Cation-active photochromic molecular swithches based on acylated enamino ketones of benzo[b]thiophene series View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2015-08

AUTHORS

A. D. Dubonosov, K. S. Tikhomirova, E. N. Shepelenko, N. I. Makarova, Zh. V. Bren’, O. I. Dmitrieva, V. A. Bren’, V. I. Minkin

ABSTRACT

Benzo-12-crown-4-containing 2-(N-acyl-N-arylaminomethylidene)benzo[b]thiophene-3(2H)-ones possess the properties of molecular switches based on the photo-initiated Z/E-isomerization with respect to the exocyclic C=C bond followed by a fast thermal N→O migration of the acyl groups (φ 0.19–0.22). In the presence of lithium cation whose diameter suits the best the cavity of 12-crown-4 ether an efficient complex formation is observed resulting in essential growth of the quantum yields of the N→O migration of the acyl groups (φ 0.58–0.63). More... »

PAGES

1096-1100

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070428015080060

DOI

http://dx.doi.org/10.1134/s1070428015080060

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1018589690


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