Vinyltetrazoles: III. Metal-catalyzed arylation, a new method of vinyltetrazoles functionalization View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-11

AUTHORS

P. A. Aleshunin, K. A. Esikov, F. M. Dolgushin, V. A. Ostrovskii

ABSTRACT

New functionalization procedure was developed for C- and N-vinyltetrazoles based on Heck reaction. Applying this method diverse (E)-styryl- and (E)-distyryltetrazoles were obtained for the first time in 76–85% yields. C-Vinyltetrazoles are more reactive in Heck cross-coupling than N-vinyltetrazoles. The arylation of 1-vinyltetrazole along Heck reaction proceeds with a C-H-activation and leads to the formation of 5-phenyl-1-[2-(E)-phenylethenyl]tetrazole. More... »

PAGES

1464-1472

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070428012110097

DOI

http://dx.doi.org/10.1134/s1070428012110097

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1016061816


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