Fused pyrimidine systems: XIII. Synthesis and some transformations of 1,3-thiazolo(thiazino)-fused pyrido[3,4-d]pyrimidines View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2014-02

AUTHORS

I. V. Dyachenko, R. I. Vas’kevich, M. V. Vovk

ABSTRACT

2-[Allyl(propargyl)sulfanyl]pyrido[3,4-d]pyrimidin-4-ones at heating in polyphosphoric acid undergo an intramolecular cyclization with the formation of pyrido[4,3-e]thiazolo-[3,2-a]pyrimidin-5-ones of angular structure. Under similar conditions the cyclization of 2-(cinnamylsulfanyl)pyrido[3,4-d]-pyrimidin-4-one results in a linear pyrido[3′,4′:4,5]pyrimido-[2,1-b][1,3]thiazin-6-one. The iodocyclization of the same substrates affords the corresponding 9-(iodomethyl)(iodomethylidene)pyrido[4,3-e][1,3]thiazolo-[3,2-a]pyrimidin-5-ones and 3-iodopyrido[3′,4′:4,5]pyrimido[2,1-b][1,3]thiazin-6-one of angular structure. 9-(Iodomethyl)-8,9-dihydro-5H-pyrido[4,3-e][1,3]thiazolo[3,2-a]pyrimidin-5-one treated with sodium azide gave 9-(azidomethyl) derivative whose cyclization with substituted alkynes in the presence of copper compounds provided pyrido [4,3-e][1,3]thiazolo[3,2-a]pyrimidinylmethyltriazoles. More... »

PAGES

263-270

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070428014020201

DOI

http://dx.doi.org/10.1134/s1070428014020201

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1011002090


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0305", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Organic Chemistry", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 02094, Kiev, Ukraine", 
          "id": "http://www.grid.ac/institutes/grid.464621.3", 
          "name": [
            "Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 02094, Kiev, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Dyachenko", 
        "givenName": "I. V.", 
        "id": "sg:person.012753060373.77", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012753060373.77"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 02094, Kiev, Ukraine", 
          "id": "http://www.grid.ac/institutes/grid.464621.3", 
          "name": [
            "Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 02094, Kiev, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Vas\u2019kevich", 
        "givenName": "R. I.", 
        "id": "sg:person.013174754337.67", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013174754337.67"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 02094, Kiev, Ukraine", 
          "id": "http://www.grid.ac/institutes/grid.464621.3", 
          "name": [
            "Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 02094, Kiev, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Vovk", 
        "givenName": "M. V.", 
        "id": "sg:person.013407403301.91", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013407403301.91"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1134/s1070428008090194", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040149901", 
          "https://doi.org/10.1134/s1070428008090194"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s1070428013080137", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1046677485", 
          "https://doi.org/10.1134/s1070428013080137"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1023/b:cohc.0000003532.58469.cc", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004138425", 
          "https://doi.org/10.1023/b:cohc.0000003532.58469.cc"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2014-02", 
    "datePublishedReg": "2014-02-01", 
    "description": "Abstract2-[Allyl(propargyl)sulfanyl]pyrido[3,4-d]pyrimidin-4-ones at heating in polyphosphoric acid undergo an intramolecular cyclization with the formation of pyrido[4,3-e]thiazolo-[3,2-a]pyrimidin-5-ones of angular structure. Under similar conditions the cyclization of 2-(cinnamylsulfanyl)pyrido[3,4-d]-pyrimidin-4-one results in a linear pyrido[3\u2032,4\u2032:4,5]pyrimido-[2,1-b][1,3]thiazin-6-one. The iodocyclization of the same substrates affords the corresponding 9-(iodomethyl)(iodomethylidene)pyrido[4,3-e][1,3]thiazolo-[3,2-a]pyrimidin-5-ones and 3-iodopyrido[3\u2032,4\u2032:4,5]pyrimido[2,1-b][1,3]thiazin-6-one of angular structure. 9-(Iodomethyl)-8,9-dihydro-5H-pyrido[4,3-e][1,3]thiazolo[3,2-a]pyrimidin-5-one treated with sodium azide gave 9-(azidomethyl) derivative whose cyclization with substituted alkynes in the presence of copper compounds provided pyrido [4,3-e][1,3]thiazolo[3,2-a]pyrimidinylmethyltriazoles.", 
    "genre": "article", 
    "id": "sg:pub.10.1134/s1070428014020201", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1136317", 
        "issn": [
          "0514-7492", 
          "1070-4280"
        ], 
        "name": "Russian Journal of Organic Chemistry", 
        "publisher": "Pleiades Publishing", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "2", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "50"
      }
    ], 
    "keywords": [
      "copper compounds", 
      "substituted alkynes", 
      "intramolecular cyclization", 
      "polyphosphoric acid", 
      "cyclization", 
      "pyrimidin-4", 
      "sodium azide", 
      "dihydro-5H", 
      "same substrate", 
      "similar conditions", 
      "alkynes", 
      "iodocyclization", 
      "azide", 
      "angular structure", 
      "compounds", 
      "synthesis", 
      "Abstract2", 
      "structure", 
      "pyrido", 
      "acid", 
      "substrate", 
      "formation", 
      "presence", 
      "heating", 
      "transformation", 
      "one", 
      "XIII", 
      "conditions"
    ], 
    "name": "Fused pyrimidine systems: XIII. Synthesis and some transformations of 1,3-thiazolo(thiazino)-fused pyrido[3,4-d]pyrimidines", 
    "pagination": "263-270", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1011002090"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s1070428014020201"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s1070428014020201", 
      "https://app.dimensions.ai/details/publication/pub.1011002090"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-05-20T07:28", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220519/entities/gbq_results/article/article_614.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1134/s1070428014020201"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1070428014020201'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1070428014020201'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1070428014020201'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1070428014020201'


 

This table displays all metadata directly associated to this object as RDF triples.

112 TRIPLES      22 PREDICATES      57 URIs      46 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s1070428014020201 schema:about anzsrc-for:03
2 anzsrc-for:0305
3 schema:author Nb6077833671d4a9d882d497fb35d84c2
4 schema:citation sg:pub.10.1023/b:cohc.0000003532.58469.cc
5 sg:pub.10.1134/s1070428008090194
6 sg:pub.10.1134/s1070428013080137
7 schema:datePublished 2014-02
8 schema:datePublishedReg 2014-02-01
9 schema:description Abstract2-[Allyl(propargyl)sulfanyl]pyrido[3,4-d]pyrimidin-4-ones at heating in polyphosphoric acid undergo an intramolecular cyclization with the formation of pyrido[4,3-e]thiazolo-[3,2-a]pyrimidin-5-ones of angular structure. Under similar conditions the cyclization of 2-(cinnamylsulfanyl)pyrido[3,4-d]-pyrimidin-4-one results in a linear pyrido[3′,4′:4,5]pyrimido-[2,1-b][1,3]thiazin-6-one. The iodocyclization of the same substrates affords the corresponding 9-(iodomethyl)(iodomethylidene)pyrido[4,3-e][1,3]thiazolo-[3,2-a]pyrimidin-5-ones and 3-iodopyrido[3′,4′:4,5]pyrimido[2,1-b][1,3]thiazin-6-one of angular structure. 9-(Iodomethyl)-8,9-dihydro-5H-pyrido[4,3-e][1,3]thiazolo[3,2-a]pyrimidin-5-one treated with sodium azide gave 9-(azidomethyl) derivative whose cyclization with substituted alkynes in the presence of copper compounds provided pyrido [4,3-e][1,3]thiazolo[3,2-a]pyrimidinylmethyltriazoles.
10 schema:genre article
11 schema:inLanguage en
12 schema:isAccessibleForFree false
13 schema:isPartOf N9eeee385d5684978880c5a722fa700eb
14 Nbaae64ba9af741a498fd43647409e1a0
15 sg:journal.1136317
16 schema:keywords Abstract2
17 XIII
18 acid
19 alkynes
20 angular structure
21 azide
22 compounds
23 conditions
24 copper compounds
25 cyclization
26 dihydro-5H
27 formation
28 heating
29 intramolecular cyclization
30 iodocyclization
31 one
32 polyphosphoric acid
33 presence
34 pyrido
35 pyrimidin-4
36 same substrate
37 similar conditions
38 sodium azide
39 structure
40 substituted alkynes
41 substrate
42 synthesis
43 transformation
44 schema:name Fused pyrimidine systems: XIII. Synthesis and some transformations of 1,3-thiazolo(thiazino)-fused pyrido[3,4-d]pyrimidines
45 schema:pagination 263-270
46 schema:productId N0b332d8124db41458397882da5a33505
47 N2a7d32d464864240ac8ff039d1981b9e
48 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011002090
49 https://doi.org/10.1134/s1070428014020201
50 schema:sdDatePublished 2022-05-20T07:28
51 schema:sdLicense https://scigraph.springernature.com/explorer/license/
52 schema:sdPublisher N4004a11a65e6464d9f5c40258b44226d
53 schema:url https://doi.org/10.1134/s1070428014020201
54 sgo:license sg:explorer/license/
55 sgo:sdDataset articles
56 rdf:type schema:ScholarlyArticle
57 N0b332d8124db41458397882da5a33505 schema:name dimensions_id
58 schema:value pub.1011002090
59 rdf:type schema:PropertyValue
60 N2a7d32d464864240ac8ff039d1981b9e schema:name doi
61 schema:value 10.1134/s1070428014020201
62 rdf:type schema:PropertyValue
63 N4004a11a65e6464d9f5c40258b44226d schema:name Springer Nature - SN SciGraph project
64 rdf:type schema:Organization
65 N9eeee385d5684978880c5a722fa700eb schema:issueNumber 2
66 rdf:type schema:PublicationIssue
67 Nb6077833671d4a9d882d497fb35d84c2 rdf:first sg:person.012753060373.77
68 rdf:rest Nce5385a2cc5d403aae57074387f63555
69 Nbaae64ba9af741a498fd43647409e1a0 schema:volumeNumber 50
70 rdf:type schema:PublicationVolume
71 Nce5385a2cc5d403aae57074387f63555 rdf:first sg:person.013174754337.67
72 rdf:rest Nf2c9702804e3400a8341b36e638d78e1
73 Nf2c9702804e3400a8341b36e638d78e1 rdf:first sg:person.013407403301.91
74 rdf:rest rdf:nil
75 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
76 schema:name Chemical Sciences
77 rdf:type schema:DefinedTerm
78 anzsrc-for:0305 schema:inDefinedTermSet anzsrc-for:
79 schema:name Organic Chemistry
80 rdf:type schema:DefinedTerm
81 sg:journal.1136317 schema:issn 0514-7492
82 1070-4280
83 schema:name Russian Journal of Organic Chemistry
84 schema:publisher Pleiades Publishing
85 rdf:type schema:Periodical
86 sg:person.012753060373.77 schema:affiliation grid-institutes:grid.464621.3
87 schema:familyName Dyachenko
88 schema:givenName I. V.
89 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012753060373.77
90 rdf:type schema:Person
91 sg:person.013174754337.67 schema:affiliation grid-institutes:grid.464621.3
92 schema:familyName Vas’kevich
93 schema:givenName R. I.
94 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013174754337.67
95 rdf:type schema:Person
96 sg:person.013407403301.91 schema:affiliation grid-institutes:grid.464621.3
97 schema:familyName Vovk
98 schema:givenName M. V.
99 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013407403301.91
100 rdf:type schema:Person
101 sg:pub.10.1023/b:cohc.0000003532.58469.cc schema:sameAs https://app.dimensions.ai/details/publication/pub.1004138425
102 https://doi.org/10.1023/b:cohc.0000003532.58469.cc
103 rdf:type schema:CreativeWork
104 sg:pub.10.1134/s1070428008090194 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040149901
105 https://doi.org/10.1134/s1070428008090194
106 rdf:type schema:CreativeWork
107 sg:pub.10.1134/s1070428013080137 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046677485
108 https://doi.org/10.1134/s1070428013080137
109 rdf:type schema:CreativeWork
110 grid-institutes:grid.464621.3 schema:alternateName Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 02094, Kiev, Ukraine
111 schema:name Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 02094, Kiev, Ukraine
112 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...