Synthesis, Molecular Structure, and Spectral Characteristics of Lead(II) Complexes with 1,5-Dimethyl-4-[2-(3-methyl-5-oxo-1-phenyl-1,5-dihydro-4H-pyrazol-4-ylidene)hydrazinyl]-2-phenyl-1,2-dihydro-3H-pyrazol-3-one View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2020-11

AUTHORS

T. N. A. Vu, A. N. Utenyshev, N. A. Polyanskaya, V. A. Nguyen, O. V. Kovalchukova

ABSTRACT

Pb(II) cations form complexes with 1,5-dimethyl-4-[2-(3-methyl-5-oxo-1-phenyl-1,5-dihydro-4H-pyrazol-4-ylidene)hydrazinyl]-2-phenyl-1,2-dihydro-3H-pyrazol-3-one (HL) in an aqueous-ethanolic solution. The C42H41N13O9Pb2 compound has been isolated in the crystalline state and its spectral characteristics have been determined. As per X-ray diffraction analysis data, it is a cocrystallizate of the Pb2L2(OH)2·(H2O)2 binuclear complex and the PbLNO3 dimeric associate. According to the simulation using the Bader method, the lead cations both in the binuclear structure and in the dimeric associate have not interacted. More... »

PAGES

2128-2133

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070363220110171

DOI

http://dx.doi.org/10.1134/s1070363220110171

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1133739393


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