2-alkyl-5-aryltetrazoles as hydrogen bond acceptors View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-07

AUTHORS

R. E. Trifonov, M. V. Trukhnitskaya, A. A. Tarkhanova, I. A. Vikhrova, V. A. Ostrovskii

ABSTRACT

The dissociation constants of the H-complexes formed by 2-alkyl-5-aryltetrazoles and p-fluorophenol in carbon tetrachloride (pKHB 0.9–1.3) were determined by Fourier-transform IR spectroscopy. 2-Alkyl-5-aryltetrazoles were found to act as medium-strength hydrogen bond acceptors comparable with diazines. The thermodynamic parameters of the equilibrium formation of H-complex with 2-isopropyl-5-phenyltetrazole were determined. The electronic nature of substituents in the tetrazole ring only slightly affects the pKHB values of tetrazoles. More... »

PAGES

1059-1062

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070428006070232

DOI

http://dx.doi.org/10.1134/s1070428006070232

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1042819796


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