Reactions of bisdiazonium salts derived from monosubstituted m-phenylenediamines with amides and nitriles of unsaturated acids under anionarylation conditions View Full Text


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Article Info

DATE

2015-08

AUTHORS

V. S. Baranovskii, V. N. Yatsyuk, A. N. Vasilenko, B. D. Grishchuk

ABSTRACT

Reactions of 5-carboxy and 4-methylphenylene-1,3-bisdiazonium tetrafluoroborates with amides and nitriles of acrylic and methacrylic acids in the presence of chloride, bromide, and thiocyanate anions proceed as anionarylation at one of the diazo groups and nucleophilic substitution at another one. With 4-methylphenylene- 1,3-bisdiazonium tetrafluoroborate as the arylating agent, the anionarylation and the Sandmeyer reaction occur involving para- and ortho-positioned diazo groups, respectively. More... »

PAGES

1821-1825

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070363215080058

DOI

http://dx.doi.org/10.1134/s1070363215080058

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1037283393


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