Synthesis of 1,2-diols ethers, condensation products of glyoxal with nitrogen-containing nucleophiles: I. Reaction of cyclic sulfites with primary alcohols and ... View Full Text


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Article Info

DATE

2007-08

AUTHORS

E. V. Sizova, V. V. Sizov, I. V. Tselinskii

ABSTRACT

In reactions of 4,5-diacetoxy-2-(dinitromethylene)imidazolidine, 4,5-diacetoxy-2-nitriminoimidazolidine, and 1,2-diacetoxy-1,2-bis(chloroacetylamino)ethane with thionyl chloride at room temperature the corresponding cyclic sulfites were obtained. Treating the sulfites with methanol, ethanol, and 2-chloroethanol at room temperature we prepared acyclic ethers in 80–90% yields. Similarly cyclic ethers were synthesized from ethylene glycol and 1,3-propanediol in 50–60% yields.

PAGES

1213-1217

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070428007080222

DOI

http://dx.doi.org/10.1134/s1070428007080222

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1031330873


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