Photo- and ionochromic indoline spiropyrans based on 7,8-dihydroxy-4-methyl-2-oxo-2H-chromene-6-carbaldehyde View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-09

AUTHORS

O. G. Nikolaeva, O. Yu. Kostyrina, E. N. Shepelenko, A. V. Tsukanov, A. V. Metelitsa, G. S. Borodkin, A. D. Dubonosov, V. A. Bren’, V. I. Minkin

ABSTRACT

A number of indoline spiropyrans were synthesized from 7,8-dihydroxy-4-methyl-2-oxo-2H-chromene-6-carbaldehyde. The products were found to exhibit both photochromic and ionochromic properties. According to the UV, IR, and 1H NMR spectral data, they exist in the spiro form. Irradiation at λ 365 nm in 2-methylbutane-propan-2-ol (4:1) at 203 K induces their isomerization into colored merocyanine structure. Addition of alkaline earth and transition metal salts to acetonitrile solutions of these compounds at room temperature changes the isomer ratio and leads to formation of merocyanine complexes characterized by different colors, so that visual detection of Zn2+, Mg2+, Hg2+, and Pb2+ ions is possible. More... »

PAGES

1370

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070428011090193

DOI

http://dx.doi.org/10.1134/s1070428011090193

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1050713032


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