New cluster-type rhodium selenochlorides in oxidative carbonylation of methane View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2007-02

AUTHORS

S. V. Volkov, L. B. Khar’kova, Z. A. Fokina, O. G. Yanko, P. E. Strizhak, G. R. Kosmambetova, V. I. Gritsenko, A. M. Korduban

ABSTRACT

New rhodium selenochlorides Rh4Se16Cl10 and Rh4Se18Cl10 whose structure is based on the cluster “cubane” [Rh4(μ3-Se)4] and products of their thermal transformations were obtained. The catalytic properties of the compounds on various carbon and silica supports in oxidative carbonylation of methane in the gas phase and their dependence on the catalyst preparation technique, type of support, and size of its nanopores were analyzed. More... »

PAGES

193-200

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s107042720702005x

DOI

http://dx.doi.org/10.1134/s107042720702005x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1018236953


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