1,1,2,2-tetraaminoethane derivatives: III. Condensation of 2-(Dinitromethylene)imidazolidine-4,5-diol with nitrogen-containing nucleophiles View Full Text


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Article Info

DATE

2007-08

AUTHORS

E. V. Sizova, V. V. Sizov, I. V. Tselinskii

ABSTRACT

Condensation of 1,1-diamino-2,2-dinitroethylene with glyoxal and formaldehyde in water solutions at pH 7–8 gave rise to 2-(dinitromethylene)imidazolidine-4,5-diol and 1,1-diamino-N,N′-bis(hydroxymethyl)-2,2-dinitroethylene respectively. Condensation products of 2-(dinitromethylene)imidazolidine-4,5-diol with acetonitrile, benzonitrile, urethane, 3,4-diaminofurazan were isolated. The reaction of 4,5-diacetamido-2-(dinitromethylene) imidazolidine sulfate with water in acetonitrile led to the formation of 2-(dinitromethylene)-5-methyl-1,2,3,3a,4,6a-hexahydroimidazo[4,5-d]imidazole. The dehydration of 2-(dinitromethylene)imidazolidine-4,5-diol in a system H2SO4-AcOH provided 2-(dinitromethylene)-2,3-dihydro-1H-imidazol-4-ol. 1,1-Diamino-N,N′-bis(hydroxymethyl)-2,2-dinitroethylene in sulfuric acid was converted into 4-(dinitromethylene)-1,3,5-oxadiazinane. More... »

PAGES

1232-1237

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s107042800708026x

DOI

http://dx.doi.org/10.1134/s107042800708026x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1000789630


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