Synthesis of 3-imino and 3-ylideno derivatives of 4-fluoro-5-polyfluoroalkyl-1,2-dithiolenes View Full Text


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Article Info

DATE

2006-02

AUTHORS

I. N. Fesun, V. M. Timoshenko, Yu. G. Shermolovich

ABSTRACT

Reactions of 4-fluoro-5-polyfluoroalkyl-1,2-dithiol-3-thiones with hydroxylamine and hydrazines occur with replacement of the thiocarbonyl by imino group affording oximes and hydrazones respectively. N-Alkyl-and N-aryl-3-imino-1,2-dithiolenes formed in reactions of 3-chlorothio-1,2-dithiolium salts with primary alkyl-or arylamines. 3-Chlorothio-1,2-dithiolium salts react with compounds possessing an active methylene group yielding 3-ylideno derivatives of 1,2-dithiolenes.

PAGES

261-265

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070428002120187

DOI

http://dx.doi.org/10.1134/s1070428002120187

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1030643153


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