Evaporation of Plasticizer from NEPE Type Propellant View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-05

AUTHORS

Yu. M. Milekhin, A. A. Koptelov, N. I. Shishov, I. A. Koptelov, A. A. Rogozina

ABSTRACT

Using the method of dynamic thermogravimetry and differential scanning calorimetry in the heating rate range 0.46–10.0 deg–1 min–1, evaporation of the plasticizer from propellant samples of the NEPE type was investigated. The experiments were carried out in an open system in a flow of pure argon at atmospheric pressure. Nitroglycerin is the main mass fraction of the plasticizer. The activation energy E of the gross evaporation–diffusion process is determined by various methods. Heat of evaporation of the plasticizer ΔHv is estimated. It is shown that in the early stage of evaporation the values of E and ΔHv practically coincide. At a temperature of 298.15 K ΔHv = 89 ± 4 kJ mol–1, which is in satisfactory agreement with the literature data for heat of evaporation of pure nitroglycerin. With any way of preventing free removal of the plasticizer from the surface of the samples on the DSC thermograms successive exothermic peaks of the thermal decomposition of the plasticizer and the octogen are observed, which are not realized in the open system for the indicated heating rates at T < 190°C. More... »

PAGES

802-812

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070427218050117

DOI

http://dx.doi.org/10.1134/s1070427218050117

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1105836564


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