Synthesis and Spectral Characteristics of Sn(IV) Tetraphenylporphyrinates View Full Text


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Article Info

DATE

2018-12

AUTHORS

N. V. Chizhova, A. V. Shinkarenko, N. Zh. Mamardashvili

ABSTRACT

Coordination reactions of 5,10,15,20-tetraphenylporphyrin, 2-bromo-5,10,15,20-tetraphenylporphyrin, 2,3,12,13-tetrabromo-5,10,15,20-tetraphenylporphyrin, 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraphenylporphyrin and metal-exchange reactions of their cadmium complexes with tin(II) chloride in dimethylformamide are described. Optimum conditions for the synthesis of Sn(IV) tetraphenylporphyrinates have been elaborated. The obtained substances have been identified by electron absorption spectroscopy, 1H NMR spectroscopy, and mass-spectroscopy.

PAGES

2559-2563

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070363218120162

DOI

http://dx.doi.org/10.1134/s1070363218120162

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1113041129


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