Chemistry of diazocarbonyl compounds: XXVII. Thermolysis and photolysis of diazirines, derivatives of 1,3-dioxane-4,6-dione View Full Text


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Article Info

DATE

2006-08

AUTHORS

V. V. Shevchenko, N. N. Khimich, M. S. Platz, V. A. Nikolaev

ABSTRACT

Photolysis of diazirines, 1,3-dioxane-4,6-dione derivatives, occurs in the presence of methanol or dimethyl sulfide as carbene traps without a formation of carbene intermediates. It was established for the first time that the thermolysis and photolysis of diazirines from the 1,3-dioxane-4,6-dione series led mainly to Wolff rearrangement with a subsequent formation of 5-oxo-1,3-dioxolane-4-carboxylic acids or their derivatives. The data obtained show that the α-oxodiazirines are the key intermediates in the photolysis and Wolff rearrangement of α-diazocarbonyl compounds. More... »

PAGES

1213-1219

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070428006080197

DOI

http://dx.doi.org/10.1134/s1070428006080197

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1027195435


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