13C-13C spin-spin coupling constants in structural studies: XLIII. Stereochemical study on functionalized 3-iminopyrrolizines View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2008-09

AUTHORS

S. S. Khutsishvili, Yu. Yu. Rusakov, L. B. Krivdin, N. V. Istomina, O. V. Petrova, L. N. Sobenina, A. I. Mikhaleva

ABSTRACT

Three 1-ethylsulfanyl-3-imino-3H-pyrrolizine-2-carboxamides were synthesized by intramolecular cyclization of substituted (2Z)-2-cyano-3-ethylsulfanyl-3-(1H-pyrrol-2-yl)prop-2-enamides. The products were assigned syn configuration at the C=N bond and preferential s-cis orientation of the carbamoyl group on the basis of the experimental 13C-13C coupling constants and high-level nonempirical quantum-chemical calculations.

PAGES

1338

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070428008090157

DOI

http://dx.doi.org/10.1134/s1070428008090157

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1024586700


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139 rdf:type schema:Organization
 




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