Reactions of 2-methyleneadamantane and 2-benzylideneadamantane with acetyl nitrate View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2016-02

AUTHORS

P. E. Krasnikov, V. A. Osyanin, D. V. Osipov, Yu. N. Klimochkin

ABSTRACT

The reactions of 2-methylene- and 2-benzylideneadamantane with acetyl nitrate have been studied. In the case of 2-methyleneadamantane, the reaction proceeds via addition of nitronium cation at the double bond followed by stabilization of 2-nitromethyl-2-adamantyl carbocation. In the case of 2-benzylidenadamantane, ortho-substitution at the benzene ring occurred predominantly.

PAGES

262-266

References to SciGraph publications

  • 2014-10-08. The Interaction of 1H-Azoles With Nitrosochlorides of Adamantane Series in CHEMISTRY OF HETEROCYCLIC COMPOUNDS
  • 2015-03. Nitrosochlorination of 2-alkylideneadamantanes in RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
  • 2015-05. Synthesis and properties of vicinal cyanoximes of adamantane series in RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1134/s1070363216020092

    DOI

    http://dx.doi.org/10.1134/s1070363216020092

    DIMENSIONS

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