New Tridentate Schiff Base, Product of Condensation of 4-Methyl-7-hydroxy-8-formylcoumarin and N-Aminomercaptotriazole: Synthesis, Structure, and Complex Formation View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-07

AUTHORS

L. D. Popov, S. A. Borodkin, I. S. Vasil’chenko, V. G. Vlasenko, G. S. Borodkin, Ya. V. Zubavichus, S. I. Levchenkov, Yu. P. Tupolova, Yu. V. Revinskii, I. N. Shcherbakov

ABSTRACT

A new Schiff base was prepared by the reaction of 4-methyl-7-hydroxy-8-formylcoumarin with N-aminomercaptotriazole. In solution and in solid phase the compound was shown to exist in the thione form. The compound reacts with Cu(II), Ni(II), Zn(II) and Cd(II) ions depending on the metal salt to give complexes of composition ML2 or MHLX, where HL is monodeprotonated form of the ligand. Cu(II) and Ni(II) complexes were studied by spectral and magnetochemical methods. The Zn(II) and Cd(II) complexes exhibit fluorescence. More... »

PAGES

1441-1450

References to SciGraph publications

  • 2010-02. Molecular design of azomethine complexes in RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
  • 2008-09. Solvent-induced E/Z(C=N)-isomerization of imines of some hydroxy-substituted formylcoumarins in RUSSIAN CHEMICAL BULLETIN
  • Identifiers

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    http://scigraph.springernature.com/pub.10.1134/s1070363218070150

    DOI

    http://dx.doi.org/10.1134/s1070363218070150

    DIMENSIONS

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    163 Southern Federal University, ul. Zorge 7, 344090, Rostov-on-Don, Russia
    164 rdf:type schema:Organization
    165 grid-institutes:grid.18919.38 schema:alternateName National Research Center “Kurchatov Institute,”, Moscow, Russia
    166 schema:name National Research Center “Kurchatov Institute,”, Moscow, Russia
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    168 grid-institutes:grid.465325.3 schema:alternateName Southern Scientific Center of the Russian Academy of Sciences, Rostov-on-Don, Russia
    169 schema:name Southern Federal University, ul. Zorge 7, 344090, Rostov-on-Don, Russia
    170 Southern Scientific Center of the Russian Academy of Sciences, Rostov-on-Don, Russia
    171 rdf:type schema:Organization
     




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