Synthesis, structure, and luminescent properties of 2-[2-(9-anthryl)vinyl]quinolines View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-01

AUTHORS

O. V. Serdyuk, I. V. Evseenko, G. A. Dushenko, Yu. V. Revinskii, I. E. Mikhailov

ABSTRACT

Previously unknown 2-[2-(9-anthryl)vinyl]quinolin-8-ol and 2-[2-(9-anthryl)vinyl]-8-methoxyquinoline were synthesized by condensation of 8-hydroxy(methoxy)-2-methylquinoline with 9-anthraldehyde in acetic anhydride, as well as by the Wittig reaction. The product structure was determined on the basis of their 1H NMR, IR, UV, and mass spectra and quantum-chemical calculations. 2-[2-(9-Anthryl)vinyl]-8-methoxyquinoline showed luminescence with a quantum yield φ of 0.25, which was considerably higher than that of its 8-hydroxy analog (φ = 0.067). More... »

PAGES

78-82

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070428012010113

DOI

http://dx.doi.org/10.1134/s1070428012010113

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1044283025


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0305", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Organic Chemistry", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Southern Federal University, Rostov-on-Don, Russia", 
          "id": "http://www.grid.ac/institutes/grid.182798.d", 
          "name": [
            "Southern Federal University, Rostov-on-Don, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Serdyuk", 
        "givenName": "O. V.", 
        "id": "sg:person.014464216573.01", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014464216573.01"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Southern Federal University, Rostov-on-Don, Russia", 
          "id": "http://www.grid.ac/institutes/grid.182798.d", 
          "name": [
            "Southern Federal University, Rostov-on-Don, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Evseenko", 
        "givenName": "I. V.", 
        "id": "sg:person.010324200243.28", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010324200243.28"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Southern Research Center, Russian Academy of Sciences, pr. Stachki 194/2, 344090, Rostov-on-Don, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Southern Research Center, Russian Academy of Sciences, pr. Stachki 194/2, 344090, Rostov-on-Don, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Dushenko", 
        "givenName": "G. A.", 
        "id": "sg:person.015115321715.66", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015115321715.66"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Southern Research Center, Russian Academy of Sciences, pr. Stachki 194/2, 344090, Rostov-on-Don, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Southern Research Center, Russian Academy of Sciences, pr. Stachki 194/2, 344090, Rostov-on-Don, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Revinskii", 
        "givenName": "Yu. V.", 
        "id": "sg:person.07435241541.11", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07435241541.11"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Southern Research Center, Russian Academy of Sciences, pr. Stachki 194/2, 344090, Rostov-on-Don, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Southern Research Center, Russian Academy of Sciences, pr. Stachki 194/2, 344090, Rostov-on-Don, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Mikhailov", 
        "givenName": "I. E.", 
        "id": "sg:person.016631604463.46", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016631604463.46"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "2012-01", 
    "datePublishedReg": "2012-01-01", 
    "description": "Previously unknown 2-[2-(9-anthryl)vinyl]quinolin-8-ol and 2-[2-(9-anthryl)vinyl]-8-methoxyquinoline were synthesized by condensation of 8-hydroxy(methoxy)-2-methylquinoline with 9-anthraldehyde in acetic anhydride, as well as by the Wittig reaction. The product structure was determined on the basis of their 1H NMR, IR, UV, and mass spectra and quantum-chemical calculations. 2-[2-(9-Anthryl)vinyl]-8-methoxyquinoline showed luminescence with a quantum yield \u03c6 of 0.25, which was considerably higher than that of its 8-hydroxy analog (\u03c6 = 0.067).", 
    "genre": "article", 
    "id": "sg:pub.10.1134/s1070428012010113", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1136317", 
        "issn": [
          "1070-4280", 
          "1608-3393"
        ], 
        "name": "Russian Journal of Organic Chemistry", 
        "publisher": "Pleiades Publishing", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "48"
      }
    ], 
    "keywords": [
      "quantum chemical calculations", 
      "quantum yield \u03a6", 
      "luminescent properties", 
      "Wittig reaction", 
      "mass spectra", 
      "yield \u03a6", 
      "acetic anhydride", 
      "methoxyquinoline", 
      "product structure", 
      "NMR", 
      "IR", 
      "UV", 
      "anhydride", 
      "methylquinolines", 
      "synthesis", 
      "luminescence", 
      "structure", 
      "reaction", 
      "ol", 
      "condensation", 
      "spectra", 
      "analogues", 
      "properties", 
      "calculations", 
      "basis"
    ], 
    "name": "Synthesis, structure, and luminescent properties of 2-[2-(9-anthryl)vinyl]quinolines", 
    "pagination": "78-82", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1044283025"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s1070428012010113"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s1070428012010113", 
      "https://app.dimensions.ai/details/publication/pub.1044283025"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-09-02T15:55", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220902/entities/gbq_results/article/article_569.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1134/s1070428012010113"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1070428012010113'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1070428012010113'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1070428012010113'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1070428012010113'


 

This table displays all metadata directly associated to this object as RDF triples.

113 TRIPLES      20 PREDICATES      50 URIs      42 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s1070428012010113 schema:about anzsrc-for:03
2 anzsrc-for:0305
3 schema:author Nfff67954803d4fb4a59b028363f1eba1
4 schema:datePublished 2012-01
5 schema:datePublishedReg 2012-01-01
6 schema:description Previously unknown 2-[2-(9-anthryl)vinyl]quinolin-8-ol and 2-[2-(9-anthryl)vinyl]-8-methoxyquinoline were synthesized by condensation of 8-hydroxy(methoxy)-2-methylquinoline with 9-anthraldehyde in acetic anhydride, as well as by the Wittig reaction. The product structure was determined on the basis of their 1H NMR, IR, UV, and mass spectra and quantum-chemical calculations. 2-[2-(9-Anthryl)vinyl]-8-methoxyquinoline showed luminescence with a quantum yield φ of 0.25, which was considerably higher than that of its 8-hydroxy analog (φ = 0.067).
7 schema:genre article
8 schema:isAccessibleForFree false
9 schema:isPartOf Nc6af3aeddfff413bbdd55fe194cd132f
10 Nf4297c0807664be8abccaf9dc86c29e2
11 sg:journal.1136317
12 schema:keywords IR
13 NMR
14 UV
15 Wittig reaction
16 acetic anhydride
17 analogues
18 anhydride
19 basis
20 calculations
21 condensation
22 luminescence
23 luminescent properties
24 mass spectra
25 methoxyquinoline
26 methylquinolines
27 ol
28 product structure
29 properties
30 quantum chemical calculations
31 quantum yield Φ
32 reaction
33 spectra
34 structure
35 synthesis
36 yield Φ
37 schema:name Synthesis, structure, and luminescent properties of 2-[2-(9-anthryl)vinyl]quinolines
38 schema:pagination 78-82
39 schema:productId N9d4e97850f014576a9df617b7f9c306f
40 Nad3705ca122448678fd99fffce677229
41 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044283025
42 https://doi.org/10.1134/s1070428012010113
43 schema:sdDatePublished 2022-09-02T15:55
44 schema:sdLicense https://scigraph.springernature.com/explorer/license/
45 schema:sdPublisher N33791ffe267d45dbb9acf75bd12d37db
46 schema:url https://doi.org/10.1134/s1070428012010113
47 sgo:license sg:explorer/license/
48 sgo:sdDataset articles
49 rdf:type schema:ScholarlyArticle
50 N27c5fd641a354e62bb88d54651f6e7a1 rdf:first sg:person.010324200243.28
51 rdf:rest N6655d41bee22418ab698136aea2b97ef
52 N33791ffe267d45dbb9acf75bd12d37db schema:name Springer Nature - SN SciGraph project
53 rdf:type schema:Organization
54 N3af7dc6270f24a969a9378867fd31358 rdf:first sg:person.07435241541.11
55 rdf:rest N5bf6d11f4dbd47b185e639b211bfb74b
56 N5bf6d11f4dbd47b185e639b211bfb74b rdf:first sg:person.016631604463.46
57 rdf:rest rdf:nil
58 N6655d41bee22418ab698136aea2b97ef rdf:first sg:person.015115321715.66
59 rdf:rest N3af7dc6270f24a969a9378867fd31358
60 N9d4e97850f014576a9df617b7f9c306f schema:name doi
61 schema:value 10.1134/s1070428012010113
62 rdf:type schema:PropertyValue
63 Nad3705ca122448678fd99fffce677229 schema:name dimensions_id
64 schema:value pub.1044283025
65 rdf:type schema:PropertyValue
66 Nc6af3aeddfff413bbdd55fe194cd132f schema:issueNumber 1
67 rdf:type schema:PublicationIssue
68 Nf4297c0807664be8abccaf9dc86c29e2 schema:volumeNumber 48
69 rdf:type schema:PublicationVolume
70 Nfff67954803d4fb4a59b028363f1eba1 rdf:first sg:person.014464216573.01
71 rdf:rest N27c5fd641a354e62bb88d54651f6e7a1
72 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
73 schema:name Chemical Sciences
74 rdf:type schema:DefinedTerm
75 anzsrc-for:0305 schema:inDefinedTermSet anzsrc-for:
76 schema:name Organic Chemistry
77 rdf:type schema:DefinedTerm
78 sg:journal.1136317 schema:issn 1070-4280
79 1608-3393
80 schema:name Russian Journal of Organic Chemistry
81 schema:publisher Pleiades Publishing
82 rdf:type schema:Periodical
83 sg:person.010324200243.28 schema:affiliation grid-institutes:grid.182798.d
84 schema:familyName Evseenko
85 schema:givenName I. V.
86 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010324200243.28
87 rdf:type schema:Person
88 sg:person.014464216573.01 schema:affiliation grid-institutes:grid.182798.d
89 schema:familyName Serdyuk
90 schema:givenName O. V.
91 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014464216573.01
92 rdf:type schema:Person
93 sg:person.015115321715.66 schema:affiliation grid-institutes:grid.4886.2
94 schema:familyName Dushenko
95 schema:givenName G. A.
96 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015115321715.66
97 rdf:type schema:Person
98 sg:person.016631604463.46 schema:affiliation grid-institutes:grid.4886.2
99 schema:familyName Mikhailov
100 schema:givenName I. E.
101 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016631604463.46
102 rdf:type schema:Person
103 sg:person.07435241541.11 schema:affiliation grid-institutes:grid.4886.2
104 schema:familyName Revinskii
105 schema:givenName Yu. V.
106 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07435241541.11
107 rdf:type schema:Person
108 grid-institutes:grid.182798.d schema:alternateName Southern Federal University, Rostov-on-Don, Russia
109 schema:name Southern Federal University, Rostov-on-Don, Russia
110 rdf:type schema:Organization
111 grid-institutes:grid.4886.2 schema:alternateName Southern Research Center, Russian Academy of Sciences, pr. Stachki 194/2, 344090, Rostov-on-Don, Russia
112 schema:name Southern Research Center, Russian Academy of Sciences, pr. Stachki 194/2, 344090, Rostov-on-Don, Russia
113 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...