α,β-Unsaturated ketones based on allobetulone View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2014-07

AUTHORS

N. L. Babak, I. M. Gella, A. N. Semenenko, S. V. Shishkina, O. V. Shishkin, V. I. Musatov, V. V. Lipson

ABSTRACT

Crotonization of allobetulone with aromatic and heteroaromatic aldehydes gave a number of new α,β-unsaturated ketones of the lupane series, and their steric structure was determined by X-ray analysis of (E)-4-[(3-oxoallobetulan-2-ylidene)methyl]benzonitrile as an example.

PAGES

1048-1055

References to SciGraph publications

  • 1930-12. Untersuchungen auf dem Gebiete der Phytochemie in MONATSHEFTE FÜR CHEMIE - CHEMICAL MONTHLY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1134/s1070428014070203

    DOI

    http://dx.doi.org/10.1134/s1070428014070203

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1016522568


    Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
    Incoming Citations Browse incoming citations for this publication using opencitations.net

    JSON-LD is the canonical representation for SciGraph data.

    TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

    [
      {
        "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
        "author": [
          {
            "affiliation": {
              "alternateName": "Institute for Single Crystals", 
              "id": "https://www.grid.ac/institutes/grid.435063.7", 
              "name": [
                "Institute for Single Crystals, National Academy of Sciences of Ukraine, pr. Lenina 60, 61001, Kharkiv, Ukraine"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Babak", 
            "givenName": "N. L.", 
            "id": "sg:person.012275533417.83", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012275533417.83"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "University of Kharkiv", 
              "id": "https://www.grid.ac/institutes/grid.18999.30", 
              "name": [
                "Institute for Single Crystals, National Academy of Sciences of Ukraine, pr. Lenina 60, 61001, Kharkiv, Ukraine", 
                "Karazin Kharkiv National University, pl. Svobody 4, 61022, Kharkiv, Ukraine"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Gella", 
            "givenName": "I. M.", 
            "id": "sg:person.07407207255.27", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07407207255.27"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Institute for Single Crystals", 
              "id": "https://www.grid.ac/institutes/grid.435063.7", 
              "name": [
                "Institute for Single Crystals, National Academy of Sciences of Ukraine, pr. Lenina 60, 61001, Kharkiv, Ukraine"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Semenenko", 
            "givenName": "A. N.", 
            "id": "sg:person.013161406665.04", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013161406665.04"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Institute for Single Crystals", 
              "id": "https://www.grid.ac/institutes/grid.435063.7", 
              "name": [
                "Institute for Single Crystals, National Academy of Sciences of Ukraine, pr. Lenina 60, 61001, Kharkiv, Ukraine"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Shishkina", 
            "givenName": "S. V.", 
            "id": "sg:person.016032264531.19", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016032264531.19"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "University of Kharkiv", 
              "id": "https://www.grid.ac/institutes/grid.18999.30", 
              "name": [
                "Institute for Single Crystals, National Academy of Sciences of Ukraine, pr. Lenina 60, 61001, Kharkiv, Ukraine", 
                "Karazin Kharkiv National University, pl. Svobody 4, 61022, Kharkiv, Ukraine"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Shishkin", 
            "givenName": "O. V.", 
            "id": "sg:person.01023575604.49", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01023575604.49"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Institute for Single Crystals", 
              "id": "https://www.grid.ac/institutes/grid.435063.7", 
              "name": [
                "Institute for Single Crystals, National Academy of Sciences of Ukraine, pr. Lenina 60, 61001, Kharkiv, Ukraine"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Musatov", 
            "givenName": "V. I.", 
            "id": "sg:person.011375757463.27", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011375757463.27"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "National Academy of Medical Sciences of Ukraine", 
              "id": "https://www.grid.ac/institutes/grid.419973.1", 
              "name": [
                "Institute for Single Crystals, National Academy of Sciences of Ukraine, pr. Lenina 60, 61001, Kharkiv, Ukraine", 
                "Karazin Kharkiv National University, pl. Svobody 4, 61022, Kharkiv, Ukraine", 
                "Danilevskii Institute of Endocrine Pathology Problems, National Academy of Medical Sciences of Ukraine, ul. Artema 10, 61002, Kharkiv, Ukraine"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Lipson", 
            "givenName": "V. V.", 
            "id": "sg:person.013636700431.06", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013636700431.06"
            ], 
            "type": "Person"
          }
        ], 
        "citation": [
          {
            "id": "https://doi.org/10.1016/j.ejmech.2011.07.057", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1003292678"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1039/jr9570000935", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1010512635"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1107/s0108767307043930", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1027786902"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1002/cber.19220550814", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1028538570"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1039/b808530g", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1029068233"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02716061", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1029643083", 
              "https://doi.org/10.1007/bf02716061"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf02716061", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1029643083", 
              "https://doi.org/10.1007/bf02716061"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/np200906s", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1032341651"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.3390/molecules16032443", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1033139074"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.3390/molecules16032443", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1033139074"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1002/poc.610030304", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1044730989"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ci049913t", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055401952"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1021/ci049913t", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1055401952"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.1135/cccc19890737", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1062754275"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.2174/0929867053202214", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1069160418"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "https://doi.org/10.2174/092986710790226147", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1069161686"
            ], 
            "type": "CreativeWork"
          }
        ], 
        "datePublished": "2014-07", 
        "datePublishedReg": "2014-07-01", 
        "description": "Crotonization of allobetulone with aromatic and heteroaromatic aldehydes gave a number of new \u03b1,\u03b2-unsaturated ketones of the lupane series, and their steric structure was determined by X-ray analysis of (E)-4-[(3-oxoallobetulan-2-ylidene)methyl]benzonitrile as an example.", 
        "genre": "research_article", 
        "id": "sg:pub.10.1134/s1070428014070203", 
        "inLanguage": [
          "en"
        ], 
        "isAccessibleForFree": false, 
        "isPartOf": [
          {
            "id": "sg:journal.1136317", 
            "issn": [
              "1070-4280", 
              "1608-3393"
            ], 
            "name": "Russian Journal of Organic Chemistry", 
            "type": "Periodical"
          }, 
          {
            "issueNumber": "7", 
            "type": "PublicationIssue"
          }, 
          {
            "type": "PublicationVolume", 
            "volumeNumber": "50"
          }
        ], 
        "name": "\u03b1,\u03b2-Unsaturated ketones based on allobetulone", 
        "pagination": "1048-1055", 
        "productId": [
          {
            "name": "readcube_id", 
            "type": "PropertyValue", 
            "value": [
              "4eb9c671b1509d55a8787dd54d11f53ad335e4e9f555cc15e7c635393bd3d201"
            ]
          }, 
          {
            "name": "doi", 
            "type": "PropertyValue", 
            "value": [
              "10.1134/s1070428014070203"
            ]
          }, 
          {
            "name": "dimensions_id", 
            "type": "PropertyValue", 
            "value": [
              "pub.1016522568"
            ]
          }
        ], 
        "sameAs": [
          "https://doi.org/10.1134/s1070428014070203", 
          "https://app.dimensions.ai/details/publication/pub.1016522568"
        ], 
        "sdDataset": "articles", 
        "sdDatePublished": "2019-04-10T16:40", 
        "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
        "sdPublisher": {
          "name": "Springer Nature - SN SciGraph project", 
          "type": "Organization"
        }, 
        "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8669_00000504.jsonl", 
        "type": "ScholarlyArticle", 
        "url": "http://link.springer.com/10.1134%2FS1070428014070203"
      }
    ]
     

    Download the RDF metadata as:  json-ld nt turtle xml License info

    HOW TO GET THIS DATA PROGRAMMATICALLY:

    JSON-LD is a popular format for linked data which is fully compatible with JSON.

    curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1070428014070203'

    N-Triples is a line-based linked data format ideal for batch operations.

    curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1070428014070203'

    Turtle is a human-readable linked data format.

    curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1070428014070203'

    RDF/XML is a standard XML format for linked data.

    curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1070428014070203'


     

    This table displays all metadata directly associated to this object as RDF triples.

    144 TRIPLES      20 PREDICATES      38 URIs      19 LITERALS      7 BLANK NODES

    Subject Predicate Object
    1 sg:pub.10.1134/s1070428014070203 schema:author N2078012db6a34161b648df6cad3b2f1d
    2 schema:citation sg:pub.10.1007/bf02716061
    3 https://doi.org/10.1002/cber.19220550814
    4 https://doi.org/10.1002/poc.610030304
    5 https://doi.org/10.1016/j.ejmech.2011.07.057
    6 https://doi.org/10.1021/ci049913t
    7 https://doi.org/10.1021/np200906s
    8 https://doi.org/10.1039/b808530g
    9 https://doi.org/10.1039/jr9570000935
    10 https://doi.org/10.1107/s0108767307043930
    11 https://doi.org/10.1135/cccc19890737
    12 https://doi.org/10.2174/0929867053202214
    13 https://doi.org/10.2174/092986710790226147
    14 https://doi.org/10.3390/molecules16032443
    15 schema:datePublished 2014-07
    16 schema:datePublishedReg 2014-07-01
    17 schema:description Crotonization of allobetulone with aromatic and heteroaromatic aldehydes gave a number of new α,β-unsaturated ketones of the lupane series, and their steric structure was determined by X-ray analysis of (E)-4-[(3-oxoallobetulan-2-ylidene)methyl]benzonitrile as an example.
    18 schema:genre research_article
    19 schema:inLanguage en
    20 schema:isAccessibleForFree false
    21 schema:isPartOf N787d42c7cd154810990de875ff7008ea
    22 N80ecb5e218624d6d8b9727359561d075
    23 sg:journal.1136317
    24 schema:name α,β-Unsaturated ketones based on allobetulone
    25 schema:pagination 1048-1055
    26 schema:productId N633efa8d699d40b88a0c52bf5acca231
    27 N813e550092354d0d99cdd5647389e45a
    28 Nc28685d65306494dadbc479ad8fa6f53
    29 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016522568
    30 https://doi.org/10.1134/s1070428014070203
    31 schema:sdDatePublished 2019-04-10T16:40
    32 schema:sdLicense https://scigraph.springernature.com/explorer/license/
    33 schema:sdPublisher N56c839a5d5db4e948c20c286f4254d1c
    34 schema:url http://link.springer.com/10.1134%2FS1070428014070203
    35 sgo:license sg:explorer/license/
    36 sgo:sdDataset articles
    37 rdf:type schema:ScholarlyArticle
    38 N00f7e745092f41aebed401f723b5a98e rdf:first sg:person.013161406665.04
    39 rdf:rest Ne396775049f549b28fc05b033401169e
    40 N2078012db6a34161b648df6cad3b2f1d rdf:first sg:person.012275533417.83
    41 rdf:rest Na28ec485dd8246669642271fb78bc34b
    42 N33a9ccdbecdb4655ac3e545aa682d48a rdf:first sg:person.01023575604.49
    43 rdf:rest Ne0e2eb2cf97049aaa4e0ca56831be85e
    44 N56c839a5d5db4e948c20c286f4254d1c schema:name Springer Nature - SN SciGraph project
    45 rdf:type schema:Organization
    46 N633efa8d699d40b88a0c52bf5acca231 schema:name doi
    47 schema:value 10.1134/s1070428014070203
    48 rdf:type schema:PropertyValue
    49 N787d42c7cd154810990de875ff7008ea schema:volumeNumber 50
    50 rdf:type schema:PublicationVolume
    51 N80ecb5e218624d6d8b9727359561d075 schema:issueNumber 7
    52 rdf:type schema:PublicationIssue
    53 N813e550092354d0d99cdd5647389e45a schema:name readcube_id
    54 schema:value 4eb9c671b1509d55a8787dd54d11f53ad335e4e9f555cc15e7c635393bd3d201
    55 rdf:type schema:PropertyValue
    56 N972ac532f13043198bc4d24c395b8202 rdf:first sg:person.013636700431.06
    57 rdf:rest rdf:nil
    58 Na28ec485dd8246669642271fb78bc34b rdf:first sg:person.07407207255.27
    59 rdf:rest N00f7e745092f41aebed401f723b5a98e
    60 Nc28685d65306494dadbc479ad8fa6f53 schema:name dimensions_id
    61 schema:value pub.1016522568
    62 rdf:type schema:PropertyValue
    63 Ne0e2eb2cf97049aaa4e0ca56831be85e rdf:first sg:person.011375757463.27
    64 rdf:rest N972ac532f13043198bc4d24c395b8202
    65 Ne396775049f549b28fc05b033401169e rdf:first sg:person.016032264531.19
    66 rdf:rest N33a9ccdbecdb4655ac3e545aa682d48a
    67 sg:journal.1136317 schema:issn 1070-4280
    68 1608-3393
    69 schema:name Russian Journal of Organic Chemistry
    70 rdf:type schema:Periodical
    71 sg:person.01023575604.49 schema:affiliation https://www.grid.ac/institutes/grid.18999.30
    72 schema:familyName Shishkin
    73 schema:givenName O. V.
    74 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01023575604.49
    75 rdf:type schema:Person
    76 sg:person.011375757463.27 schema:affiliation https://www.grid.ac/institutes/grid.435063.7
    77 schema:familyName Musatov
    78 schema:givenName V. I.
    79 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011375757463.27
    80 rdf:type schema:Person
    81 sg:person.012275533417.83 schema:affiliation https://www.grid.ac/institutes/grid.435063.7
    82 schema:familyName Babak
    83 schema:givenName N. L.
    84 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012275533417.83
    85 rdf:type schema:Person
    86 sg:person.013161406665.04 schema:affiliation https://www.grid.ac/institutes/grid.435063.7
    87 schema:familyName Semenenko
    88 schema:givenName A. N.
    89 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013161406665.04
    90 rdf:type schema:Person
    91 sg:person.013636700431.06 schema:affiliation https://www.grid.ac/institutes/grid.419973.1
    92 schema:familyName Lipson
    93 schema:givenName V. V.
    94 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013636700431.06
    95 rdf:type schema:Person
    96 sg:person.016032264531.19 schema:affiliation https://www.grid.ac/institutes/grid.435063.7
    97 schema:familyName Shishkina
    98 schema:givenName S. V.
    99 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016032264531.19
    100 rdf:type schema:Person
    101 sg:person.07407207255.27 schema:affiliation https://www.grid.ac/institutes/grid.18999.30
    102 schema:familyName Gella
    103 schema:givenName I. M.
    104 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07407207255.27
    105 rdf:type schema:Person
    106 sg:pub.10.1007/bf02716061 schema:sameAs https://app.dimensions.ai/details/publication/pub.1029643083
    107 https://doi.org/10.1007/bf02716061
    108 rdf:type schema:CreativeWork
    109 https://doi.org/10.1002/cber.19220550814 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028538570
    110 rdf:type schema:CreativeWork
    111 https://doi.org/10.1002/poc.610030304 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044730989
    112 rdf:type schema:CreativeWork
    113 https://doi.org/10.1016/j.ejmech.2011.07.057 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003292678
    114 rdf:type schema:CreativeWork
    115 https://doi.org/10.1021/ci049913t schema:sameAs https://app.dimensions.ai/details/publication/pub.1055401952
    116 rdf:type schema:CreativeWork
    117 https://doi.org/10.1021/np200906s schema:sameAs https://app.dimensions.ai/details/publication/pub.1032341651
    118 rdf:type schema:CreativeWork
    119 https://doi.org/10.1039/b808530g schema:sameAs https://app.dimensions.ai/details/publication/pub.1029068233
    120 rdf:type schema:CreativeWork
    121 https://doi.org/10.1039/jr9570000935 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010512635
    122 rdf:type schema:CreativeWork
    123 https://doi.org/10.1107/s0108767307043930 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027786902
    124 rdf:type schema:CreativeWork
    125 https://doi.org/10.1135/cccc19890737 schema:sameAs https://app.dimensions.ai/details/publication/pub.1062754275
    126 rdf:type schema:CreativeWork
    127 https://doi.org/10.2174/0929867053202214 schema:sameAs https://app.dimensions.ai/details/publication/pub.1069160418
    128 rdf:type schema:CreativeWork
    129 https://doi.org/10.2174/092986710790226147 schema:sameAs https://app.dimensions.ai/details/publication/pub.1069161686
    130 rdf:type schema:CreativeWork
    131 https://doi.org/10.3390/molecules16032443 schema:sameAs https://app.dimensions.ai/details/publication/pub.1033139074
    132 rdf:type schema:CreativeWork
    133 https://www.grid.ac/institutes/grid.18999.30 schema:alternateName University of Kharkiv
    134 schema:name Institute for Single Crystals, National Academy of Sciences of Ukraine, pr. Lenina 60, 61001, Kharkiv, Ukraine
    135 Karazin Kharkiv National University, pl. Svobody 4, 61022, Kharkiv, Ukraine
    136 rdf:type schema:Organization
    137 https://www.grid.ac/institutes/grid.419973.1 schema:alternateName National Academy of Medical Sciences of Ukraine
    138 schema:name Danilevskii Institute of Endocrine Pathology Problems, National Academy of Medical Sciences of Ukraine, ul. Artema 10, 61002, Kharkiv, Ukraine
    139 Institute for Single Crystals, National Academy of Sciences of Ukraine, pr. Lenina 60, 61001, Kharkiv, Ukraine
    140 Karazin Kharkiv National University, pl. Svobody 4, 61022, Kharkiv, Ukraine
    141 rdf:type schema:Organization
    142 https://www.grid.ac/institutes/grid.435063.7 schema:alternateName Institute for Single Crystals
    143 schema:name Institute for Single Crystals, National Academy of Sciences of Ukraine, pr. Lenina 60, 61001, Kharkiv, Ukraine
    144 rdf:type schema:Organization
     




    Preview window. Press ESC to close (or click here)


    ...