Electrophilic intramolecular cyclization of functional derivatives of unsaturated compounds: V. Cyclization of anilides of styrylacetic acids in polyphosphoric acid View Full Text


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Article Info

DATE

2013-08

AUTHORS

R. I. Vas’kevich, A. I. Vas’kevich, I. Yu. Daniluk, M. V. Vovk

ABSTRACT

Anilides of styrylacetic acids at heating in polyphosphoric acid undergo an intramolecular cyclization giving 1,5-diarylpyrrolidin-2-ones, 5-aryl-1,3,4,5-tetrahydro-2H-benzazepin-2-ones, and 5-(3-fluorophenyl) dihydrofuran-2(3H)-one, where the ratio of the products depends on the character of the aromatic substituents in the amide and styrene fragments of the substrate.

PAGES

1175-1181

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070428013080137

DOI

http://dx.doi.org/10.1134/s1070428013080137

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1046677485


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