known cycloaddition reactions. The entropy of activation and reaction volume differ only slightly from the corresponding parameters of conventional Diels–Alder reactions. More... »

PAGES

777-780

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070428016060038

DOI

http://dx.doi.org/10.1134/s1070428016060038

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1019974169


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