Spectral luminescent properties of 5-(2-hydroxyphenyl)-3-ethyl-1-(pyridin-2-yl)-1Н-1,2,4-triazole and its Be(II) complex View Full Text


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Article Info

DATE

2017-01

AUTHORS

I. E. Mikhailov, L. D. Popov, N. I. Vikrischuk, A. D. Beldovskaya, G. A. Dushenko, Yu. V. Revinskii, V. I. Minkin

ABSTRACT

The interaction of 4-oxo-1,3-benzoxazinium perchlorate with 2-pyridylhydrazine has given 5-(2-hydroxyphenyl)-3-ethyl-1-(pyridin-2-yl)-1Н-1,2,4-triazole (L). Boiling of the latter in methanol with 0.5 equiv of beryllium sulfate tetrahydrate has afforded the L2Be metal complex. In contrast to the starting triazole, its beryllium complex exhibits strong violet luminescence (λmaxfl = 431–434 nm, φ = 0.56–0.64).

PAGES

156-158

References to SciGraph publications

  • 2011-01. Synthesis of 1-(benzothiazol-2-yl)-5-(o-hydroxyphenyl)-1H-1,2,4-triazoles in RUSSIAN JOURNAL OF GENERAL CHEMISTRY
  • 2013-11. Synthesis, structure, and spectral luminescent properties of novel 1,2,4-triazole derivatives containing benzthiazole group in RUSSIAN JOURNAL OF GENERAL CHEMISTRY
  • 2012-01. Synthesis, structure, and luminescent properties of 2-[2-(9-anthryl)vinyl]quinolines in RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
  • 2010-07. Synthesis and properties of substituted [3-(2-hydroxyphenyl)-1H-1,2,4-triazol-1-yl]acetonitriles in RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
  • 2014-01. 2-(2′-Hydroxyphenyl)-5-(4″-nonylphenyl)-1,3,4-oxadiazole and its beryllium complex in RUSSIAN JOURNAL OF GENERAL CHEMISTRY
  • 2011-02-25. Coordination compound of cadmium acetate with the condensation product of salicylaldehyde and 3-(pyridin-2-yl)-5-(2-aminophenyl)-1H-1,2,4-triazole in RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
  • 2015-05. Synthesis and spectral-luminescence properties of 2-[2-(pyridin-4-yl)vinyl]quinolines in RUSSIAN JOURNAL OF GENERAL CHEMISTRY
  • 2013-12. Synthesis and luminescence properties of 2-(2-benzoyloxyphenyl)-5-aryl-1,3,4-oxadiazoles in RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
  • 2009-10. Reactions of hydroxyphenyl-substituted 1,2,4-triazoles with electrophylic reagents in RUSSIAN JOURNAL OF GENERAL CHEMISTRY
  • 2016-05. Absorption and luminescence spectra of 5-aryl-3-methyl-1,2,4-oxadiazoles and their chelate complexes with Zinc(II) and copper(II) in RUSSIAN JOURNAL OF GENERAL CHEMISTRY
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    http://scigraph.springernature.com/pub.10.1134/s1070363217010261

    DOI

    http://dx.doi.org/10.1134/s1070363217010261

    DIMENSIONS

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