Fused pyrimidine systems: XVI. Electrophilic intramolecular cyclization of 2-(alkenylsulfanyl)pteridin-4(3H)-ones View Full Text


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Article Info

DATE

2016-05

AUTHORS

I. V. Dyachenko, R. I. Vas’kevich, A. I. Vas’kevich, S. V. Shishkina, M. V. Vovk

ABSTRACT

2-[Allyl(but-3-en-1-yl, pent-4-en-1-yl)sulfanyl]pteridin-4(3Н)-ones at heating in polyphosphoric acid undergo an intramolecular cyclization affording respectively 9-methyl-8,9-dihydro-5H-[1,3]thiazolo[3,2-a] pteridin-5-one and 10-methyl(ethyl)-9,10-dihydro-5Н,8Н-[1,3]thiazino[3,2-a]pteridin-5-ones of angular structure. The cyclization of 2-(alkenylsulfanyl)pteridin-4(3Н)-ones under the action of iodine or arylsulfenyl chlorides afforded iodo(arylsulfanyl) derivatives of angularly fuzed thiazolo- and thiazinopteridines.

PAGES

745-752

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070428016050225

DOI

http://dx.doi.org/10.1134/s1070428016050225

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1038156417


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