Examination of catalyst for α-metylstyrene oligomerization “Phosphoric Acid on Sibunit” under conditions of laboratory and industrial application View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2008-03

AUTHORS

V. P. Talzi, G. V. Plaksin, V. Yu. Davydova

ABSTRACT

A catalyst obtained by impregnation of a mesoporous carbon carrier sibunit with orthophosphoric acid is examined under conditions of pilot plant manufacturing for producing α-methylstyrene dimer. The produced catalyzate (the product obtained with catalysis, 300 ton) containing ca. 70% of targeted 2,4-diphenyl-4-methyl-1-penetene at 95% conversion was after filtration used for control of molecular mass at producing polystyrene of different sorts. Consumption of the catalyst under optimal conditions of exploitation of the installation was ca. 1.5 kg per 1 ton of dimer at temperature ca. 50°C and volume rate ∼ 0.5 h−1. Content of 2,4-diphenyl-4-methyl-1-pentene in the dimer can be elevated to 80% by significant decreasing conversion (∼50%) and by application of solvents. More... »

PAGES

516-519

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070427208030397

DOI

http://dx.doi.org/10.1134/s1070427208030397

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1018885705


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of the Problems of Processing Hydrocarbons, Russian Academy of Sciences, Siberian Branch, Siberian, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Talzi", 
        "givenName": "V. P.", 
        "id": "sg:person.010036115232.48", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010036115232.48"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of the Problems of Processing Hydrocarbons, Russian Academy of Sciences, Siberian Branch, Siberian, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Plaksin", 
        "givenName": "G. V.", 
        "id": "sg:person.012120153545.27", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012120153545.27"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Institute of the Problems of Processing Hydrocarbons, Russian Academy of Sciences, Siberian Branch, Siberian, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Davydova", 
        "givenName": "V. Yu.", 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1021/ie00096a004", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055594744"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2008-03", 
    "datePublishedReg": "2008-03-01", 
    "description": "A catalyst obtained by impregnation of a mesoporous carbon carrier sibunit with orthophosphoric acid is examined under conditions of pilot plant manufacturing for producing \u03b1-methylstyrene dimer. The produced catalyzate (the product obtained with catalysis, 300 ton) containing ca. 70% of targeted 2,4-diphenyl-4-methyl-1-penetene at 95% conversion was after filtration used for control of molecular mass at producing polystyrene of different sorts. Consumption of the catalyst under optimal conditions of exploitation of the installation was ca. 1.5 kg per 1 ton of dimer at temperature ca. 50\u00b0C and volume rate \u223c 0.5 h\u22121. Content of 2,4-diphenyl-4-methyl-1-pentene in the dimer can be elevated to 80% by significant decreasing conversion (\u223c50%) and by application of solvents.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/s1070427208030397", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1022288", 
        "issn": [
          "1070-4272", 
          "1608-3296"
        ], 
        "name": "Russian Journal of Applied Chemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "3", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "81"
      }
    ], 
    "name": "Examination of catalyst for \u03b1-metylstyrene oligomerization \u201cPhosphoric Acid on Sibunit\u201d under conditions of laboratory and industrial application", 
    "pagination": "516-519", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "59fc2409ae783aacbca67246ee29712d5869b0ad4b1d6bc60abed779498068a6"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s1070427208030397"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1018885705"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s1070427208030397", 
      "https://app.dimensions.ai/details/publication/pub.1018885705"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T22:30", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8690_00000504.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1134%2FS1070427208030397"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1070427208030397'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1070427208030397'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1070427208030397'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1070427208030397'


 

This table displays all metadata directly associated to this object as RDF triples.

77 TRIPLES      21 PREDICATES      28 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s1070427208030397 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N5a98379bb73645f8ab959c8f8cc4dae9
4 schema:citation https://doi.org/10.1021/ie00096a004
5 schema:datePublished 2008-03
6 schema:datePublishedReg 2008-03-01
7 schema:description A catalyst obtained by impregnation of a mesoporous carbon carrier sibunit with orthophosphoric acid is examined under conditions of pilot plant manufacturing for producing α-methylstyrene dimer. The produced catalyzate (the product obtained with catalysis, 300 ton) containing ca. 70% of targeted 2,4-diphenyl-4-methyl-1-penetene at 95% conversion was after filtration used for control of molecular mass at producing polystyrene of different sorts. Consumption of the catalyst under optimal conditions of exploitation of the installation was ca. 1.5 kg per 1 ton of dimer at temperature ca. 50°C and volume rate ∼ 0.5 h−1. Content of 2,4-diphenyl-4-methyl-1-pentene in the dimer can be elevated to 80% by significant decreasing conversion (∼50%) and by application of solvents.
8 schema:genre research_article
9 schema:inLanguage en
10 schema:isAccessibleForFree false
11 schema:isPartOf N5b3c2812dee3440c87e47a2449a0ed32
12 Naf4ef23d9806418a9480e557250dd90b
13 sg:journal.1022288
14 schema:name Examination of catalyst for α-metylstyrene oligomerization “Phosphoric Acid on Sibunit” under conditions of laboratory and industrial application
15 schema:pagination 516-519
16 schema:productId N11463e6df5824e2f9cd0b9aacf697f0d
17 N955f68cd8a9043d9952d562927aff0a7
18 Nd285fca33f2b45468000eae4503c8c61
19 schema:sameAs https://app.dimensions.ai/details/publication/pub.1018885705
20 https://doi.org/10.1134/s1070427208030397
21 schema:sdDatePublished 2019-04-10T22:30
22 schema:sdLicense https://scigraph.springernature.com/explorer/license/
23 schema:sdPublisher Ndba74517f1cf4d409ff3cef819692be5
24 schema:url http://link.springer.com/10.1134%2FS1070427208030397
25 sgo:license sg:explorer/license/
26 sgo:sdDataset articles
27 rdf:type schema:ScholarlyArticle
28 N00cf976ccc8848a2a0c816fd03524714 rdf:first Nec8e718439334163b0721e6e904e972b
29 rdf:rest rdf:nil
30 N11463e6df5824e2f9cd0b9aacf697f0d schema:name readcube_id
31 schema:value 59fc2409ae783aacbca67246ee29712d5869b0ad4b1d6bc60abed779498068a6
32 rdf:type schema:PropertyValue
33 N5a98379bb73645f8ab959c8f8cc4dae9 rdf:first sg:person.010036115232.48
34 rdf:rest Nab301f75da724aaeb0a15bf23030d9df
35 N5b3c2812dee3440c87e47a2449a0ed32 schema:issueNumber 3
36 rdf:type schema:PublicationIssue
37 N955f68cd8a9043d9952d562927aff0a7 schema:name doi
38 schema:value 10.1134/s1070427208030397
39 rdf:type schema:PropertyValue
40 Nab301f75da724aaeb0a15bf23030d9df rdf:first sg:person.012120153545.27
41 rdf:rest N00cf976ccc8848a2a0c816fd03524714
42 Naf4ef23d9806418a9480e557250dd90b schema:volumeNumber 81
43 rdf:type schema:PublicationVolume
44 Nd285fca33f2b45468000eae4503c8c61 schema:name dimensions_id
45 schema:value pub.1018885705
46 rdf:type schema:PropertyValue
47 Ndba74517f1cf4d409ff3cef819692be5 schema:name Springer Nature - SN SciGraph project
48 rdf:type schema:Organization
49 Nec8e718439334163b0721e6e904e972b schema:affiliation https://www.grid.ac/institutes/grid.4886.2
50 schema:familyName Davydova
51 schema:givenName V. Yu.
52 rdf:type schema:Person
53 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
54 schema:name Chemical Sciences
55 rdf:type schema:DefinedTerm
56 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
57 schema:name Physical Chemistry (incl. Structural)
58 rdf:type schema:DefinedTerm
59 sg:journal.1022288 schema:issn 1070-4272
60 1608-3296
61 schema:name Russian Journal of Applied Chemistry
62 rdf:type schema:Periodical
63 sg:person.010036115232.48 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
64 schema:familyName Talzi
65 schema:givenName V. P.
66 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010036115232.48
67 rdf:type schema:Person
68 sg:person.012120153545.27 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
69 schema:familyName Plaksin
70 schema:givenName G. V.
71 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012120153545.27
72 rdf:type schema:Person
73 https://doi.org/10.1021/ie00096a004 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055594744
74 rdf:type schema:CreativeWork
75 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
76 schema:name Institute of the Problems of Processing Hydrocarbons, Russian Academy of Sciences, Siberian Branch, Siberian, Russia
77 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...