Five-membered 2,3-dioxo heterocycles: LXX. Spiro heterocyclization of 1H-pyrrole-2,3-diones by the action of 1,5-binucleophiles. Crystalline and molecular structure of ethyl 1′-benzyl-7-methoxy-3,3-dimethyl-1,2′-dioxo-5′-phenyl-1′,2,2′,3,4,10-hexahydro-1H-spiro[acridine-9,3′-pyrrole]-4′-carboxylate View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2010-08

AUTHORS

P. S. Silaichev, M. V. Dmitriev, Z. G. Aliev, A. N. Maslivets

ABSTRACT

Ethyl 1-alkyl-4,5-dioxo-2-phenyl-4,5-dihydro-1H-pyrrole-3-carboxylates reacted with 3-arylamino-5,5-dimethylcyclohex-2-en-1-ones as carbon-centered 1,5-binucleophiles to give the corresponding substituted ethyl 1′-alkyl-3,3-dimethyl-1,2′-dioxo-5′-phenyl-1′,2,2′,3,4,10-hexahydro-1H-spiro[acridine-9,3′-pyrrole]-4′-carboxylates whose structure was proved by X-ray analysis.

PAGES

1173-1177

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070428010080105

DOI

http://dx.doi.org/10.1134/s1070428010080105

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1028905892


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Perm State University, ul. Bukireva 15, 614990, Perm, Russia", 
          "id": "http://www.grid.ac/institutes/grid.77611.36", 
          "name": [
            "Perm State University, ul. Bukireva 15, 614990, Perm, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Silaichev", 
        "givenName": "P. S.", 
        "id": "sg:person.015746074244.34", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015746074244.34"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Perm State University, ul. Bukireva 15, 614990, Perm, Russia", 
          "id": "http://www.grid.ac/institutes/grid.77611.36", 
          "name": [
            "Perm State University, ul. Bukireva 15, 614990, Perm, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Dmitriev", 
        "givenName": "M. V.", 
        "id": "sg:person.015741240313.37", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015741240313.37"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Chemical Physics Problems, Russian Academy of Sciences, Chernogolovka, Moscow oblast, Russia", 
          "id": "http://www.grid.ac/institutes/grid.418949.9", 
          "name": [
            "Institute of Chemical Physics Problems, Russian Academy of Sciences, Chernogolovka, Moscow oblast, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Aliev", 
        "givenName": "Z. G.", 
        "id": "sg:person.010574144735.96", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010574144735.96"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Perm State University, ul. Bukireva 15, 614990, Perm, Russia", 
          "id": "http://www.grid.ac/institutes/grid.77611.36", 
          "name": [
            "Perm State University, ul. Bukireva 15, 614990, Perm, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Maslivets", 
        "givenName": "A. N.", 
        "id": "sg:person.0662414002.02", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0662414002.02"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1134/s1070428008050278", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1049474773", 
          "https://doi.org/10.1134/s1070428008050278"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s1070428010040159", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042853625", 
          "https://doi.org/10.1134/s1070428010040159"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s1070428009070239", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1049745328", 
          "https://doi.org/10.1134/s1070428009070239"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2010-08", 
    "datePublishedReg": "2010-08-01", 
    "description": "Ethyl 1-alkyl-4,5-dioxo-2-phenyl-4,5-dihydro-1H-pyrrole-3-carboxylates reacted with 3-arylamino-5,5-dimethylcyclohex-2-en-1-ones as carbon-centered 1,5-binucleophiles to give the corresponding substituted ethyl 1\u2032-alkyl-3,3-dimethyl-1,2\u2032-dioxo-5\u2032-phenyl-1\u2032,2,2\u2032,3,4,10-hexahydro-1H-spiro[acridine-9,3\u2032-pyrrole]-4\u2032-carboxylates whose structure was proved by X-ray analysis.", 
    "genre": "article", 
    "id": "sg:pub.10.1134/s1070428010080105", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1136317", 
        "issn": [
          "0514-7492", 
          "1070-4280"
        ], 
        "name": "Russian Journal of Organic Chemistry", 
        "publisher": "Pleiades Publishing", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "8", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "46"
      }
    ], 
    "keywords": [
      "molecular structure", 
      "ray analysis", 
      "ethyl", 
      "heterocycles", 
      "heterocyclization", 
      "structure", 
      "pyrrole-3-carboxylate", 
      "analysis", 
      "action", 
      "LXX", 
      "Spiro heterocyclization"
    ], 
    "name": "Five-membered 2,3-dioxo heterocycles: LXX. Spiro heterocyclization of 1H-pyrrole-2,3-diones by the action of 1,5-binucleophiles. Crystalline and molecular structure of ethyl 1\u2032-benzyl-7-methoxy-3,3-dimethyl-1,2\u2032-dioxo-5\u2032-phenyl-1\u2032,2,2\u2032,3,4,10-hexahydro-1H-spiro[acridine-9,3\u2032-pyrrole]-4\u2032-carboxylate", 
    "pagination": "1173-1177", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1028905892"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s1070428010080105"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s1070428010080105", 
      "https://app.dimensions.ai/details/publication/pub.1028905892"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-01-01T18:21", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220101/entities/gbq_results/article/article_503.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1134/s1070428010080105"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1070428010080105'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1070428010080105'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1070428010080105'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1070428010080105'


 

This table displays all metadata directly associated to this object as RDF triples.

105 TRIPLES      22 PREDICATES      40 URIs      29 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s1070428010080105 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author Nd8694a99eaa74628856c56a5ebda7bf6
4 schema:citation sg:pub.10.1134/s1070428008050278
5 sg:pub.10.1134/s1070428009070239
6 sg:pub.10.1134/s1070428010040159
7 schema:datePublished 2010-08
8 schema:datePublishedReg 2010-08-01
9 schema:description Ethyl 1-alkyl-4,5-dioxo-2-phenyl-4,5-dihydro-1H-pyrrole-3-carboxylates reacted with 3-arylamino-5,5-dimethylcyclohex-2-en-1-ones as carbon-centered 1,5-binucleophiles to give the corresponding substituted ethyl 1′-alkyl-3,3-dimethyl-1,2′-dioxo-5′-phenyl-1′,2,2′,3,4,10-hexahydro-1H-spiro[acridine-9,3′-pyrrole]-4′-carboxylates whose structure was proved by X-ray analysis.
10 schema:genre article
11 schema:inLanguage en
12 schema:isAccessibleForFree false
13 schema:isPartOf N37590aa42fe34a35acc1230103e0743c
14 N47841adefd9849d3a8eba0957d11ed87
15 sg:journal.1136317
16 schema:keywords LXX
17 Spiro heterocyclization
18 action
19 analysis
20 ethyl
21 heterocycles
22 heterocyclization
23 molecular structure
24 pyrrole-3-carboxylate
25 ray analysis
26 structure
27 schema:name Five-membered 2,3-dioxo heterocycles: LXX. Spiro heterocyclization of 1H-pyrrole-2,3-diones by the action of 1,5-binucleophiles. Crystalline and molecular structure of ethyl 1′-benzyl-7-methoxy-3,3-dimethyl-1,2′-dioxo-5′-phenyl-1′,2,2′,3,4,10-hexahydro-1H-spiro[acridine-9,3′-pyrrole]-4′-carboxylate
28 schema:pagination 1173-1177
29 schema:productId N37cd304e822144dea35df0c81eab1b46
30 N764c763fd26543fc863a8a2529e75784
31 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028905892
32 https://doi.org/10.1134/s1070428010080105
33 schema:sdDatePublished 2022-01-01T18:21
34 schema:sdLicense https://scigraph.springernature.com/explorer/license/
35 schema:sdPublisher Nb2b6ff073e9a4f4a80abd5ccb710b662
36 schema:url https://doi.org/10.1134/s1070428010080105
37 sgo:license sg:explorer/license/
38 sgo:sdDataset articles
39 rdf:type schema:ScholarlyArticle
40 N2363eb3999904fd79622184425136a86 rdf:first sg:person.0662414002.02
41 rdf:rest rdf:nil
42 N37590aa42fe34a35acc1230103e0743c schema:volumeNumber 46
43 rdf:type schema:PublicationVolume
44 N37cd304e822144dea35df0c81eab1b46 schema:name doi
45 schema:value 10.1134/s1070428010080105
46 rdf:type schema:PropertyValue
47 N47841adefd9849d3a8eba0957d11ed87 schema:issueNumber 8
48 rdf:type schema:PublicationIssue
49 N56f1296de84a4c088c0d962ec9378de9 rdf:first sg:person.010574144735.96
50 rdf:rest N2363eb3999904fd79622184425136a86
51 N764c763fd26543fc863a8a2529e75784 schema:name dimensions_id
52 schema:value pub.1028905892
53 rdf:type schema:PropertyValue
54 N9e5a971596504eb3b54748f2e298773a rdf:first sg:person.015741240313.37
55 rdf:rest N56f1296de84a4c088c0d962ec9378de9
56 Nb2b6ff073e9a4f4a80abd5ccb710b662 schema:name Springer Nature - SN SciGraph project
57 rdf:type schema:Organization
58 Nd8694a99eaa74628856c56a5ebda7bf6 rdf:first sg:person.015746074244.34
59 rdf:rest N9e5a971596504eb3b54748f2e298773a
60 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
61 schema:name Chemical Sciences
62 rdf:type schema:DefinedTerm
63 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
64 schema:name Physical Chemistry (incl. Structural)
65 rdf:type schema:DefinedTerm
66 sg:journal.1136317 schema:issn 0514-7492
67 1070-4280
68 schema:name Russian Journal of Organic Chemistry
69 schema:publisher Pleiades Publishing
70 rdf:type schema:Periodical
71 sg:person.010574144735.96 schema:affiliation grid-institutes:grid.418949.9
72 schema:familyName Aliev
73 schema:givenName Z. G.
74 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010574144735.96
75 rdf:type schema:Person
76 sg:person.015741240313.37 schema:affiliation grid-institutes:grid.77611.36
77 schema:familyName Dmitriev
78 schema:givenName M. V.
79 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015741240313.37
80 rdf:type schema:Person
81 sg:person.015746074244.34 schema:affiliation grid-institutes:grid.77611.36
82 schema:familyName Silaichev
83 schema:givenName P. S.
84 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015746074244.34
85 rdf:type schema:Person
86 sg:person.0662414002.02 schema:affiliation grid-institutes:grid.77611.36
87 schema:familyName Maslivets
88 schema:givenName A. N.
89 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0662414002.02
90 rdf:type schema:Person
91 sg:pub.10.1134/s1070428008050278 schema:sameAs https://app.dimensions.ai/details/publication/pub.1049474773
92 https://doi.org/10.1134/s1070428008050278
93 rdf:type schema:CreativeWork
94 sg:pub.10.1134/s1070428009070239 schema:sameAs https://app.dimensions.ai/details/publication/pub.1049745328
95 https://doi.org/10.1134/s1070428009070239
96 rdf:type schema:CreativeWork
97 sg:pub.10.1134/s1070428010040159 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042853625
98 https://doi.org/10.1134/s1070428010040159
99 rdf:type schema:CreativeWork
100 grid-institutes:grid.418949.9 schema:alternateName Institute of Chemical Physics Problems, Russian Academy of Sciences, Chernogolovka, Moscow oblast, Russia
101 schema:name Institute of Chemical Physics Problems, Russian Academy of Sciences, Chernogolovka, Moscow oblast, Russia
102 rdf:type schema:Organization
103 grid-institutes:grid.77611.36 schema:alternateName Perm State University, ul. Bukireva 15, 614990, Perm, Russia
104 schema:name Perm State University, ul. Bukireva 15, 614990, Perm, Russia
105 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...