Structure and rearrangements of 3-Iso(thio,seleno)cyanato-1,2,3-triarylcyclopropenes View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-11

AUTHORS

I. E. Mikhailov, G. A. Dushenko, G. Reck, B. Schulz, O. I. Mikhailova, V. I. Minkin

ABSTRACT

A series of new fluctional 3-iso(thio,seleno)cyanato-1,2,3-triarylcyclopropenes was synthesized. The structure of compounds was proved by 1H and 13C NMR, IR, and mass spectra, and that of 3-(1,2,3-triphenylcyclopropenyl) isothiocycnate was confirmed by X-ray crystallography. In compounds under consideration by means of 1H and 13C NMR was discovered and investigated a fast reversible migration of isocyanato, isothiocyanato, and isoselenocyanato groups along the perimeter of the theree-membered ring proceeding according to the dissociation-recombination mechanism. More... »

PAGES

1630-1635

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070428006110066

DOI

http://dx.doi.org/10.1134/s1070428006110066

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1014952351


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