Kinetics and mechanism of 5-vinyltetrazole alkylation View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2008-11

AUTHORS

Yu. N. Pavlyukova, R. E. Trifonov, E. V. Yugai, P. A. Aleshunin, I. V. Tselinskii, V. A. Ostrovskii

ABSTRACT

Alkylation of NH-unsubstituted 5-vinyltetrazole with methyl iodide in the presence of triethylamine in acetonitrile solution led to the formation of isomeric 1- and 2-methyl-5-vinyltetrazoles in 1:1 ratio. The reaction rate constants were measured at 25–55°C. According to the thermodynamic parameters of the reaction [ΔH≠ 66 kJ mol−1, ΔS≠-74 (mol K)−1, 298 K] the limiting stage of the reaction consists in the electrophilic attack of methyl iodide on an H-complex of the heterocycle with triethylamine. More... »

PAGES

1711

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070428008110249

DOI

http://dx.doi.org/10.1134/s1070428008110249

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1004258094


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