Thiomethylation of heteroaromatic amines View Full Text


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Article Info

DATE

2011-06

AUTHORS

V. R. Akhmetova, Z. T. Niatshina, Z. A. Starikova, L. F. Korzhova, A. G. Ibragimov

ABSTRACT

Thiomethylation of heteroaromatic amines with formaldehyde-hydrogen sulfide gave linear and cyclic heteroatom compounds: N,N′-[methylenebis(sulfanediylmethylene)]bishetarenamines and 5-hetaryl-1,3,5-dithiazinanes. N,N′-[Methylenebis(sulfanediylmethylene)]bishetarenamines were found to undergo transformation into 5-hetaryl-1,3,5-dithiazinanes by the action of CH2O-H2S. Transamination of 5-methyl-1Hpyrazol-3-amine, 6-nitro-1,3-benzothiazol-2-amine, and 5-bromopyridin-2-amine with 5-methyl-1,3,5-dithiazinane selectively afforded the corresponding 5-hetaryl-1,3,5-dithiazinanes.

PAGES

920-927

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070428011060157

DOI

http://dx.doi.org/10.1134/s1070428011060157

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1009855599


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