Reactivity of Silver(I) Diethyldithiocarbamate and Ion-Polymeric Complexes {[Au(S2CNEt2)2][AgCl2]}n and {[Au(S2CNEt2)2]2[AgCl2]Cl·2H2O}n: Synthesis, Supramolecular Structures, and Thermal Behavior View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-08

AUTHORS

E. V. Korneeva, O. V. Loseva, A. I. Smolentsev, A. V. Ivanov

ABSTRACT

New ion polymeric gold(III)–silver(I) complexes, {[Au(S2CNEt2)2][AgCl2]}n and {[Au(S2CNEt2)2]2[AgCl2]Cl·2H2O}n have been synthesized and characterized by X-ray diffraction data and IR spectra. The structure of the first complex is represented by [Au{S2CNEt2}2]+ complex cations and polymeric silver chloride anion ([AgCl2]–)n; the second complex consists of isomeric cations, linear [AgCl2]– anions, chloride ions, and water molecules. Gold cations are involved in zigzag (AuAuAu angle 99.06°) and linear polymeric chains via secondary Au···S bond pairs. Thermal decomposition of the complexes with regeneration of gold and silver has been studied by simultaneous thermal analysis (STA). More... »

PAGES

1681-1689

References to SciGraph publications

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