Ontology type: schema:ScholarlyArticle
2006-09
AUTHORSR. I. Vas’kevich, P. V. Savitskii, Yu. L. Zborovskii, V. I. Staninets, E. B. Rusanov, A. N. Chernega
ABSTRACTHeterocyclization of 1-(4,6-dimethylpyrimidin-2-yl)-4-R-thiosemicarbazides by the action of methyl iodide in ethanol in the presence of sodium acetate is accompanied by Dimroth rearrangement leading to the formation of 5,7-dimethyl-2-R-amino[1,2,4]triazolo[1,5-a]pyrimidines. Analogous heterocyclization of 4-aryl-1-(4-methyl-6-oxo-1,6-dihydropyrimidin-2-yl)thiosemicarbazides gives 3-arylamino-7-methyl-5-oxo-[1,2,4]triazolo[4,3-a]pyrimidines. The presence in the pyrimidine ring of a carbonyl group capable of forming hydrogen bond with protons of the amino group stabilizes the molecule, thus hampering the Dimroth rearrangement. More... »
PAGES1403-1408
http://scigraph.springernature.com/pub.10.1134/s1070428006090272
DOIhttp://dx.doi.org/10.1134/s1070428006090272
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1017125269
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0601",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Biochemistry and Cell Biology",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/06",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Biological Sciences",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "Institute of Organic Chemistry",
"id": "https://www.grid.ac/institutes/grid.464621.3",
"name": [
"Institute of Organic Chemistry, National Academy of Sciences of Ukraine, ul. Murmanskaya 5, 02094, Kiev, Ukraine"
],
"type": "Organization"
},
"familyName": "Vas\u2019kevich",
"givenName": "R. I.",
"id": "sg:person.013174754337.67",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013174754337.67"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Institute of Organic Chemistry",
"id": "https://www.grid.ac/institutes/grid.464621.3",
"name": [
"Institute of Organic Chemistry, National Academy of Sciences of Ukraine, ul. Murmanskaya 5, 02094, Kiev, Ukraine"
],
"type": "Organization"
},
"familyName": "Savitskii",
"givenName": "P. V.",
"id": "sg:person.015551724522.27",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015551724522.27"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Institute of Organic Chemistry",
"id": "https://www.grid.ac/institutes/grid.464621.3",
"name": [
"Institute of Organic Chemistry, National Academy of Sciences of Ukraine, ul. Murmanskaya 5, 02094, Kiev, Ukraine"
],
"type": "Organization"
},
"familyName": "Zborovskii",
"givenName": "Yu. L.",
"id": "sg:person.010120771367.48",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010120771367.48"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Institute of Organic Chemistry",
"id": "https://www.grid.ac/institutes/grid.464621.3",
"name": [
"Institute of Organic Chemistry, National Academy of Sciences of Ukraine, ul. Murmanskaya 5, 02094, Kiev, Ukraine"
],
"type": "Organization"
},
"familyName": "Staninets",
"givenName": "V. I.",
"id": "sg:person.016653667731.06",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016653667731.06"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Institute of Organic Chemistry",
"id": "https://www.grid.ac/institutes/grid.464621.3",
"name": [
"Institute of Organic Chemistry, National Academy of Sciences of Ukraine, ul. Murmanskaya 5, 02094, Kiev, Ukraine"
],
"type": "Organization"
},
"familyName": "Rusanov",
"givenName": "E. B.",
"id": "sg:person.01247600537.28",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01247600537.28"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Institute of Organic Chemistry",
"id": "https://www.grid.ac/institutes/grid.464621.3",
"name": [
"Institute of Organic Chemistry, National Academy of Sciences of Ukraine, ul. Murmanskaya 5, 02094, Kiev, Ukraine"
],
"type": "Organization"
},
"familyName": "Chernega",
"givenName": "A. N.",
"id": "sg:person.013701677755.94",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013701677755.94"
],
"type": "Person"
}
],
"citation": [
{
"id": "https://doi.org/10.1071/ch9772515",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1001556048"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1107/s0567740876009989",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1004032002"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1107/s0567739468000707",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1006361149"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/jhet.5570120619",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1021325278"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/jhet.5570120619",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1021325278"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1246/bcsj.56.1227",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1023282631"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1107/s0567739479001613",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1023477475"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/jhet.5570150530",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1025143989"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1002/jhet.5570150530",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1025143989"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1107/s0567740881005943",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1047682328"
],
"type": "CreativeWork"
},
{
"id": "https://doi.org/10.1021/jo01088a014",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1056003234"
],
"type": "CreativeWork"
},
{
"id": "https://app.dimensions.ai/details/publication/pub.1081934255",
"type": "CreativeWork"
}
],
"datePublished": "2006-09",
"datePublishedReg": "2006-09-01",
"description": "Heterocyclization of 1-(4,6-dimethylpyrimidin-2-yl)-4-R-thiosemicarbazides by the action of methyl iodide in ethanol in the presence of sodium acetate is accompanied by Dimroth rearrangement leading to the formation of 5,7-dimethyl-2-R-amino[1,2,4]triazolo[1,5-a]pyrimidines. Analogous heterocyclization of 4-aryl-1-(4-methyl-6-oxo-1,6-dihydropyrimidin-2-yl)thiosemicarbazides gives 3-arylamino-7-methyl-5-oxo-[1,2,4]triazolo[4,3-a]pyrimidines. The presence in the pyrimidine ring of a carbonyl group capable of forming hydrogen bond with protons of the amino group stabilizes the molecule, thus hampering the Dimroth rearrangement.",
"genre": "research_article",
"id": "sg:pub.10.1134/s1070428006090272",
"inLanguage": [
"en"
],
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1136317",
"issn": [
"1070-4280",
"1608-3393"
],
"name": "Russian Journal of Organic Chemistry",
"type": "Periodical"
},
{
"issueNumber": "9",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "42"
}
],
"name": "Synthesis of amino derivatives of triazolopyrimidine",
"pagination": "1403-1408",
"productId": [
{
"name": "readcube_id",
"type": "PropertyValue",
"value": [
"51977cf8b66ab1c48509049197990eca96bec3a0a672d91bc05a0a865782787c"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1134/s1070428006090272"
]
},
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1017125269"
]
}
],
"sameAs": [
"https://doi.org/10.1134/s1070428006090272",
"https://app.dimensions.ai/details/publication/pub.1017125269"
],
"sdDataset": "articles",
"sdDatePublished": "2019-04-10T15:49",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8664_00000504.jsonl",
"type": "ScholarlyArticle",
"url": "http://link.springer.com/10.1134%2FS1070428006090272"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1070428006090272'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1070428006090272'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1070428006090272'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1070428006090272'
This table displays all metadata directly associated to this object as RDF triples.
125 TRIPLES
21 PREDICATES
37 URIs
19 LITERALS
7 BLANK NODES