Thiomethylation of amino alcohols using formaldehyde and hydrogen sulfide View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2007-06

AUTHORS

V. R. Akhmetova, G. R. Nadyrgulova, T. V. Tyumkina, Z. A. Starikova, M. Yu. Antipin, R. V. Kunakova, U. M. Dzhemilev

ABSTRACT

Three-component condensations of formaldehyde with hydrogen sulfide and hydroxylamine or amino alcohols at a ratio of 3:2:1 give 47–73% of N-hydroxy(or hydroxyalkyl)-1,3,5-dithiazinanes. The reactions of CH2O with H2S and hydroxylamine or α-amino alcohols at a ratio of 4:3:1 involve both amino and hydroxy groups, leading to the corresponding dithiazinanes. 4-Aminobutan-1-ol reacts with CH2O and H2S under analogous conditions only at the amino group to form 4-(1,3,5-dithiazinan-5-yl)butan-1-ol. More... »

PAGES

918-925

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070428007060218

DOI

http://dx.doi.org/10.1134/s1070428007060218

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1032950991


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Petroleum Chemistry and Catalysis, Russian Academy of Sciences, pr. Oktyabrya 141, 450075, Ufa, Bashkortostan, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Akhmetova", 
        "givenName": "V. R.", 
        "id": "sg:person.012710502205.02", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012710502205.02"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Petroleum Chemistry and Catalysis, Russian Academy of Sciences, pr. Oktyabrya 141, 450075, Ufa, Bashkortostan, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Nadyrgulova", 
        "givenName": "G. R.", 
        "id": "sg:person.01110631333.47", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01110631333.47"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Petroleum Chemistry and Catalysis, Russian Academy of Sciences, pr. Oktyabrya 141, 450075, Ufa, Bashkortostan, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Tyumkina", 
        "givenName": "T. V.", 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Nesmeyanov Institute of Organometallic Compounds, Russian Academy of Sciences, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Starikova", 
        "givenName": "Z. A.", 
        "id": "sg:person.014473641160.05", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014473641160.05"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Nesmeyanov Institute of Organometallic Compounds, Russian Academy of Sciences, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Antipin", 
        "givenName": "M. Yu.", 
        "id": "sg:person.010142146727.55", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010142146727.55"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Petroleum Chemistry and Catalysis, Russian Academy of Sciences, pr. Oktyabrya 141, 450075, Ufa, Bashkortostan, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kunakova", 
        "givenName": "R. V.", 
        "id": "sg:person.012457144442.98", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012457144442.98"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of Petroleum Chemistry and Catalysis, Russian Academy of Sciences, pr. Oktyabrya 141, 450075, Ufa, Bashkortostan, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Dzhemilev", 
        "givenName": "U. M.", 
        "id": "sg:person.011637315036.37", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011637315036.37"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1002/jhet.5570190608", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001054587"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/jhet.5570190608", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001054587"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0040-4039(00)85555-0", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006731606"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0957-4166(94)80025-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028701455"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0040-4020(81)85004-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1046856502"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja01621a045", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055813402"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jo01053a024", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055999405"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2007-06", 
    "datePublishedReg": "2007-06-01", 
    "description": "Three-component condensations of formaldehyde with hydrogen sulfide and hydroxylamine or amino alcohols at a ratio of 3:2:1 give 47\u201373% of N-hydroxy(or hydroxyalkyl)-1,3,5-dithiazinanes. The reactions of CH2O with H2S and hydroxylamine or \u03b1-amino alcohols at a ratio of 4:3:1 involve both amino and hydroxy groups, leading to the corresponding dithiazinanes. 4-Aminobutan-1-ol reacts with CH2O and H2S under analogous conditions only at the amino group to form 4-(1,3,5-dithiazinan-5-yl)butan-1-ol.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/s1070428007060218", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": true, 
    "isPartOf": [
      {
        "id": "sg:journal.1136317", 
        "issn": [
          "1070-4280", 
          "1608-3393"
        ], 
        "name": "Russian Journal of Organic Chemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "6", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "43"
      }
    ], 
    "name": "Thiomethylation of amino alcohols using formaldehyde and hydrogen sulfide", 
    "pagination": "918-925", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "9cf9698c2f006821fd21a8d31a16c2b1899bf78dfd58643dcd0af3a9536bbb6d"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s1070428007060218"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1032950991"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s1070428007060218", 
      "https://app.dimensions.ai/details/publication/pub.1032950991"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T15:50", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8664_00000506.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1134%2FS1070428007060218"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1070428007060218'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1070428007060218'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1070428007060218'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1070428007060218'


 

This table displays all metadata directly associated to this object as RDF triples.

121 TRIPLES      21 PREDICATES      33 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s1070428007060218 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N6cdf0976234e4e63bccba986794cf975
4 schema:citation https://doi.org/10.1002/jhet.5570190608
5 https://doi.org/10.1016/0040-4020(81)85004-1
6 https://doi.org/10.1016/0957-4166(94)80025-1
7 https://doi.org/10.1016/s0040-4039(00)85555-0
8 https://doi.org/10.1021/ja01621a045
9 https://doi.org/10.1021/jo01053a024
10 schema:datePublished 2007-06
11 schema:datePublishedReg 2007-06-01
12 schema:description Three-component condensations of formaldehyde with hydrogen sulfide and hydroxylamine or amino alcohols at a ratio of 3:2:1 give 47–73% of N-hydroxy(or hydroxyalkyl)-1,3,5-dithiazinanes. The reactions of CH2O with H2S and hydroxylamine or α-amino alcohols at a ratio of 4:3:1 involve both amino and hydroxy groups, leading to the corresponding dithiazinanes. 4-Aminobutan-1-ol reacts with CH2O and H2S under analogous conditions only at the amino group to form 4-(1,3,5-dithiazinan-5-yl)butan-1-ol.
13 schema:genre research_article
14 schema:inLanguage en
15 schema:isAccessibleForFree true
16 schema:isPartOf N099f24deeb804541b20b378ad0be8ddd
17 Nb18bcfd33dad4bef86e49a5613dd76a8
18 sg:journal.1136317
19 schema:name Thiomethylation of amino alcohols using formaldehyde and hydrogen sulfide
20 schema:pagination 918-925
21 schema:productId N642d963618f646b58b1ec42750ce0186
22 N976d871d1c064daf8a6e8d38feb49a66
23 N9b8a0d41ca1a462ea55f19842eb2737c
24 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032950991
25 https://doi.org/10.1134/s1070428007060218
26 schema:sdDatePublished 2019-04-10T15:50
27 schema:sdLicense https://scigraph.springernature.com/explorer/license/
28 schema:sdPublisher N64b3c3bc572a4a8189156f616ebe4a7c
29 schema:url http://link.springer.com/10.1134%2FS1070428007060218
30 sgo:license sg:explorer/license/
31 sgo:sdDataset articles
32 rdf:type schema:ScholarlyArticle
33 N0764284806d94212a0283e23f8c8fcaa schema:affiliation https://www.grid.ac/institutes/grid.4886.2
34 schema:familyName Tyumkina
35 schema:givenName T. V.
36 rdf:type schema:Person
37 N099f24deeb804541b20b378ad0be8ddd schema:volumeNumber 43
38 rdf:type schema:PublicationVolume
39 N3356d092e6d7412195c38353b9a8833b rdf:first sg:person.011637315036.37
40 rdf:rest rdf:nil
41 N46d16d7c50d34152aac0a47c32c4a121 rdf:first sg:person.012457144442.98
42 rdf:rest N3356d092e6d7412195c38353b9a8833b
43 N642d963618f646b58b1ec42750ce0186 schema:name dimensions_id
44 schema:value pub.1032950991
45 rdf:type schema:PropertyValue
46 N64b3c3bc572a4a8189156f616ebe4a7c schema:name Springer Nature - SN SciGraph project
47 rdf:type schema:Organization
48 N6cdf0976234e4e63bccba986794cf975 rdf:first sg:person.012710502205.02
49 rdf:rest Nee3d6a7c9b4d4907bb1f200746350d87
50 N976d871d1c064daf8a6e8d38feb49a66 schema:name readcube_id
51 schema:value 9cf9698c2f006821fd21a8d31a16c2b1899bf78dfd58643dcd0af3a9536bbb6d
52 rdf:type schema:PropertyValue
53 N9b8a0d41ca1a462ea55f19842eb2737c schema:name doi
54 schema:value 10.1134/s1070428007060218
55 rdf:type schema:PropertyValue
56 Nb18bcfd33dad4bef86e49a5613dd76a8 schema:issueNumber 6
57 rdf:type schema:PublicationIssue
58 Nb85e672e16e3492b8b69912c2d1466bc rdf:first sg:person.014473641160.05
59 rdf:rest Nc4d6f1a5de5b432e9c0e4a7b8d2ae868
60 Nbbaab8809f5b44459ca211178f2906ad rdf:first N0764284806d94212a0283e23f8c8fcaa
61 rdf:rest Nb85e672e16e3492b8b69912c2d1466bc
62 Nc4d6f1a5de5b432e9c0e4a7b8d2ae868 rdf:first sg:person.010142146727.55
63 rdf:rest N46d16d7c50d34152aac0a47c32c4a121
64 Nee3d6a7c9b4d4907bb1f200746350d87 rdf:first sg:person.01110631333.47
65 rdf:rest Nbbaab8809f5b44459ca211178f2906ad
66 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
67 schema:name Chemical Sciences
68 rdf:type schema:DefinedTerm
69 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
70 schema:name Physical Chemistry (incl. Structural)
71 rdf:type schema:DefinedTerm
72 sg:journal.1136317 schema:issn 1070-4280
73 1608-3393
74 schema:name Russian Journal of Organic Chemistry
75 rdf:type schema:Periodical
76 sg:person.010142146727.55 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
77 schema:familyName Antipin
78 schema:givenName M. Yu.
79 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010142146727.55
80 rdf:type schema:Person
81 sg:person.01110631333.47 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
82 schema:familyName Nadyrgulova
83 schema:givenName G. R.
84 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01110631333.47
85 rdf:type schema:Person
86 sg:person.011637315036.37 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
87 schema:familyName Dzhemilev
88 schema:givenName U. M.
89 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011637315036.37
90 rdf:type schema:Person
91 sg:person.012457144442.98 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
92 schema:familyName Kunakova
93 schema:givenName R. V.
94 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012457144442.98
95 rdf:type schema:Person
96 sg:person.012710502205.02 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
97 schema:familyName Akhmetova
98 schema:givenName V. R.
99 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012710502205.02
100 rdf:type schema:Person
101 sg:person.014473641160.05 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
102 schema:familyName Starikova
103 schema:givenName Z. A.
104 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014473641160.05
105 rdf:type schema:Person
106 https://doi.org/10.1002/jhet.5570190608 schema:sameAs https://app.dimensions.ai/details/publication/pub.1001054587
107 rdf:type schema:CreativeWork
108 https://doi.org/10.1016/0040-4020(81)85004-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046856502
109 rdf:type schema:CreativeWork
110 https://doi.org/10.1016/0957-4166(94)80025-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028701455
111 rdf:type schema:CreativeWork
112 https://doi.org/10.1016/s0040-4039(00)85555-0 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006731606
113 rdf:type schema:CreativeWork
114 https://doi.org/10.1021/ja01621a045 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055813402
115 rdf:type schema:CreativeWork
116 https://doi.org/10.1021/jo01053a024 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055999405
117 rdf:type schema:CreativeWork
118 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
119 schema:name Institute of Petroleum Chemistry and Catalysis, Russian Academy of Sciences, pr. Oktyabrya 141, 450075, Ufa, Bashkortostan, Russia
120 Nesmeyanov Institute of Organometallic Compounds, Russian Academy of Sciences, Moscow, Russia
121 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...