Synthesis of ferrocenyl-containing heterocyclic derivatives of 5-(4-aminophenyl)-10,15,20-triphenylporphyrin for sonodynamic therapy View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2016-01

AUTHORS

E. Yu. Osipova, A. N. Rodionov, Yu. A. Belousov, M. M. Il’in, A. L. Nikolaev, A. V. Gopin, S. E. Mazina, A. A. Simenel

ABSTRACT

The condensation of 1-(ferrocenylalkyl)pyrazole-3-carbaldehydes with 4′-aminotetraphenylporphyrin, followed by reduction with NaBH(OAc)3 in 1,2-dichloroethane, provides a convenient method for the synthesis of 5-{4-[({1-[1-(ferrocen-1-yl)alkyl]-5-methyl-1H-pyrazol-3-yl}methyl)amino]phenyl}-10,15,20-triphenylporphyrins which exhibit pronounced cytotoxicity against Staphylococcus aureus under ultrasonic irradiation.

PAGES

127-130

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070428016010243

DOI

http://dx.doi.org/10.1134/s1070428016010243

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1002721132


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0305", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Organic Chemistry", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.431939.5", 
          "name": [
            "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Osipova", 
        "givenName": "E. Yu.", 
        "id": "sg:person.014241577207.10", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014241577207.10"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.431939.5", 
          "name": [
            "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Rodionov", 
        "givenName": "A. N.", 
        "id": "sg:person.016212142456.86", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016212142456.86"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.431939.5", 
          "name": [
            "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Belousov", 
        "givenName": "Yu. A.", 
        "id": "sg:person.012244263761.21", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012244263761.21"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.431939.5", 
          "name": [
            "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Il\u2019in", 
        "givenName": "M. M.", 
        "id": "sg:person.015661113163.01", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015661113163.01"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Faculty of Chemistry, Moscow State University, Vorob\u2019evy gory 1, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.14476.30", 
          "name": [
            "Faculty of Chemistry, Moscow State University, Vorob\u2019evy gory 1, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Nikolaev", 
        "givenName": "A. L.", 
        "id": "sg:person.015607407154.80", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015607407154.80"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Faculty of Chemistry, Moscow State University, Vorob\u2019evy gory 1, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.14476.30", 
          "name": [
            "Faculty of Chemistry, Moscow State University, Vorob\u2019evy gory 1, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Gopin", 
        "givenName": "A. V.", 
        "id": "sg:person.015763006737.55", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015763006737.55"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Faculty of Chemistry, Moscow State University, Vorob\u2019evy gory 1, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.14476.30", 
          "name": [
            "Faculty of Chemistry, Moscow State University, Vorob\u2019evy gory 1, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Mazina", 
        "givenName": "S. E.", 
        "id": "sg:person.012345273766.45", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012345273766.45"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "\u201cMoscow Institute of Steel and Alloys\u201d National University of Science and Technology, Leninskii pr. 2, 119049, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.35043.31", 
          "name": [
            "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia", 
            "\u201cMoscow Institute of Steel and Alloys\u201d National University of Science and Technology, Leninskii pr. 2, 119049, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Simenel", 
        "givenName": "A. A.", 
        "id": "sg:person.014345475757.92", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014345475757.92"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1023/b:rucb.0000037868.08052.23", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1046906283", 
          "https://doi.org/10.1023/b:rucb.0000037868.08052.23"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s11172-014-0736-y", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043870335", 
          "https://doi.org/10.1007/s11172-014-0736-y"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2016-01", 
    "datePublishedReg": "2016-01-01", 
    "description": "The condensation of 1-(ferrocenylalkyl)pyrazole-3-carbaldehydes with 4\u2032-aminotetraphenylporphyrin, followed by reduction with NaBH(OAc)3 in 1,2-dichloroethane, provides a convenient method for the synthesis of 5-{4-[({1-[1-(ferrocen-1-yl)alkyl]-5-methyl-1H-pyrazol-3-yl}methyl)amino]phenyl}-10,15,20-triphenylporphyrins which exhibit pronounced cytotoxicity against Staphylococcus aureus under ultrasonic irradiation.", 
    "genre": "article", 
    "id": "sg:pub.10.1134/s1070428016010243", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1136317", 
        "issn": [
          "0514-7492", 
          "1070-4280"
        ], 
        "name": "Russian Journal of Organic Chemistry", 
        "publisher": "Pleiades Publishing", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "52"
      }
    ], 
    "keywords": [
      "heterocyclic derivatives", 
      "ultrasonic irradiation", 
      "triphenylporphyrin", 
      "pronounced cytotoxicity", 
      "convenient method", 
      "synthesis", 
      "sonodynamic therapy", 
      "carbaldehyde", 
      "derivatives", 
      "condensation", 
      "Staphylococcus aureus", 
      "irradiation", 
      "cytotoxicity", 
      "aureus", 
      "reduction", 
      "method", 
      "therapy"
    ], 
    "name": "Synthesis of ferrocenyl-containing heterocyclic derivatives of 5-(4-aminophenyl)-10,15,20-triphenylporphyrin for sonodynamic therapy", 
    "pagination": "127-130", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1002721132"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s1070428016010243"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s1070428016010243", 
      "https://app.dimensions.ai/details/publication/pub.1002721132"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-06-01T22:14", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220601/entities/gbq_results/article/article_704.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1134/s1070428016010243"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1070428016010243'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1070428016010243'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1070428016010243'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1070428016010243'


 

This table displays all metadata directly associated to this object as RDF triples.

139 TRIPLES      22 PREDICATES      45 URIs      35 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s1070428016010243 schema:about anzsrc-for:03
2 anzsrc-for:0305
3 schema:author N46d8787a29ef4f19bd2ac104bd7ae527
4 schema:citation sg:pub.10.1007/s11172-014-0736-y
5 sg:pub.10.1023/b:rucb.0000037868.08052.23
6 schema:datePublished 2016-01
7 schema:datePublishedReg 2016-01-01
8 schema:description The condensation of 1-(ferrocenylalkyl)pyrazole-3-carbaldehydes with 4′-aminotetraphenylporphyrin, followed by reduction with NaBH(OAc)3 in 1,2-dichloroethane, provides a convenient method for the synthesis of 5-{4-[({1-[1-(ferrocen-1-yl)alkyl]-5-methyl-1H-pyrazol-3-yl}methyl)amino]phenyl}-10,15,20-triphenylporphyrins which exhibit pronounced cytotoxicity against Staphylococcus aureus under ultrasonic irradiation.
9 schema:genre article
10 schema:inLanguage en
11 schema:isAccessibleForFree false
12 schema:isPartOf N67e72b652a4340a89e0408bbf6bd1ebf
13 Nf2699df696d74b8ba2be1ba7c870ab3e
14 sg:journal.1136317
15 schema:keywords Staphylococcus aureus
16 aureus
17 carbaldehyde
18 condensation
19 convenient method
20 cytotoxicity
21 derivatives
22 heterocyclic derivatives
23 irradiation
24 method
25 pronounced cytotoxicity
26 reduction
27 sonodynamic therapy
28 synthesis
29 therapy
30 triphenylporphyrin
31 ultrasonic irradiation
32 schema:name Synthesis of ferrocenyl-containing heterocyclic derivatives of 5-(4-aminophenyl)-10,15,20-triphenylporphyrin for sonodynamic therapy
33 schema:pagination 127-130
34 schema:productId N88bd7ac713024b6bbecd91f9e8726ca2
35 Nd54c6c69684040f8b02d00122c6b5652
36 schema:sameAs https://app.dimensions.ai/details/publication/pub.1002721132
37 https://doi.org/10.1134/s1070428016010243
38 schema:sdDatePublished 2022-06-01T22:14
39 schema:sdLicense https://scigraph.springernature.com/explorer/license/
40 schema:sdPublisher N9537d977be77472982819241a5f49d40
41 schema:url https://doi.org/10.1134/s1070428016010243
42 sgo:license sg:explorer/license/
43 sgo:sdDataset articles
44 rdf:type schema:ScholarlyArticle
45 N04619e0007574c90a69bddda587fbee5 rdf:first sg:person.016212142456.86
46 rdf:rest N4a6bd70c8bb9411ebee53b77bdf62c19
47 N25261b8d43a943cc9f04622c78a166a4 rdf:first sg:person.015661113163.01
48 rdf:rest Nbbaeeaf7d9924923a572e6ce6e4d857e
49 N46d8787a29ef4f19bd2ac104bd7ae527 rdf:first sg:person.014241577207.10
50 rdf:rest N04619e0007574c90a69bddda587fbee5
51 N4a6bd70c8bb9411ebee53b77bdf62c19 rdf:first sg:person.012244263761.21
52 rdf:rest N25261b8d43a943cc9f04622c78a166a4
53 N67e72b652a4340a89e0408bbf6bd1ebf schema:issueNumber 1
54 rdf:type schema:PublicationIssue
55 N7fb4316230fb433c8cdeaf537b689d7c rdf:first sg:person.015763006737.55
56 rdf:rest Nd0f49ad6089f4e2f94522692bd49cf49
57 N88bd7ac713024b6bbecd91f9e8726ca2 schema:name dimensions_id
58 schema:value pub.1002721132
59 rdf:type schema:PropertyValue
60 N9537d977be77472982819241a5f49d40 schema:name Springer Nature - SN SciGraph project
61 rdf:type schema:Organization
62 Nbbaeeaf7d9924923a572e6ce6e4d857e rdf:first sg:person.015607407154.80
63 rdf:rest N7fb4316230fb433c8cdeaf537b689d7c
64 Nbdddaf8382d14a1d87abde0cbf6fbea2 rdf:first sg:person.014345475757.92
65 rdf:rest rdf:nil
66 Nd0f49ad6089f4e2f94522692bd49cf49 rdf:first sg:person.012345273766.45
67 rdf:rest Nbdddaf8382d14a1d87abde0cbf6fbea2
68 Nd54c6c69684040f8b02d00122c6b5652 schema:name doi
69 schema:value 10.1134/s1070428016010243
70 rdf:type schema:PropertyValue
71 Nf2699df696d74b8ba2be1ba7c870ab3e schema:volumeNumber 52
72 rdf:type schema:PublicationVolume
73 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
74 schema:name Chemical Sciences
75 rdf:type schema:DefinedTerm
76 anzsrc-for:0305 schema:inDefinedTermSet anzsrc-for:
77 schema:name Organic Chemistry
78 rdf:type schema:DefinedTerm
79 sg:journal.1136317 schema:issn 0514-7492
80 1070-4280
81 schema:name Russian Journal of Organic Chemistry
82 schema:publisher Pleiades Publishing
83 rdf:type schema:Periodical
84 sg:person.012244263761.21 schema:affiliation grid-institutes:grid.431939.5
85 schema:familyName Belousov
86 schema:givenName Yu. A.
87 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012244263761.21
88 rdf:type schema:Person
89 sg:person.012345273766.45 schema:affiliation grid-institutes:grid.14476.30
90 schema:familyName Mazina
91 schema:givenName S. E.
92 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012345273766.45
93 rdf:type schema:Person
94 sg:person.014241577207.10 schema:affiliation grid-institutes:grid.431939.5
95 schema:familyName Osipova
96 schema:givenName E. Yu.
97 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014241577207.10
98 rdf:type schema:Person
99 sg:person.014345475757.92 schema:affiliation grid-institutes:grid.35043.31
100 schema:familyName Simenel
101 schema:givenName A. A.
102 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014345475757.92
103 rdf:type schema:Person
104 sg:person.015607407154.80 schema:affiliation grid-institutes:grid.14476.30
105 schema:familyName Nikolaev
106 schema:givenName A. L.
107 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015607407154.80
108 rdf:type schema:Person
109 sg:person.015661113163.01 schema:affiliation grid-institutes:grid.431939.5
110 schema:familyName Il’in
111 schema:givenName M. M.
112 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015661113163.01
113 rdf:type schema:Person
114 sg:person.015763006737.55 schema:affiliation grid-institutes:grid.14476.30
115 schema:familyName Gopin
116 schema:givenName A. V.
117 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015763006737.55
118 rdf:type schema:Person
119 sg:person.016212142456.86 schema:affiliation grid-institutes:grid.431939.5
120 schema:familyName Rodionov
121 schema:givenName A. N.
122 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016212142456.86
123 rdf:type schema:Person
124 sg:pub.10.1007/s11172-014-0736-y schema:sameAs https://app.dimensions.ai/details/publication/pub.1043870335
125 https://doi.org/10.1007/s11172-014-0736-y
126 rdf:type schema:CreativeWork
127 sg:pub.10.1023/b:rucb.0000037868.08052.23 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046906283
128 https://doi.org/10.1023/b:rucb.0000037868.08052.23
129 rdf:type schema:CreativeWork
130 grid-institutes:grid.14476.30 schema:alternateName Faculty of Chemistry, Moscow State University, Vorob’evy gory 1, 119991, Moscow, Russia
131 schema:name Faculty of Chemistry, Moscow State University, Vorob’evy gory 1, 119991, Moscow, Russia
132 rdf:type schema:Organization
133 grid-institutes:grid.35043.31 schema:alternateName “Moscow Institute of Steel and Alloys” National University of Science and Technology, Leninskii pr. 2, 119049, Moscow, Russia
134 schema:name Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia
135 “Moscow Institute of Steel and Alloys” National University of Science and Technology, Leninskii pr. 2, 119049, Moscow, Russia
136 rdf:type schema:Organization
137 grid-institutes:grid.431939.5 schema:alternateName Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia
138 schema:name Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia
139 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...