Protonation of 1,2,4-triazine 4-oxides View Full Text


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Article Info

DATE

2013-03

AUTHORS

R. E. Trifonov, V. A. Ostrovskii, V. L. Rusinov, O. N. Chupakhin

ABSTRACT

The basicity of some 1,2,4-triazine 4-oxides was estimated on a quantitative level, and their probable protonation patterns were ascertained. The dissociation constants of mono- and diprotonated 3-R-6-phenyl-1,2,4-triazine 4-oxides in aqueous buffer solutions and aqueous sulfuric acid solutions were determined (6-phenyl-1,2,4-triazine 4-oxide: , ). According to the results of DFT calculations (B3LYP/6-311**) and spectral data, first protonation of 1,2,4-triazine 4-oxides involves the N1 nitrogen atom, and the second proton adds to the N-oxide oxygen atom. More... »

PAGES

450-454

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070428013030238

DOI

http://dx.doi.org/10.1134/s1070428013030238

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1004236775


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