Reactions of polyfluoroalkanethioamides with tris(diethylamino)phosphine View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-11

AUTHORS

N. V. Pikun, S. S. Mykhaylychenko, E. B. Rusanov, Yu. G. Shermolovich

ABSTRACT

Structure of reaction products obtained from tris(diethylamino)phosphine with N,Ndialkylpolyfluoroalkanethioamides depends on the length of the polyfluoroalkyl substituent in the latter. In the case of morpholides of perfluorothiopropionic and perfluorothiobutyric acids the main reaction products are fluoro-containing aminoacetylenes: 4-(perfluoroalkan-1-yn-1-yl)morpholines, and also tris(diethylamino)phosphine sulfide and tris(diethylamino)difluorophosphorane. From morpholides or piperidides of ω-H-perfluorothiovaleric acid with a longer perfluoroalkyl substituents amides of cis- and trans-perfluoropent-2-enethiocarboxylic acids were obtained. More... »

PAGES

1572-1579

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070428013110031

DOI

http://dx.doi.org/10.1134/s1070428013110031

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1029367483


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