Synthesis of Cu(II)-containing TiO2-SiO2 binary xerogels by hydrolysis of a mixture of tetrabutoxytitanium, tetraethoxysilane, and copper(II) chloride in a water-ammonia ... View Full Text


Ontology type: schema:ScholarlyArticle      Open Access: True


Article Info

DATE

2013-03

AUTHORS

A. B. Shishmakov, M. S. Molochnikov, D. O. Antonov, O. V. Koryakova, A. S. Seleznev, L. A. Petrov

ABSTRACT

A Cu(II)-containing binary xerogel TiO2-SiO2 was synthesized by joint hydrolysis of tetrabutoxytitanium, teraethoxysilane and copper(II) chloride dissolved in their mixture. The synthesis was performed in a vapor of 10% aqueous ammonia under static conditions. EPR spectroscopy was used to examine the state of Cu(II) in the xerogel matrix. Data on specific features of the behavior of saccharose within xerogel pores under heating were obtained. The catalytic activity of the xerogel was tested by the kinetic method on model reactions of hydrogen peroxide decomposition and oxidative dehydrogenation of trimethylhydroquinone. More... »

PAGES

297-303

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070427213030014

DOI

http://dx.doi.org/10.1134/s1070427213030014

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1006573257


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