Reactions of polyfluoroalkanethioamides with tris(diethylamino)phosphine View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-11

AUTHORS

N. V. Pikun, S. S. Mykhaylychenko, E. B. Rusanov, Yu. G. Shermolovich

ABSTRACT

Structure of reaction products obtained from tris(diethylamino)phosphine with N,Ndialkylpolyfluoroalkanethioamides depends on the length of the polyfluoroalkyl substituent in the latter. In the case of morpholides of perfluorothiopropionic and perfluorothiobutyric acids the main reaction products are fluoro-containing aminoacetylenes: 4-(perfluoroalkan-1-yn-1-yl)morpholines, and also tris(diethylamino)phosphine sulfide and tris(diethylamino)difluorophosphorane. From morpholides or piperidides of ω-H-perfluorothiovaleric acid with a longer perfluoroalkyl substituents amides of cis- and trans-perfluoropent-2-enethiocarboxylic acids were obtained. More... »

PAGES

1572-1579

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070428013110031

DOI

http://dx.doi.org/10.1134/s1070428013110031

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1029367483


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0305", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Organic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.464621.3", 
          "name": [
            "Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 02094, Kiev, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Pikun", 
        "givenName": "N. V.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.464621.3", 
          "name": [
            "Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 02094, Kiev, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Mykhaylychenko", 
        "givenName": "S. S.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.464621.3", 
          "name": [
            "Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 02094, Kiev, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Rusanov", 
        "givenName": "E. B.", 
        "id": "sg:person.01247600537.28", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01247600537.28"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.464621.3", 
          "name": [
            "Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 02094, Kiev, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shermolovich", 
        "givenName": "Yu. G.", 
        "id": "sg:person.013103553321.47", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013103553321.47"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/j.tetlet.2011.07.037", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005283017"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jfluchem.2010.06.008", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1018192858"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.tet.2005.11.086", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019742118"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0108767307043930", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027786902"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jfluchem.2003.11.009", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031348483"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/3-540-69197-9_4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034007438", 
          "https://doi.org/10.1007/3-540-69197-9_4"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/3-540-69197-9_4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034007438", 
          "https://doi.org/10.1007/3-540-69197-9_4"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jfluchem.2006.07.006", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1035143957"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jfluchem.2007.02.007", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1037028803"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jfluchem.2005.12.035", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1052580030"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1246/cl.1998.615", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1064486245"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2013-11", 
    "datePublishedReg": "2013-11-01", 
    "description": "Structure of reaction products obtained from tris(diethylamino)phosphine with N,Ndialkylpolyfluoroalkanethioamides depends on the length of the polyfluoroalkyl substituent in the latter. In the case of morpholides of perfluorothiopropionic and perfluorothiobutyric acids the main reaction products are fluoro-containing aminoacetylenes: 4-(perfluoroalkan-1-yn-1-yl)morpholines, and also tris(diethylamino)phosphine sulfide and tris(diethylamino)difluorophosphorane. From morpholides or piperidides of \u03c9-H-perfluorothiovaleric acid with a longer perfluoroalkyl substituents amides of cis- and trans-perfluoropent-2-enethiocarboxylic acids were obtained.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/s1070428013110031", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1136317", 
        "issn": [
          "1070-4280", 
          "1608-3393"
        ], 
        "name": "Russian Journal of Organic Chemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "11", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "49"
      }
    ], 
    "name": "Reactions of polyfluoroalkanethioamides with tris(diethylamino)phosphine", 
    "pagination": "1572-1579", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "8be6e92de3dfeef2f1aaf310dd0a47d26772eac2273e3d3e31dfab8fbab8e556"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s1070428013110031"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1029367483"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s1070428013110031", 
      "https://app.dimensions.ai/details/publication/pub.1029367483"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T19:50", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8681_00000481.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1134/S1070428013110031"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1070428013110031'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1070428013110031'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1070428013110031'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1070428013110031'


 

This table displays all metadata directly associated to this object as RDF triples.

111 TRIPLES      21 PREDICATES      37 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s1070428013110031 schema:about anzsrc-for:03
2 anzsrc-for:0305
3 schema:author N191e3b4df871467f925bd6fc312be6b7
4 schema:citation sg:pub.10.1007/3-540-69197-9_4
5 https://doi.org/10.1016/j.jfluchem.2003.11.009
6 https://doi.org/10.1016/j.jfluchem.2005.12.035
7 https://doi.org/10.1016/j.jfluchem.2006.07.006
8 https://doi.org/10.1016/j.jfluchem.2007.02.007
9 https://doi.org/10.1016/j.jfluchem.2010.06.008
10 https://doi.org/10.1016/j.tet.2005.11.086
11 https://doi.org/10.1016/j.tetlet.2011.07.037
12 https://doi.org/10.1107/s0108767307043930
13 https://doi.org/10.1246/cl.1998.615
14 schema:datePublished 2013-11
15 schema:datePublishedReg 2013-11-01
16 schema:description Structure of reaction products obtained from tris(diethylamino)phosphine with N,Ndialkylpolyfluoroalkanethioamides depends on the length of the polyfluoroalkyl substituent in the latter. In the case of morpholides of perfluorothiopropionic and perfluorothiobutyric acids the main reaction products are fluoro-containing aminoacetylenes: 4-(perfluoroalkan-1-yn-1-yl)morpholines, and also tris(diethylamino)phosphine sulfide and tris(diethylamino)difluorophosphorane. From morpholides or piperidides of ω-H-perfluorothiovaleric acid with a longer perfluoroalkyl substituents amides of cis- and trans-perfluoropent-2-enethiocarboxylic acids were obtained.
17 schema:genre research_article
18 schema:inLanguage en
19 schema:isAccessibleForFree false
20 schema:isPartOf N1d8ad6d41b6c45e5951ad78b9fef3d4b
21 N4ab5226becb5464888c1cacd6a16ecb7
22 sg:journal.1136317
23 schema:name Reactions of polyfluoroalkanethioamides with tris(diethylamino)phosphine
24 schema:pagination 1572-1579
25 schema:productId N1fca3a485d25469a8765af74c1c6a8ae
26 N27b7991da1424510874b1533d29e416d
27 N9831b32a0cbb42f692513e85110b7cf0
28 schema:sameAs https://app.dimensions.ai/details/publication/pub.1029367483
29 https://doi.org/10.1134/s1070428013110031
30 schema:sdDatePublished 2019-04-10T19:50
31 schema:sdLicense https://scigraph.springernature.com/explorer/license/
32 schema:sdPublisher N33d0505dd7604383ba0fa5e5a1853ffa
33 schema:url http://link.springer.com/10.1134/S1070428013110031
34 sgo:license sg:explorer/license/
35 sgo:sdDataset articles
36 rdf:type schema:ScholarlyArticle
37 N01e7374f71df4df29d40f5bafd39a074 schema:affiliation https://www.grid.ac/institutes/grid.464621.3
38 schema:familyName Pikun
39 schema:givenName N. V.
40 rdf:type schema:Person
41 N191e3b4df871467f925bd6fc312be6b7 rdf:first N01e7374f71df4df29d40f5bafd39a074
42 rdf:rest Nfadc54e7a12c4fad8ad246a031959027
43 N1d8ad6d41b6c45e5951ad78b9fef3d4b schema:issueNumber 11
44 rdf:type schema:PublicationIssue
45 N1fca3a485d25469a8765af74c1c6a8ae schema:name dimensions_id
46 schema:value pub.1029367483
47 rdf:type schema:PropertyValue
48 N27b7991da1424510874b1533d29e416d schema:name readcube_id
49 schema:value 8be6e92de3dfeef2f1aaf310dd0a47d26772eac2273e3d3e31dfab8fbab8e556
50 rdf:type schema:PropertyValue
51 N2b54e38a071a4696931ddb4934e86a85 schema:affiliation https://www.grid.ac/institutes/grid.464621.3
52 schema:familyName Mykhaylychenko
53 schema:givenName S. S.
54 rdf:type schema:Person
55 N33d0505dd7604383ba0fa5e5a1853ffa schema:name Springer Nature - SN SciGraph project
56 rdf:type schema:Organization
57 N4ab5226becb5464888c1cacd6a16ecb7 schema:volumeNumber 49
58 rdf:type schema:PublicationVolume
59 N9831b32a0cbb42f692513e85110b7cf0 schema:name doi
60 schema:value 10.1134/s1070428013110031
61 rdf:type schema:PropertyValue
62 Na264ed86041948788bf371140e9b97c3 rdf:first sg:person.013103553321.47
63 rdf:rest rdf:nil
64 Nec83d18368b94ce29bbc6f5880110a32 rdf:first sg:person.01247600537.28
65 rdf:rest Na264ed86041948788bf371140e9b97c3
66 Nfadc54e7a12c4fad8ad246a031959027 rdf:first N2b54e38a071a4696931ddb4934e86a85
67 rdf:rest Nec83d18368b94ce29bbc6f5880110a32
68 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
69 schema:name Chemical Sciences
70 rdf:type schema:DefinedTerm
71 anzsrc-for:0305 schema:inDefinedTermSet anzsrc-for:
72 schema:name Organic Chemistry
73 rdf:type schema:DefinedTerm
74 sg:journal.1136317 schema:issn 1070-4280
75 1608-3393
76 schema:name Russian Journal of Organic Chemistry
77 rdf:type schema:Periodical
78 sg:person.01247600537.28 schema:affiliation https://www.grid.ac/institutes/grid.464621.3
79 schema:familyName Rusanov
80 schema:givenName E. B.
81 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01247600537.28
82 rdf:type schema:Person
83 sg:person.013103553321.47 schema:affiliation https://www.grid.ac/institutes/grid.464621.3
84 schema:familyName Shermolovich
85 schema:givenName Yu. G.
86 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013103553321.47
87 rdf:type schema:Person
88 sg:pub.10.1007/3-540-69197-9_4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034007438
89 https://doi.org/10.1007/3-540-69197-9_4
90 rdf:type schema:CreativeWork
91 https://doi.org/10.1016/j.jfluchem.2003.11.009 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031348483
92 rdf:type schema:CreativeWork
93 https://doi.org/10.1016/j.jfluchem.2005.12.035 schema:sameAs https://app.dimensions.ai/details/publication/pub.1052580030
94 rdf:type schema:CreativeWork
95 https://doi.org/10.1016/j.jfluchem.2006.07.006 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035143957
96 rdf:type schema:CreativeWork
97 https://doi.org/10.1016/j.jfluchem.2007.02.007 schema:sameAs https://app.dimensions.ai/details/publication/pub.1037028803
98 rdf:type schema:CreativeWork
99 https://doi.org/10.1016/j.jfluchem.2010.06.008 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018192858
100 rdf:type schema:CreativeWork
101 https://doi.org/10.1016/j.tet.2005.11.086 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019742118
102 rdf:type schema:CreativeWork
103 https://doi.org/10.1016/j.tetlet.2011.07.037 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005283017
104 rdf:type schema:CreativeWork
105 https://doi.org/10.1107/s0108767307043930 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027786902
106 rdf:type schema:CreativeWork
107 https://doi.org/10.1246/cl.1998.615 schema:sameAs https://app.dimensions.ai/details/publication/pub.1064486245
108 rdf:type schema:CreativeWork
109 https://www.grid.ac/institutes/grid.464621.3 schema:alternateName Institute of Organic Chemistry
110 schema:name Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 02094, Kiev, Ukraine
111 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...