Heat Release Kinetics in Thermally Initiated 1,4-Diethynylbenzene Polymerization View Full Text


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Article Info

DATE

2021-07

AUTHORS

A. I. Kazakov, D. B. Lempert, A. V. Nabatova, T. S. Larikova, A. A. Molokanov, I. N. Zyuzin, N. N. Volkova, M. B. Kislov, A. F. Zholudev, L. S. Yanovskii

ABSTRACT

The heat release kinetics in thermally initiated polymerization of 1,4-diethynylbenzene suggested as fuel dispersant in gas generator engines was studied under isothermal conditions in the temperature interval 90–150°С in the melt–vapor two-phase closed system. The enthalpies and entropies of melting, vaporization, and sublimation of 1,4-diethynylbenzene and the kinetics of a decrease in its vapor pressure in the course of polymerization in the melt were determined. Specific features of pressure and temperature variation in the course of propagation of the 1,4-diethynylbenzene combustion front in a cylindrical specimen in a Crawford bomb at the initial pressure of 2 MPa were studied. More... »

PAGES

977-985

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070427221070168

DOI

http://dx.doi.org/10.1134/s1070427221070168

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1141645973


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