Chlorination and oxidation of 4-fluoro-5-tetrafluoroethyl-1,2-dithiole-3-thione View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-01

AUTHORS

I. N. Fesun, V. M. Timoshenko, A. N. Chernega, Yu. G. Shermolovich

ABSTRACT

Chlorination of 4-fluoro-5-(1,1,2,2-tetrafluoroethyl)-1,2-dithiole-3-thione with an equimolar amount of chlorine or sulfuryl chloride gives 3-chlorosulfanyl-4-fluoro-5-(1,1,2,2-tetrafluoroethyl)-1,2-dithiolium chloride. The reaction of the title compound with excess chlorinating agent leads to 3,3,4,5-tetrachloro-4-fluoro-5-(1,1,2,2-tetrafluoroethyl)-1,2-dithiolane. By oxidation and oxidative imination of 4-fluoro-5-(1,1,2,2-tetrafluoroethyl)-1,2-dithiole-3-thione, the corresponding S-oxide and sulfimide were obtained, respectively.

PAGES

124-130

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070428006010192

DOI

http://dx.doi.org/10.1134/s1070428006010192

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1026511595


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