Ontology type: schema:ScholarlyArticle
2016-02
AUTHORSP. E. Krasnikov, V. A. Osyanin, D. V. Osipov, Yu. N. Klimochkin
ABSTRACTThe reactions of 2-methylene- and 2-benzylideneadamantane with acetyl nitrate have been studied. In the case of 2-methyleneadamantane, the reaction proceeds via addition of nitronium cation at the double bond followed by stabilization of 2-nitromethyl-2-adamantyl carbocation. In the case of 2-benzylidenadamantane, ortho-substitution at the benzene ring occurred predominantly.
PAGES262-266
http://scigraph.springernature.com/pub.10.1134/s1070363216020092
DOIhttp://dx.doi.org/10.1134/s1070363216020092
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1052708968
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Physical Chemistry (incl. Structural)",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "Samara State Technical University, ul. Molodogvardeiskaya 244, 443100, Samara, Russia",
"id": "http://www.grid.ac/institutes/grid.445792.9",
"name": [
"Samara State Technical University, ul. Molodogvardeiskaya 244, 443100, Samara, Russia"
],
"type": "Organization"
},
"familyName": "Krasnikov",
"givenName": "P. E.",
"id": "sg:person.011641341374.36",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011641341374.36"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Samara State Technical University, ul. Molodogvardeiskaya 244, 443100, Samara, Russia",
"id": "http://www.grid.ac/institutes/grid.445792.9",
"name": [
"Samara State Technical University, ul. Molodogvardeiskaya 244, 443100, Samara, Russia"
],
"type": "Organization"
},
"familyName": "Osyanin",
"givenName": "V. A.",
"id": "sg:person.01214150106.35",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01214150106.35"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Samara State Technical University, ul. Molodogvardeiskaya 244, 443100, Samara, Russia",
"id": "http://www.grid.ac/institutes/grid.445792.9",
"name": [
"Samara State Technical University, ul. Molodogvardeiskaya 244, 443100, Samara, Russia"
],
"type": "Organization"
},
"familyName": "Osipov",
"givenName": "D. V.",
"id": "sg:person.0774140267.77",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0774140267.77"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Samara State Technical University, ul. Molodogvardeiskaya 244, 443100, Samara, Russia",
"id": "http://www.grid.ac/institutes/grid.445792.9",
"name": [
"Samara State Technical University, ul. Molodogvardeiskaya 244, 443100, Samara, Russia"
],
"type": "Organization"
},
"familyName": "Klimochkin",
"givenName": "Yu. N.",
"id": "sg:person.012470171230.98",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012470171230.98"
],
"type": "Person"
}
],
"citation": [
{
"id": "sg:pub.10.1134/s107042801505005x",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1015190938",
"https://doi.org/10.1134/s107042801505005x"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1007/s10593-014-1568-2",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1023377848",
"https://doi.org/10.1007/s10593-014-1568-2"
],
"type": "CreativeWork"
},
{
"id": "sg:pub.10.1134/s1070428015030069",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1037211532",
"https://doi.org/10.1134/s1070428015030069"
],
"type": "CreativeWork"
}
],
"datePublished": "2016-02",
"datePublishedReg": "2016-02-01",
"description": "The reactions of 2-methylene- and 2-benzylideneadamantane with acetyl nitrate have been studied. In the case of 2-methyleneadamantane, the reaction proceeds via addition of nitronium cation at the double bond followed by stabilization of 2-nitromethyl-2-adamantyl carbocation. In the case of 2-benzylidenadamantane, ortho-substitution at the benzene ring occurred predominantly.",
"genre": "article",
"id": "sg:pub.10.1134/s1070363216020092",
"inLanguage": "en",
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1109093",
"issn": [
"1070-3632",
"1608-3350"
],
"name": "Russian Journal of General Chemistry",
"publisher": "Pleiades Publishing",
"type": "Periodical"
},
{
"issueNumber": "2",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "86"
}
],
"keywords": [
"acetyl nitrate",
"nitronium cation",
"double bond",
"benzene ring",
"reaction",
"nitrate",
"cations",
"carbocations",
"bonds",
"ring",
"stabilization",
"addition",
"cases"
],
"name": "Reactions of 2-methyleneadamantane and 2-benzylideneadamantane with acetyl nitrate",
"pagination": "262-266",
"productId": [
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1052708968"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1134/s1070363216020092"
]
}
],
"sameAs": [
"https://doi.org/10.1134/s1070363216020092",
"https://app.dimensions.ai/details/publication/pub.1052708968"
],
"sdDataset": "articles",
"sdDatePublished": "2022-01-01T18:41",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-springernature-scigraph/baseset/20220101/entities/gbq_results/article/article_703.jsonl",
"type": "ScholarlyArticle",
"url": "https://doi.org/10.1134/s1070363216020092"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1070363216020092'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1070363216020092'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1070363216020092'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1070363216020092'
This table displays all metadata directly associated to this object as RDF triples.
104 TRIPLES
22 PREDICATES
42 URIs
31 LITERALS
6 BLANK NODES