Structure and magnetic properties of 2,4,6,8-tetra(tert-butyl)phenoxazin-1-one adducts with cobalt(II) salts View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2016-07

AUTHORS

E. P. Ivakhnenko, Yu. V. Koshchienko, A. V. Chernyshev, P. A. Knyazev, T. E. Ivakhnenko, K. A. Lyssenko

ABSTRACT

Complex formation reaction of redox-active 2,4,6,8-tetra(tert-butyl)phenoxazin-1-one with cobalt(II) chloride leading to the dimeric adduct has been studied. UV spectroscopy studies have revealed the equilibrium of the formed adduct with dissociated form of the complex in the acetonitrile solution. In the presence of ethylene glycol, the complex formation with cobalt(II) perchlorate has afforded the high-spin trimolecular adduct. Crystal structure of the obtained adducts has been studied by means of X-ray diffraction analysis. More... »

PAGES

1664-1670

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070363216070227

DOI

http://dx.doi.org/10.1134/s1070363216070227

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1039883316


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