Comparison of different reducing systems in the synthesis of functionally substituted benzylamines from alkyl aryl ketones and aromatic aldehydes View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2010-07

AUTHORS

D. M. Musatov, E. V. Starodubtseva, O. V. Turova, D. V. Kurilov, M. G. Vinogradov, A. K. Rakishev, M. I. Struchkova

ABSTRACT

Different synthetic approaches to functionally substituted benzylamines were examined: reductive amination of alkyl aryl ketones and reduction of aromatic aldehyde oximes. The most efficient procedures were used to prepare a series of previously unknown hydroxy-, alkoxy-, and halogen-substituted benzylamines.

PAGES

1021-1028

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070428010070110

DOI

http://dx.doi.org/10.1134/s1070428010070110

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1005896975


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0305", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Organic Chemistry", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Leninskii pr. 47, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Leninskii pr. 47, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Musatov", 
        "givenName": "D. M.", 
        "id": "sg:person.016040426570.45", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016040426570.45"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Leninskii pr. 47, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Leninskii pr. 47, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Starodubtseva", 
        "givenName": "E. V.", 
        "id": "sg:person.011417521145.28", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011417521145.28"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Leninskii pr. 47, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Leninskii pr. 47, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Turova", 
        "givenName": "O. V.", 
        "id": "sg:person.016555476053.35", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016555476053.35"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Leninskii pr. 47, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Leninskii pr. 47, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kurilov", 
        "givenName": "D. V.", 
        "id": "sg:person.016245401745.85", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016245401745.85"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Leninskii pr. 47, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Leninskii pr. 47, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Vinogradov", 
        "givenName": "M. G.", 
        "id": "sg:person.0751717767.16", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0751717767.16"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Leninskii pr. 47, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Leninskii pr. 47, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Rakishev", 
        "givenName": "A. K.", 
        "id": "sg:person.012400316113.76", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012400316113.76"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Leninskii pr. 47, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Leninskii pr. 47, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Struchkova", 
        "givenName": "M. I.", 
        "id": "sg:person.01342454222.91", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01342454222.91"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "2010-07", 
    "datePublishedReg": "2010-07-01", 
    "description": "Different synthetic approaches to functionally substituted benzylamines were examined: reductive amination of alkyl aryl ketones and reduction of aromatic aldehyde oximes. The most efficient procedures were used to prepare a series of previously unknown hydroxy-, alkoxy-, and halogen-substituted benzylamines.", 
    "genre": "article", 
    "id": "sg:pub.10.1134/s1070428010070110", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1136317", 
        "issn": [
          "0514-7492", 
          "1070-4280"
        ], 
        "name": "Russian Journal of Organic Chemistry", 
        "publisher": "Pleiades Publishing", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "7", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "46"
      }
    ], 
    "keywords": [
      "alkyl aryl ketones", 
      "aryl ketones", 
      "aromatic aldehydes", 
      "different synthetic approaches", 
      "synthetic approach", 
      "reductive amination", 
      "benzylamine", 
      "aldehydes", 
      "ketones", 
      "efficient procedure", 
      "amination", 
      "alkoxy", 
      "hydroxy", 
      "synthesis", 
      "series", 
      "reduction", 
      "procedure", 
      "system", 
      "comparison", 
      "approach"
    ], 
    "name": "Comparison of different reducing systems in the synthesis of functionally substituted benzylamines from alkyl aryl ketones and aromatic aldehydes", 
    "pagination": "1021-1028", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1005896975"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s1070428010070110"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s1070428010070110", 
      "https://app.dimensions.ai/details/publication/pub.1005896975"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-05-20T07:26", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220519/entities/gbq_results/article/article_498.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1134/s1070428010070110"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1070428010070110'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1070428010070110'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1070428010070110'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1070428010070110'


 

This table displays all metadata directly associated to this object as RDF triples.

120 TRIPLES      21 PREDICATES      46 URIs      38 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s1070428010070110 schema:about anzsrc-for:03
2 anzsrc-for:0305
3 schema:author Nf1feeaee414f49d8858d0cf2ac2e2c2f
4 schema:datePublished 2010-07
5 schema:datePublishedReg 2010-07-01
6 schema:description Different synthetic approaches to functionally substituted benzylamines were examined: reductive amination of alkyl aryl ketones and reduction of aromatic aldehyde oximes. The most efficient procedures were used to prepare a series of previously unknown hydroxy-, alkoxy-, and halogen-substituted benzylamines.
7 schema:genre article
8 schema:inLanguage en
9 schema:isAccessibleForFree false
10 schema:isPartOf N22b602defc94471ea18fe0786b71bc05
11 N68650629934c4c5984ce22f7a8a1add6
12 sg:journal.1136317
13 schema:keywords aldehydes
14 alkoxy
15 alkyl aryl ketones
16 amination
17 approach
18 aromatic aldehydes
19 aryl ketones
20 benzylamine
21 comparison
22 different synthetic approaches
23 efficient procedure
24 hydroxy
25 ketones
26 procedure
27 reduction
28 reductive amination
29 series
30 synthesis
31 synthetic approach
32 system
33 schema:name Comparison of different reducing systems in the synthesis of functionally substituted benzylamines from alkyl aryl ketones and aromatic aldehydes
34 schema:pagination 1021-1028
35 schema:productId N0873353aefac46528e877cc299e03a37
36 N74896281edba4e83a1c74cbfbaaf443f
37 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005896975
38 https://doi.org/10.1134/s1070428010070110
39 schema:sdDatePublished 2022-05-20T07:26
40 schema:sdLicense https://scigraph.springernature.com/explorer/license/
41 schema:sdPublisher N6cf7c23056664d34ae257d05faee6bf1
42 schema:url https://doi.org/10.1134/s1070428010070110
43 sgo:license sg:explorer/license/
44 sgo:sdDataset articles
45 rdf:type schema:ScholarlyArticle
46 N0873353aefac46528e877cc299e03a37 schema:name dimensions_id
47 schema:value pub.1005896975
48 rdf:type schema:PropertyValue
49 N22b602defc94471ea18fe0786b71bc05 schema:issueNumber 7
50 rdf:type schema:PublicationIssue
51 N68650629934c4c5984ce22f7a8a1add6 schema:volumeNumber 46
52 rdf:type schema:PublicationVolume
53 N6cf7c23056664d34ae257d05faee6bf1 schema:name Springer Nature - SN SciGraph project
54 rdf:type schema:Organization
55 N74896281edba4e83a1c74cbfbaaf443f schema:name doi
56 schema:value 10.1134/s1070428010070110
57 rdf:type schema:PropertyValue
58 Nb7cf81a916824af5b6dc7b3168e17527 rdf:first sg:person.016555476053.35
59 rdf:rest Nee5cb8a7a96c4ed592cb836040ad82e2
60 Nce7f6ee1a82a4596819bec5f8e4e10a1 rdf:first sg:person.0751717767.16
61 rdf:rest Nf65004ee0eaa4bb695645accf311a899
62 Ne1094eedb62c407eb1c95a2ac6f9efa8 rdf:first sg:person.011417521145.28
63 rdf:rest Nb7cf81a916824af5b6dc7b3168e17527
64 Nee5cb8a7a96c4ed592cb836040ad82e2 rdf:first sg:person.016245401745.85
65 rdf:rest Nce7f6ee1a82a4596819bec5f8e4e10a1
66 Nf0588898baed487cb2be6aef5ac9b2fd rdf:first sg:person.01342454222.91
67 rdf:rest rdf:nil
68 Nf1feeaee414f49d8858d0cf2ac2e2c2f rdf:first sg:person.016040426570.45
69 rdf:rest Ne1094eedb62c407eb1c95a2ac6f9efa8
70 Nf65004ee0eaa4bb695645accf311a899 rdf:first sg:person.012400316113.76
71 rdf:rest Nf0588898baed487cb2be6aef5ac9b2fd
72 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
73 schema:name Chemical Sciences
74 rdf:type schema:DefinedTerm
75 anzsrc-for:0305 schema:inDefinedTermSet anzsrc-for:
76 schema:name Organic Chemistry
77 rdf:type schema:DefinedTerm
78 sg:journal.1136317 schema:issn 0514-7492
79 1070-4280
80 schema:name Russian Journal of Organic Chemistry
81 schema:publisher Pleiades Publishing
82 rdf:type schema:Periodical
83 sg:person.011417521145.28 schema:affiliation grid-institutes:grid.4886.2
84 schema:familyName Starodubtseva
85 schema:givenName E. V.
86 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011417521145.28
87 rdf:type schema:Person
88 sg:person.012400316113.76 schema:affiliation grid-institutes:grid.4886.2
89 schema:familyName Rakishev
90 schema:givenName A. K.
91 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012400316113.76
92 rdf:type schema:Person
93 sg:person.01342454222.91 schema:affiliation grid-institutes:grid.4886.2
94 schema:familyName Struchkova
95 schema:givenName M. I.
96 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01342454222.91
97 rdf:type schema:Person
98 sg:person.016040426570.45 schema:affiliation grid-institutes:grid.4886.2
99 schema:familyName Musatov
100 schema:givenName D. M.
101 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016040426570.45
102 rdf:type schema:Person
103 sg:person.016245401745.85 schema:affiliation grid-institutes:grid.4886.2
104 schema:familyName Kurilov
105 schema:givenName D. V.
106 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016245401745.85
107 rdf:type schema:Person
108 sg:person.016555476053.35 schema:affiliation grid-institutes:grid.4886.2
109 schema:familyName Turova
110 schema:givenName O. V.
111 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016555476053.35
112 rdf:type schema:Person
113 sg:person.0751717767.16 schema:affiliation grid-institutes:grid.4886.2
114 schema:familyName Vinogradov
115 schema:givenName M. G.
116 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0751717767.16
117 rdf:type schema:Person
118 grid-institutes:grid.4886.2 schema:alternateName Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Leninskii pr. 47, 119991, Moscow, Russia
119 schema:name Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Leninskii pr. 47, 119991, Moscow, Russia
120 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...