Synthesis and steric structure of N″-(arylmethylidene)-N″′-(1-methyl-3-phenylprop-2-yn-1-ylidene)thiocarbonohydrazides View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2008-01

AUTHORS

T. E. Glotova, M. Yu. Dvorko, N. N. Chipanina, A. I. Albanov, L. V. Sherstyannikova, O. N. Kazheva, A. N. Chekhlov, O. A. D’yachenko

ABSTRACT

Thiocarbonohydrazones derived from aromatic aldehydes reacted with 4-phenylbut-3-yn-2-one in aqueous acetic acid (20°C, 2 h) to produce previously unknown N″-[(E-s-cis)-arylmethylidene]-N″′-[(Z-s-trans)-1-methyl-3-phenylprop-2-yn-1-ylidene]thiocarbonohydrazides with high chemo-, regio-, and stereoselectivity. The steric structure of N″-[(E-s-cis)-benzylidene]-N″′-[(Z-s-trans)-1-methyl-3-phenylprop-2-yn-1-ylidene]thiocarbonohydrazide in crystal and in solution was studied by X-ray analysis and IR and NMR spectroscopy.

PAGES

114-119

References to SciGraph publications

  • 2002-08. Thiocarbohydrazide as ``Diamine'' to Construct Macrocyclic and Side-Off Compartmental Ligands in JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
  • Identifiers

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    DOI

    http://dx.doi.org/10.1134/s1070428008010144

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