Synthesis and properties of 1-dinitromethyl-3-R-1,2,4-triazoles View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2007-05

AUTHORS

T. P. Kofman, A. E. Trubitsyn, I. V. Dmitrienko, E. Yu. Glazkova, I. V. Tselinskii

ABSTRACT

Reductive denitration of 1-trinitromethyl-3-R-1,2,4-triazoles by KI or NH2OH followed by the treatment of the formed 1-dinitromethyl-3-R-1,2,4-triazoles salts with sulfuric acid yielded dinitromethyl compounds (R = H, N3, Cl, NO2), sufficiently strong CH-acids (pKa 1.37–0.12) whose typical reactions are similar to those of gem-dinitrocompounds from the aliphatic series. The spectral data and the analysis of correlation relations between pKa of 1-dinitromethyl-3-R-1,2,4-triazoles and the substituent constants confirm that their structure is analogous to that of the majority of compounds belonging to the mentioned series. More... »

PAGES

758-764

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070428007050193

DOI

http://dx.doi.org/10.1134/s1070428007050193

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1034838276


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