Synthesis and Some Chemical Transformations of Adamantyl-Substituted Pyrazolones View Full Text


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Article Info

DATE

2010-10

AUTHORS

K. M. Bormasheva, S. A. Kon’kov, I. K. Moiseev

ABSTRACT

1-Substituted 3-(1-adamantyl)-4,5-dihydro-1H-pyrazol–5-ones and 3-(1-adamantyl)-4,5-dihydroiso-xazol-5-one were synthesized by reaction of ethyl 3-(1-adamantyl)-3-oxopropanoate with various hydrazine derivatives and hydroxylamine hydrochloride. Nitrosation of adamantyl-substituted pyrazolones with sodium nitrite in acetic acid gave the corresponding 4-hydroxyimino derivatives. Reactions of 3-(1-adamantyl)-4,5-di-hydro-1H-pyrazol–5-ones and 3-(1-adamantyl)-4,5-dihydroisoxazol–5-one with aromatic and heterocyclic aldehydes led to the formation of condensation products at position 4 of the heteroring. More... »

PAGES

1558-1562

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070428010100209

DOI

http://dx.doi.org/10.1134/s1070428010100209

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1044305672


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